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Review | Open Access

Nickel–Nitrogen–Carbon (Ni–N–C) Electrocatalysts Toward CO₂ electroreduction to CO: Advances, Optimizations, Challenges, and Prospects

Qingqing Pang^¹, Xizheng Fan^¹, Kaihang Sun^¹, Kun Xiang^², Baojun Li^¹, Shufang Zhao^³, Young Dok Kim^³, Qiaoyun Liu^¹(), Zhongyi Liu^¹(), Zhikun Peng^¹

()

1

School of Chemical Engineering, College of Chemistry, Henan Institute of Advance Technology, Zhengzhou University, Zhengzhou 450001, China

2

School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China

3

Department of Chemistry, Sungkyunkwan University, Suwon 16419, Korea

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Abstract

Electrocatalytic reduction of CO₂ into high energy-density fuels and value-added chemicals under mild conditions can promote the sustainable cycle of carbon and decrease current energy and environmental problems. Constructing electrocatalyst with high activity, selectivity, stability, and low cost is really matter to realize industrial application of electrocatalytic CO₂ reduction (ECR). Metal–nitrogen–carbon (M–N–C), especially Ni–N–C, display excellent performance, such as nearly 100% CO selectivity, high current density, outstanding tolerance, etc., which is considered to possess broad application prospects. Based on the current research status, starting from the mechanism of ECR and the existence form of Ni active species, the latest research progress of Ni–N–C electrocatalysts in CO₂ electroreduction is systematically summarized. An overview is emphatically interpreted on the regulatory strategies for activity optimization over Ni–N–C, including N coordination modulation, vacancy defects construction, morphology design, surface modification, heteroatom activation, and bimetallic cooperation. Finally, some urgent problems and future prospects on designing Ni–N–C catalysts for ECR are discussed. This review aims to provide the guidance for the design and development of Ni–N–C catalysts with practical application.

Keywords

active sites CO₂ reduction electrocatalysis Ni–N–C electrocatalysts optimization strategies

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Energy & Environmental Materials

Volume 7 Issue 5,
September 2024

Article number: e12731

DOI: 10.1002/eem2.12731

Cite this article:

Pang Q, Fan X, Sun K, et al. Nickel–Nitrogen–Carbon (Ni–N–C) Electrocatalysts Toward CO₂ electroreduction to CO: Advances, Optimizations, Challenges, and Prospects. Energy & Environmental Materials, 2024, 7(5): e12731. https://doi.org/10.1002/eem2.12731

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