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Organosulfur materials containing sulfur–sulfur bonds are an emerging class of high-capacity cathodes for lithium storage. However, it remains a great challenge to achieve rapid conversion reaction kinetics at practical testing conditions of high cathode mass loading and low electrolyte utilization. In this study, a Li-rich pyrolyzed polyacrylonitrile/selenium disulfide (pPAN/Se2S3) composite cathode is synthesized by deep lithiation to address the above challenges. The Li-rich molecular structure significantly boosts the lithium storage kinetics by accelerating lithium diffusivity and improving electronic conductivity. Even under practical test conditions requiring a lean electrolyte (Electrolyte/sulfur ratio of 4.1 μL mg−1) and high loading (7 mg cm−2 of pPAN/Se2S3), DL-pPAN/Se2S3 exhibits a specific capacity of 558 mAh g−1, maintaining 484 mAh g−1 at the 100th cycle with an average Coulombic efficiency of near 100%. Moreover, it provides (electro)chemically stable Li resources to offset Li consumption over charge–discharge cycles. As a result the as-fabricated anode-free cell shows a superior cycling stability with 90% retention of the initial capacity over 45 cycles. This study provides a novel approach for fabricating high-energy and stable Li–SPAN cells.
M. Li, J. Lu, Z. Chen, K. Amine, Adv. Mater. 2018, 30, 1800561.
Y. M. Zhao, F. S. Yue, S. C. Li, Y. Zhang, Z. R. Tian, Q. Xu, S. Xin, Y. G. Guo, InfoMat 2021, 3, 460.
Z. Han, S. Li, R. Xiong, Z. Jiang, M. Sun, W. Hu, L. Peng, R. He, H. Zhou, C. Yu, Adv. Funct. Mater. 2022, 32, 2108669.
J. Liu, Z. Bao, Y. Cui, E. J. Dufek, J. B. Goodenough, P. Khalifah, Q. Li, B. Y. Liaw, P. Liu, A. Manthiram, Nat. Energy 2019, 4, 180.
Z. W. Seh, Y. Sun, Q. Zhang, Y. Cui, Chem. Soc. Rev. 2016, 45, 5605.
Y. Guo, H. Li, T. Zhai, Adv. Mater. 2017, 29, 1700007.
Y. Chen, T. Wang, H. Tian, D. Su, Q. Zhang, G. Wang, Adv. Mater. 2021, 33, 2003666.
J. Sun, T. Wang, Y. Gao, Z. Pan, R. Hu, J. Wang, InfoMat 2022, 4, e12359.
C. P. Yang, S. Xin, Y. X. Yin, H. Ye, J. Zhang, Y. G. Guo, Angew. Chem. Int. Ed. 2013, 52, 8363.
L. Hencz, H. Chen, Z. Wu, S. Qian, S. Chen, X. Gu, X. Liu, C. Yan, S. Zhang, Exp. Dermatol. 2022, 2, 20210131.
S. S. Zhang, Energies 2014, 7, 4588.
G. Li, S. Wang, Y. Zhang, M. Li, Z. Chen, J. Lu, Adv. Mater. 2018, 30, 1705590.
Z. Han, S. Li, Y. Wu, C. Yu, S. Cheng, J. Xie, J. Mater. Chem. A 2021, 9, 24215.
X. Yu, J. Zhao, R. Lv, Q. Liang, C. Zhan, Y. Bai, Z.-H. Huang, W. Shen, F. Kang, J. Mater. Chem. A 2015, 3, 18400.
X. Yu, J. Deng, R. Lv, Z.-H. Huang, B. Li, F. Kang, Energy Storage Mater. 2019, 20, 14.
Y. Wang, R. Zhang, J. Chen, H. Wu, S. Lu, K. Wang, H. Li, C. J. Harris, K. Xi, R. V. Kumar, Adv. Energy Mater. 2019, 9, 1900953.
Z. Cui, C. Zu, W. Zhou, A. Manthiram, J. B. Goodenough, Adv. Mater. 2016, 28, 6926.
Y.-S. Su, A. Manthiram, Nat. Commun. 2012, 3, 1166.
Z. Xiao, Z. Yang, L. Wang, H. Nie, M. E. Zhong, Q. Lai, X. Xu, L. Zhang, S. Huang, Adv. Mater. 2015, 27, 2891.
X. Yu, T. Liao, J. Tang, K. Zhang, S. Tang, R.-S. Gao, S. Lin, L.-C. Qin, Adv. Energy Sustainability Res. 2021, 2, 2100053.
W. Shin, L. Zhu, H. Jiang, W. F. Stickle, C. Fang, C. Liu, J. Lu, X. Ji, Mater. Today 2020, 40, 63.
Z. Jiang, Z. Zeng, W. Hu, Z. Han, S. Cheng, J. Xie, Energy. Storage Mater. 2021, 36, 333.
H. Liu, J. Holoubek, H. Zhou, A. Chen, N. Chang, Z. Wu, S. Yu, Q. Yan, X. Xing, Y. Li, Mater. Today 2021, 42, 17.
J. Lian, W. Guo, Y. Fu, J. Am. Chem. Soc. 2021, 143, 11063.
P. Sang, Q. Chen, D.-Y. Wang, W. Guo, Y. Fu, Chem. Rev. 2023, 123, 1262.
H. Yang, J. Chen, J. Yang, J. Wang, Angew. Chem. Int. Ed. 2020, 132, 7374.
Z. Jiang, H.-J. Guo, Z. Zeng, Z. Han, W. Hu, R. Wen, J. Xie, ACS Nano 2020, 14, 13784.
W. Wang, Z. Cao, G. A. Elia, Y. Wu, W. Wahyudi, E. Abou-Hamad, A.-H. Emwas, L. Cavallo, L.-J. Li, J. Ming, ACS. Energy Lett. 2018, 3, 2899.
C. Luo, Y. Zhu, O. Borodin, T. Gao, X. Fan, Y. Xu, K. Xu, C. Wang, Adv. Funct. Mater. 2016, 26, 745.
W. J. Chen, B. Q. Li, C. X. Zhao, M. Zhao, T. Q. Yuan, R. C. Sun, J. Q. Huang, Q. Zhang, Angew. Chem. Int. Ed. 2020, 59, 10732.
C. Luo, E. Hu, K. J. Gaskell, X. Fan, T. Gao, C. Cui, S. Ghose, X.-Q. Yang, C. Wang, Proc. Natl. Acad. Sci. 2020, 117, 14712.
M. A. Weret, C.-F. J. Kuo, W.-N. Su, T. S. Zeleke, C.-J. Huang, N. A. Sahalie, T. A. Zegeye, Z. T. Wondimkun, F. W. Fenta, B. A. Jote, J. Power Sources 2022, 541, 231693.
Z. Li, J. Zhang, Y. Lu, X. W. Lou, Sci. Adv. 2018, 4, eaat1687.
Y. Liu, A. K. Haridas, K.-K. Cho, Y. Lee, J.-H. Ahn, J. Phys. Chem. C 2017, 121, 26172.
X. Chen, L. Peng, L. Wang, J. Yang, Z. Hao, J. Xiang, K. Yuan, Y. Huang, B. Shan, L. Yuan, Nat. Commun. 2019, 10, 1021.
S. Ma, Z. Zhang, Y. Wang, Z. Yu, C. Cui, M. He, H. Huo, G. Yin, P. Zuo, Chem. Eng. J. 2021, 418, 129410.
L. Lin, K. Qin, Q. Zhang, L. Gu, L. Suo, Y. S. Hu, H. Li, X. Huang, L. Chen, Angew. Chem. Int. Ed. 2021, 60, 8289.
S. Langrud, A. A. Razzaq, S. Santhanagopalan, R. Brow, W. Xing, J. Electrochem. Soc. 2022, 169, 070514.
Z. Jiang, H.-J. Guo, Z. Zeng, X. Chen, Y. Lei, X. Liang, Z. Han, W. Hu, J. Feng, R. Wen, ACS Appl. Mater. Interfaces 2021, 13, 41555.
Y. Deng, H. Xu, Z. Bai, B. Huang, J. Su, G. Chen, J. Power Sources 2015, 300, 386.
M. Wang, H. Yang, K. Shen, H. Xu, W. Wang, Z. Yang, L. Zhang, J. Chen, Y. Huang, M. Chen, Small Methods 2020, 4, 2000353.
S. Chen, J. Zheng, D. Mei, K. S. Han, M. H. Engelhard, W. Zhao, W. Xu, J. Liu, J. G. Zhang, Adv. Mater. 2018, 30, 1706102.
X. Zhao, C. Wang, Z. Li, X. Hu, A. A. Razzaq, Z. Deng, J. Mater. Chem. A 2021, 9, 19282.
Q. Zhang, S. Liu, Z. Lin, K. Wang, M. Chen, K. Xu, W. Li, Nano Energy 2020, 74, 104860.
Z. Piao, P. Xiao, R. Luo, J. Ma, R. Gao, C. Li, J. Tan, K. Yu, G. Zhou, H. M. Cheng, Adv. Mater. 2022, 34, 2108400.
C. Yan, Y. X. Yao, X. Chen, X. B. Cheng, X. Q. Zhang, J. Q. Huang, Q. Zhang, Angew. Chem. Int. Ed. 2018, 130, 14251.
X. Q. Zhang, X. B. Cheng, X. Chen, C. Yan, Q. Zhang, Adv. Funct. Mater. 2017, 27, 1605989.
X. Fan, L. Chen, X. Ji, T. Deng, S. Hou, J. Chen, J. Zheng, F. Wang, J. Jiang, K. Xu, Chem 2018, 4, 174.
S. Liu, X. Ji, N. Piao, J. Chen, N. Eidson, J. Xu, P. Wang, L. Chen, J. Zhang, T. Deng, Angew. Chem. Int. Ed. 2021, 60, 3661.
M. Itagaki, K. Honda, Y. Hoshi, I. Shitanda, J. Electroanal. Chem. 2015, 737, 78.
M. Barghamadi, A. S. Best, A. I. Bhatt, A. F. Hollenkamp, P. J. Mahon, M. Musameh, T. Rüther, J. Power Sources 2015, 295, 212.
J. Wu, L. Yuan, Z. Li, X. Xie, Y. Huang, Mater. Horiz. 2020, 7, 2619.
J. Qian, B. D. Adams, J. Zheng, W. Xu, W. A. Henderson, J. Wang, M. E. Bowden, S. Xu, J. Hu, J. G. Zhang, Adv. Funct. Mater. 2016, 26, 7094.
H. J. Peng, J. Q. Huang, X. B. Cheng, Q. Zhang, Adv. Energy Mater. 2017, 7, 1700260.
S. Nanda, A. Gupta, A. Manthiram, Adv. Energy Mater. 2018, 8, 1801556.
H. Cheng, C. Gao, N. Cai, M. Wang, Chem. Commun. 2021, 57, 3708.
S. Nanda, A. Bhargav, A. Manthiram, Joule 2020, 4, 1121.
J. Chen, J. Xiang, X. Chen, L. Yuan, Z. Li, Y. Huang, Energy Storage Mater. 2020, 30, 179.
S. Nanda, H. Y. Asl, A. Bhargav, A. Manthiram, Cell Rep. Phys. Sci. 2022, 3, 100808.
N. Piao, S. Liu, B. Zhang, X. Ji, X. Fan, L. Wang, P.-F. Wang, T. Jin, S.-C. Liou, H. Yang, ACS Energy Lett. 2021, 6, 1839.
W. Kohn, L. J. Sham, Phys. Rev. 1965, 140, A1133.
H. J. Monkhorst, J. D. Pack, Phys. Rev. B 1976, 13, 5188.
S. Grimme, J. Comput. Chem. 2006, 27, 1787.
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