AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
{{expandStatus?'Exit ':''}}Advanced Search
(
(
The undesirable capacity loss after first cycle is universal among layered cathode materials, which results in the capacity and energy decay. The key to resolving this obstacle lies in understanding the effect and origin of specific active Li sites during discharge process. In this study, focusing on Ah-level pouch cells for reliability, an ultrahigh initial Coulombic efficiency (96.1%) is achieved in an archetypical Li-rich layered oxide material. Combining the structure and electrochemistry analysis, we demonstrate that the achievement of high-capacity reversibility is a kinetic effect, primarily related to the sluggish Li mobility during oxygen reduction. Activating oxygen reduction through small density would induce the oxygen framework contraction, which, according to Pauli repulsion, imposes a great repulsive force to hinder the transport of tetrahedral Li. The tetrahedral Li storage upon deep oxygen reduction is experimentally visualized and, more importantly, contributes to 6% Coulombic efficiency enhancement as well as 10% energy density improvement for pouch cells, which shows great potentials breaking through the capacity and energy limitation imposed by intercalation chemistry.
M. Armand, J. M. Tarascon, Nature 2008, 451, 652.
T. H. Kim, J. S. Park, S. K. Chang, S. Choi, J. H. Ryu, H. K. Song, Adv. Energy Mater. 2012, 2, 860.
G. Assat, J. M. Tarascon, Nat. Energy 2018, 3, 373.
A. Grenier, P. J. Reeves, H. Liu, I. D. Seymour, K. Marker, K. M. Wiaderek, P. J. Chupas, C. P. Grey, K. W. Chapman, J. Am. Chem. Soc. 2020, 142, 7001.
K. Märker, P. J. Reeves, C. Xu, K. J. Griffith, C. P. Grey, Chem. Mater. 2019, 31, 2545.
M. Gu, I. Belharouak, J. Zheng, H. Wu, J. Xiao, A. Genc, K. Amine, S. Thevuthasan, D. R. Baer, J.-G. Zhang, N. D. Browning, J. Liu, A. C. Wang, ACS Nano 2013, 7, 760.
K. Kleiner, B. Strehle, A. R. Baker, S. J. Day, C. C. Tang, I. Buchberger, F.-F. Chesneau, H. A. Gasteiger, M. Piana, Chem. Mater. 2018, 30, 3656.
W. Li, A. Dolocan, P. Oh, H. Celio, S. Park, J. Cho, A. Manthiram, Nat. Commun. 2017, 8, 14589.
Y. Li, L. Weikang, S. Ryosuke, C. Diyi, N. HongNam, P. Jens, K. Shinichi, Z. Minghao, M. Y. Shirley, Adv. Energy Mater. 2022, 12, 2103033.
J. Kasnatscheew, M. Evertz, B. Streipert, R. Wagner, R. Klopsch, B. Vortmann, H. Hahn, S. Nowak, M. Amereller, A. C. Gentschev, P. Lamp, M. Winter, Phys. Chem. Chem. Phys. 2016, 18, 3956.
K. Kisuk, C. Ching-Hsiang, B. J. Hwang, C. Gerbrand, Chem. Mater. 2004, 16, 1685.
D. H. Seo, J. Lee, A. Urban, R. Malik, S. Y. Kang, G. Ceder, Nat. Chem. 2016, 8, 692.
Y. Xie, M. Saubanère, M. L. Doublet, Energy Environ. Sci. 2017, 10, 266.
B. Qiu, M. Zhang, L. Wu, J. Wang, Y. Xia, D. Qian, H. Liu, S. Hy, Y. Chen, K. An, Y. Zhu, Z. Liu, Y. S. Meng, Nat. Commun. 2016, 7, 12108.
Y. Lei, J. Ni, Z. J. Hu, Z. M. Wang, F. K. Gui, B. Li, P. W. Ming, C. M. Zhang, Y. Elias, D. Aurbach, Q. F. Xiao, Adv. Energy Mater 2020, 10, 2002506.
X. Li, Q. Gu, B. Qiu, C. Yin, Z. Wei, W. Wen, Y. Zhang, Y. Zhou, H. Gao, H. Liang, Z. He, M. Zhang, Y. S. Meng, Z. Liu, Mater. Today 2022, 61, 91.
A. Boulineau, L. Simonin, J. F. Colin, C. Bourbon, S. Patoux, Nano Lett. 2013, 13, 3857.
K. Luo, M. R. Roberts, R. Hao, N. Guerrini, D. M. Pickup, Y. S. Liu, K. Edstrom, J. Guo, A. V. Chadwick, L. C. Duda, P. G. Bruce, Nat. Chem. 2016, 8, 684.
L. Fang, D. Han, S. Kang, U.-S. Heo, K.-W. Nam, Y.-M. Kang, Energy Environ. Sci. 2023, 16, 3053.
Y. Zhang, Z. Chen, X. Shi, C. Meng, P. Das, S. Zheng, F. Pan, Z. S. Wu, Adv. Energy Mater. 2022, 13, 2203045.
H. L. Yu, K. B. Ibrahim, P. W. Chi, Y. H. Su, W. T. Chen, S. C. Tseng, M. T. Tang, C. L. Chen, H. Y. Tang, C. W. Pao, K. H. Chen, M. K. Wu, H. L. Wu, Adv. Funct. Mater. 2022, 32, 2112394.
J. Song, F. Ning, Y. Zuo, A. Li, H. Wang, K. Zhang, T. Yang, Y. Yang, C. Gao, W. Xiao, Z. Jiang, T. Chen, G. Feng, D. Xia, Adv. Mater. 2022, 35, 2208726.
J. Zhang, F. Cheng, S. Chou, J. Wang, L. Gu, H. Wang, H. Yoshikawa, Y. Lu, J. Chen, Adv. Mater. 2019, 31, 1901808.
J. Hwang, S. Myeong, W. Jin, H. Jang, G. Nam, M. Yoon, S. H. Kim, S. H. Joo, S. K. Kwak, M. G. Kim, J. Cho, Adv. Mater. 2020, 32, 2001944.
T. H. Wu, X. Liu, X. Zhang, Y. Lu, B. Y. Wang, Q. S. Deng, Y. B. Yang, E. Wang, Z. T. Lyu, Y. Q. Li, Y. T. Wang, Y. Lyu, C. F. He, Y. Ren, G. L. Xu, X. L. Sun, A. Khalil, H. J. Yu, Adv. Mater. 2021, 33, 2001358.
S.-Y. Liu, Y.-H. Zhou, Y.-B. Zhang, S.-J. Xia, Y. Li, X. Zhou, B. Qiu, G.-J. Shao, Z.-P. Liu, Tungsten 2022, 4, 336.
X. He, J. Wu, Z. Zhu, H. Liu, N. Li, D. Zhou, X. Zhou, H. Zhang, D. Bresser, Y. Fu, M. J. Crafton, B. D. McCloskey, Y. Chen, K. An, P. Liu, A. Jain, J. Li, W. Yang, Y. Yang, M. Winter, R. Kostecki, Energy Environ. Sci. 2022, 15, 4137.
Y. Tang, Y. Zhang, W. Li, B. Ma, X. Chen, Chem. Soc. Rev. 2015, 44, 5926.
J. Ni, A. Dai, Y. Yuan, L. Li, J. Lu, Matter 2020, 2, 1366.
G. Assat, C. Delacourt, D. A. D. Corte, J.-M. Tarascon, J. Electrochem. Soc. 2016, 163, A2965.
G. Assat, D. Foix, C. Delacourt, A. Iadecola, R. Dedryvere, J. M. Tarascon, Nat. Commun. 2017, 8, 2219.
K. S. Kang, Y. S. Meng, J. Breger, C. P. Grey, G. Ceder, Science 2006, 311, 977.
J. Lee, A. Urban, X. Li, D. Su, G. Hautier, G. Ceder, Science 2014, 343, 519.
Y. Wei, J. X. Zheng, S. H. Cui, X. H. Song, Y. T. Su, W. J. Deng, Z. Z. Wu, X. W. Wang, W. D. Wang, M. M. Rao, Y. Lin, C. M. Wang, K. Amine, F. Pan, J. Am. Chem. Soc. 2015, 137, 8364.
R. A. House, G. J. Rees, K. McColl, J.-J. Marie, M. Garcia-Fernandez, A. Nag, K.-J. Zhou, S. Cassidy, B. J. Morgan, M. Saiful Islam, P. G. Bruce, Nat. Energy 2023, 8, 351.
M. Sathiya, G. Rousse, K. Ramesha, C. P. Laisa, H. Vezin, M. T. Sougrati, M. L. Doublet, D. Foix, D. Gonbeau, W. Walker, A. S. Prakash, M. Ben Hassine, L. Dupont, J. M. Tarascon, Nat. Mater. 2013, 12, 827.
C. Yin, Z. Wei, M. Zhang, B. Qiu, Y. Zhou, Y. Xiao, D. Zhou, L. Yun, C. Li, Q. Gu, W. Wen, X. Li, X. Wen, Z. Shi, L. He, Y. Shirley Meng, Z. Liu, Mater. Today 2021, 51, 15.
R. A. House, H. Y. Playford, R. I. Smith, J. Holter, I. Griffiths, K.-J. Zhou, P. G. Bruce, Energy Environ. Sci. 2022, 15, 376.
Y. Zhou, H. Cui, B. Qiu, Y. Xia, C. Yin, L. Wan, Z. Shi, Z. Liu, ACS Mater. Lett. 2021, 3, 433.
B. Qiu, M. Zhang, S.-Y. Lee, H. Liu, T. A. Wynn, L. Wu, Y. Zhu, W. Wen, C. M. Brown, D. Zhou, Z. Liu, Y. S. Meng, Cell. Rep. Phys. Sci. 2020, 1, 100028.
Z. Wei, Z. Shi, X. Wen, X. Li, B. Qiu, Q. Gu, J. Sun, Y. Han, H. Luo, H. Guo, Y. Xia, C. Yin, P. Cai, Z. Liu, Mater. Today Energy 2022, 27, 101039.
R. A. House, G. J. Rees, M. A. Pérez Osorio, J. J. Marie, E. Boivin, A. W. Robertson, A. Nag, M. Garcia Fernandez, K. J. Zhou, P. G. Bruce, Nat. Energy 2020, 5, 777.
C. Cui, X. Fan, X. Zhou, J. Chen, Q. Wang, L. Ma, C. Yang, E. Hu, X. Q. Yang, C. Wang, J. Am. Chem. Soc. 2020, 142, 8918.
Y. Li, Z. Shi, B. Qiu, J. Zhao, X. Li, Y. Zhang, T. Li, Q. Gu, J. Gao, Z. Liu, Adv. Funct. Mater. 2023, 33, 2302236.
Z. Shi, Q. Gu, L. Yun, Z. Wei, D. Hu, B. Qiu, G. Z. Chen, Z. Liu, J. Mater. Chem. A 2021, 9, 24426.
L. Zeng, H. Liang, B. Qiu, Z. Shi, S. Cheng, K. Shi, Q. Liu, Z. Liu, Adv. Funct. Mater 2023, 33, 2213260.
C. Yin, X. Wen, L. Wan, Z. Shi, Z. Wei, X. Li, Q. Gu, B. Qiu, Z. Liu, J. Power Sources 2021, 503, 230048.
P. Yan, J. Zheng, J. G. Zhang, C. Wang, Nano Lett. 2017, 17, 3946.
L. Li, E. C. Self, D. Darbar, L. Zou, I. Bhattacharya, D. Wang, J. Nanda, C. Wang, Nano Lett. 2020, 20, 2756.
D. Qian, B. Xu, M. Chi, Y. S. Meng, Phys. Chem. Chem. Phys. 2014, 16, 14665.
W. Huang, L. Yang, Z. Chen, T. Liu, G. Ren, P. Shan, B. W. Zhang, S. Chen, S. Li, J. Li, C. Lin, W. Zhao, J. Qiu, J. Fang, M. Zhang, C. Dong, F. Li, Y. Yang, C. J. Sun, Y. Ren, Q. Huang, G. Hou, S. X. Dou, J. Lu, K. Amine, F. Pan, Adv. Mater. 2022, 34, 2202745.
X. Q. Yu, Y. C. Lyu, L. Gu, H. M. Wu, S. M. Bak, Y. N. Zhou, K. Amine, S. N. Ehrlich, H. Li, K. W. Nam, X. Q. Yang, Adv. Energy Mater 2014, 4, 1300950.
E. Y. Hu, X. Q. Yu, R. Q. Lin, X. X. Bi, J. Lu, S. Bak, K. W. Nam, H. L. Xin, C. Jaye, D. A. Fischer, K. Amine, X. Q. Yang, Nat. Energy 2018, 3, 690.
G. Liang, C. Didier, Z. Guo, W. K. Pang, V. K. Peterson, Adv. Mater. 2020, 32, 1904528.
H. Liu, Y. Chen, S. Hy, K. An, S. Venkatachalam, D. Qian, M. Zhang, Y. S. Meng, Adv. Energy Mater. 2016, 6, 1502143.
J. Reed, G. Ceder, Chem. Rev. 2004, 104, 4513.
E. Lee, W. Lee, H. Kim, M. Kim, S. Yun, J. Kim, W.-S. Yoon, ACS Energy Lett. 2023, 8, 707.
W. Zhang, D.-H. Seo, T. Chen, L. Wu, M. Topsakal, Y. Zhu, D. Lu, G. Ceder, F. Wang, Science 2020, 367, 1030.
M. Zhang, B. Qiu, J. M. Gallardo-Amores, M. Olguin, H. Liu, Y. Li, C. Yin, S. Jiang, W. Yao, M. E. Arroyo-de Dompablo, Z. Liu, Y. S. Meng, Matter 2020, 4, 164.
B. H. Toby, R. B. Von Dreele, J. Appl. Crystallogr. 2013, 46, 544.
B. Ravel, M. Newville, J. Synchrotron Radiat. 2005, 12, 537.
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
京公网安备11010802044758号