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Research Article

Microporous bamboo biochar for lithium-sulfur batteries

Xingxing Gu1, Yazhou Wang1, Chao Lai1, Jingxia Qiu1, Sheng Li1, Yanglong Hou2( ), Wayde Martens3, Nasir Mahmood2, Shanqing Zhang1( )
Centre for Clean Environment and EnergyEnvironmental Futures Research InstituteGriffith School of EnvironmentGold Coast CampusGriffith UniversityGold CoastQLD4222Australia
Department of Materials Science and EngineeringCollege of EngineeringPeking UniversityBeijing100871China
Science and Engineering FacultyQueensland University of TechnologyGold CoastQLD4001Australia
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Abstract

Being simple, inexpensive, scalable and environmentally friendly, microporous biomass biochars have been attracting enthusiastic attention for application in lithium-sulfur (Li-S) batteries. Herein, porous bamboo biochar is activated via a KOH/annealing process that creates a microporous structure, boosts surface area and enhances electronic conductivity. The treated sample is used to encapsulate sulfur to prepare a microporous bamboo carbon-sulfur (BC-S) nanocomposite for use as the cathode for Li-S batteries for the first time. The BC-S nanocomposite with 50 wt.% sulfur content delivers a high initial capacity of 1, 295 mA·h/g at a low discharge rate of 160 mA/g and high capacity retention of 550 mA·h/g after 150 cycles at a high discharge rate of 800 mA/g with excellent coulombic efficiency (≥95%). This suggests that the BC-S nanocomposite could be a promising cathode material for Li-S batteries.

Keywords

biocharslithium-sulfur batteriesmicroporous structurebamboo carbon-sulfur composites

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References

1

Peramunage, D.; Licht, S. A solid sulfur cathode for aqueous batteries. Science 1993, 261, 1029-1032.
Crossref Google Scholar
2

Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. -M. Li-O2 and Li-S batteries with high energy storage. Nature Mater. 2012, 11, 19-29.
Crossref Google Scholar
3

Ji, X. L.; Nazar, L. F. Advances in Li-S batteries. J. Mater. Chem. 2010, 20, 9821-9826.
Crossref Google Scholar
4

Zhang, J.; Xiang, J. Y.; Dong, Z. M.; Liu, Y.; Wu, Y. S.; Xu, C. M.; Du, G. H. Biomass derived activated carbon with 3D connected architecture for rechargeable lithium-sulfur batteries. Electrochim. Acta 2014, 116, 146-151.
Crossref Google Scholar
5

Jayaprakash, N.; Shen, J.; Moganty, S. S.; Corona, A.; Archer, L. A. Porous hollow carbon@sulfur composites for high-power lithium-sulfur batteries. Angew. Chem. Int. Ed. 2011, 50, 5904-5908.
Crossref Google Scholar
6

Zhao, S. R.; Li, C. M.; Wang, W. K.; Zhang, H.; Gao, M. Y.; Xiong, X.; Wang, A. B.; Yuan, K. G.; Huang, Y. Q.; Wang, F. A novel porous nanocomposite of sulfur/carbon obtained from fish scales for lithium-sulfur batteries. J. Mater. Chem. A 2013, 1, 3334-3339.
Crossref Google Scholar
7

Jeddi, K.; Ghaznavi, M.; Chen, P. A novel polymer electrolyte to improve the cycle life of high performance lithium-sulfur batteries. J. Mater. Chem. A 2013, 1, 2769-2772.
Crossref Google Scholar
8

Lee, J. -H.; Lee, H. -Y.; Oh, S. -M.; Lee, S. -J.; Lee, K. -Y.; Lee, S. -M. Effect of carbon coating on electrochemical performance of hard carbons as anode materials for lithium-ion batteries. J. Power Sources 2007, 166, 250-254.
Crossref Google Scholar
9

Zhou, G. M.; Pei, S. F.; Li, L.; Wang, D. W.; Wang, S. G.; Huang, K.; Yin, L. C.; Li, F.; Cheng, H. M. A graphene-pure-sulfur sandwich structure for ultrafast, long-life lithium-sulfur batteries. Adv. Mater. 2014, 26, 625-631.
Crossref Google Scholar
10

Ji, X. L.; Lee, K. T.; Nazar, L. F. A highly ordered nanostructured carbon-sulfur cathode for lithium-sulfur batteries. Nature Mater. 2009, 8, 500-506.
Crossref Google Scholar
11

Xu, G. L.; Xu, Y. F.; Fang, J. C.; Peng, X. X.; Fu, F.; Huang, L.; Li, J. T.; Sun, S. G. Porous graphitic carbon loading ultra high sulfur as high-performance cathode of rechargeable lithium-sulfur batteries. ACS Appl. Mater. Interfaces 2013, 5, 10782-10793.
Crossref Google Scholar
12

He, G.; Evers, S.; Liang, X.; Cuisinier, M.; Garsuch, A.; Nazar, L. F. Tailoring porosity in carbon nanospheres for lithium-sulfur battery cathodes. ACS Nano 2013, 7, 10920-10930.
Crossref Google Scholar
13

Zhang, W. H.; Qiao, D.; Pan, J. X.; Cao, Y. L.; Yang, H. X.; Ai, X. P. A Li+-conductive microporous carbon-sulfur composite for Li-S batteries. Electrochim. Acta 2013, 87, 497-502.
Crossref Google Scholar
14

Xi, K.; Cao, S.; Peng, X. Y.; Ducati, C.; Kumar, R. V.; Cheetham, A. K. Carbon with hierarchical pores from carbonized metal-organic frameworks for lithium sulfur batteries. Chem. Commun. 2013, 49, 2192-2194.
Crossref Google Scholar
15

Tao, X. Y.; Chen, X. R.; Xia, Y.; Huang, H.; Gan, Y. P.; Wu, R.; Chen, F.; Zhang, W. K. Highly mesoporous carbon foams synthesized by a facile, cost-effective and template-free Pechini method for advanced lithium-sulfur batteries. J. Mater. Chem. A 2013, 1, 3295-3301.
Crossref Google Scholar
16

Brun, N.; Sakaushi, K.; Yu, L. H.; Giebeler, L.; Eckert, J.; Titirici, M. M. Hydrothermal carbon-based nanostructured hollow spheres as electrode materials for high-power lithium-sulfur batteries. Phys. Chem. Chem. Phys. 2013, 15, 6080-6087.
Crossref Google Scholar
17

Zhang, K.; Zhao, Q.; Tao, Z. L.; Chen, J. Composite of sulfur impregnated in porous hollow carbon spheres as the cathode of Li-S batteries with high performance. Nano Res. 2013, 6, 38-46.
Crossref Google Scholar
18

Zhou, X. H.; Li, L. F.; Dong, S. M.; Chen, X.; Han, P. X.; Xu, H. X.; Yao, J. H.; Shang, C. Q.; Liu, Z. H.; Cui, G. L. A renewable bamboo carbon/polyaniline composite for a high-performance supercapacitor electrode material. J. Solid State Electrochem. 2012, 16, 877-882.
Crossref Google Scholar
19

Wei, S. C.; Zhang, H.; Huang, Y. Q.; Wang, W. K.; Xia, Y. Z.; Yu, Z. B. Pig bone derived hierarchical porous carbon and its enhanced cycling performance of lithium-sulfur batteries. Energy Environ. Sci. 2011, 4, 736-740.
Crossref Google Scholar
20

Chung, S. H.; Manthiram, A. A natural carbonized leaf as polysulfide diffusion inhibitor for high-performance lithium-sulfur battery cells. ChemSusChem 2014, 7, 1655-1661.
Crossref Google Scholar
21

Tao, X. Y.; Zhang, J. T.; Xia, Y.; Huang, H.; Du, J.; Xiao, H.; Zhang, W. K.; Gan, Y. P. Bio-inspired fabrication of carbon nanotiles for high performance cathode of Li-S batteries. J. Mater. Chem. A 2014, 2, 2290-2296.
Crossref Google Scholar
22

Moreno, N.; Caballero, A.; Hernán, L.; Morales, J. Lithium-sulfur batteries with activated carbons derived from olive stones. Carbon 2014, 70, 241-248.
Crossref Google Scholar
23

Tan, Z. Q.; Sun, L. S.; Xiang, J.; Zeng, H. C.; Liu, Z. H.; Hu, S.; Qiu, J. R. Gas-phase elemental mercury removal by novel carbon-based sorbents. Carbon 2012, 50, 362-371.
Crossref Google Scholar
24

Kannan, N.; Sundaram, M. M. Kinetics and mechanism of removal of methylene blue by adsorption on various carbons-A comparative study. Dyes Pigm. 2001, 51, 25-40.
Crossref Google Scholar
25

Kim, Y. J.; Lee, B. J.; Suezaki, H.; Chino, T.; Abe, Y.; Yanagiura, T.; Park, K. C.; Endo, M. Preparation and characterization of bamboo-based activated carbons as electrode materials for electric double layer capacitors. Carbon 2006, 44, 1592-1595.
Crossref Google Scholar
26

Jiang, J.; Zhu, J. H.; Ai, W.; Fan, Z. X.; Shen, X. N.; Zou, C. J.; Liu, J. P.; Zhang, H.; Yu, T. Evolution of disposable bamboo chopsticks into uniform carbon fibers: A smart strategy to fabricate sustainable anodes for Li-ion batteries. Energy Environ. Sci. 2014, 7, 2670-2679.
Crossref Google Scholar
27

Zhang, B.; Qin, X.; Li, G. R.; Gao, X. P. Enhancement of long stability of sulfur cathode by encapsulating sulfur into micropores of carbon spheres. Energy Environ. Sci. 2010, 3, 1531-1537.
Crossref Google Scholar
28

Wang, J. C.; Kaskel, S. KOH activation of carbon-based materials for energy storage. J. Mater. Chem. 2012, 22, 23710-23725.
Crossref Google Scholar
29

Shinkarev, V. V.; Fenelonov, V. B.; Kuvshinov, G. G. Sulfur distribution on the surface of mesoporous nanofibrous carbon. Carbon 2003, 41, 295-302.
Crossref Google Scholar
30

Zhang, Y. Z.; Liu, S.; Li, G. C.; Li, G. R.; Gao, X. P. Sulfur/polyacrylonitrile/carbon multi-composites as cathode materials for lithium/sulfur battery in the concentrated electrolyte. J. Mater. Chem. A 2014, 2, 4652-4659.
Crossref Google Scholar
31

Zhou, G. M.; Yin, L. C.; Wang, D. W.; Li, L.; Pei, S. F.; Gentle, I. R.; Li, F.; Cheng, H. M. Fibrous hybrid of graphene and sulfur nanocrystals for high-performance lithium-sulfur batteries. ACS Nano 2013, 7, 5367-5375.
Crossref Google Scholar
32

Li, D.; Han, F.; Wang, S.; Cheng, F.; Sun, Q.; Li, W. C. High sulfur loading cathodes fabricated using peapodlike, large pore volume mesoporous carbon for lithium-sulfur battery. ACS Appl. Mater. Interfaces 2013, 5, 2208-2213.
Crossref Google Scholar
33

Li, Z.; Jiang, Y.; Yuan, L. X.; Yi, Z. Q.; Wu, C.; Liu, Y.; Strasser, P.; Huang, Y. H. A highly ordered meso@microporous carbon-supported sulfur@smaller sulfur core-shell structured cathode for Li-S batteries. ACS Nano 2014, 8, 9295-9303.
Crossref Google Scholar
34

Huang, J. Q.; Liu, X. F.; Zhang, Q.; Chen, C. M.; Zhao, M. Q.; Zhang, S. M.; Zhu, W. C.; Qian, W. Z.; Wei, F. Entrapment of sulfur in hierarchical porous graphene for lithium-sulfur batteries with high rate performance from -40 to 60 ℃. Nano Energy 2013, 2, 314-321.
Crossref Google Scholar
35

Ding, B.; Yuan, C. Z.; Shen, L. F.; Xu, G. Y.; Nie, P.; Zhang, X. G. Encapsulating sulfur into hierarchically ordered porous carbon as a high-performance cathode for lithium-sulfur batteries. Chem. -Eur. J. 2013, 19, 1013-1019.
Crossref Google Scholar
36

Zhang, S. S. Sulfurized carbon: A class of cathode materials for high performance lithium/sulfur batteries. Front. Energy Res. 2013, 1, 1-9.
Crossref Google Scholar
37

Wang, Y. X.; Huang, L.; Sun, L. C.; Xie, S. Y.; Xu, G. L.; Chen, S. R.; Xu, Y. F.; Li, J. T.; Chou, S. L.; Dou, S. X.; et al. Facile synthesis of a interleaved expanded graphite-embedded sulfur nanocomposite as cathode of Li-S batteries with excellent lithium storage performance. J. Mater. Chem. 2012, 22, 4744-4750.
Crossref Google Scholar
38

Seh, Z. W.; Li, W. Y.; Cha, J. J.; Zheng, G. Y.; Yang, Y.; McDowell, M. T.; Hsu, P. C.; Cui, Y. Sulfur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulfur batteries. Nature Commun. 2013, 4, 1331-1336.
Crossref Google Scholar
39

Wang, W. G.; Wang, X.; Tian, L. Y.; Wang, Y. L.; Ye, S. H. In situ sulfur deposition route to obtain sulfur-carbon composite cathodes for lithium-sulfur batteries. J. Mater. Chem. A 2014, 2, 4316-4323.
Crossref Google Scholar
40

Ahn, W.; Kim, K. -B.; Jung, K. -N.; Shin, K. -H.; Jin, C. -S. Synthesis and electrochemical properties of a sulfur-multi walled carbon nanotubes composite as a cathode material for lithium sulfur batteries. J. Power Sources 2012, 202, 394-399.
Crossref Google Scholar
41

Choi, H. S.; Oh, J. Y.; Park, C. R. One step synthesis of sulfur-carbon nanosheet hybrids via a solid solvothermal reaction for lithium sulfur batteries. RSC Adv. 2014, 4, 3684-3690.
Crossref Google Scholar
Nano Research
Volume 8 Issue 1,
January 2015
Pages 129-139
DOI: 10.1007/s12274-014-0601-1
Cite this article:
Gu X, Wang Y, Lai C, et al. Microporous bamboo biochar for lithium-sulfur batteries. Nano Research, 2015, 8(1): 129-139. https://doi.org/10.1007/s12274-014-0601-1
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Received: 07 August 2014
Revised: 07 September 2014
Accepted: 01 October 2014
Published: 07 November 2014
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2014
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