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Research Article

Two-dimensional Ni(OH)2 nanoplates for flexible on-chip microsupercapacitors

Hao Wu1,2, Kai Jiang3( ), Shaosong Gu1,†, Hong Yang2, Zheng Lou1, Di Chen4, Guozhen Shen1( )
State Key Laboratory for Superlattices and MicrostructuresInstitute of SemiconductorsChinese Academy of SciencesBeijing100083China
The Key Laboratory of Resource Chemistry of Ministry of EducationShanghai Key Laboratory of Rare Earth Functional Materialsand Shanghai Municipal Education Committee Key Laboratory of Molecular Imaging Probes and SensorsShanghai Normal UniversityShanghai200234China
Institute & Hospital of Hepatobiliary SurgeryKey Laboratory of Digital Hepatobiliary Surgery of Chinese PLAChinese PLA Medical SchoolChinese PLA General HospitalBeijing100853China
School of Mathematics and PhysicsUniversity of Science and Technology BeijingBeijing100083China

† Present address: China University of Mining & Technology, Beijing 100083, China

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Abstract

On-chip microsupercapacitors (MSCs) compatible with on-chip geometries of integrated circuits can be used either as a separate power supply in microelectronic devices or as an energy storage or energy receptor accessory unit. In this work, we report the fabrication of flexible two-dimensional Ni(OH)2 nanoplates-based MSCs, which achieved a specific capacitance of 8.80 F/cm3 at the scan rates of 100 mV/s, losing only 0.20% of its original value after 10, 000 charge/discharge cycles. Besides, the MSCs reached an energy density of 0.59 mWh/cm3 and a power density up to 1.80 W/cm3, which is comparable to traditional carbon-based devices. The flexible MSCs exhibited good electrochemical stability when subjected to bending at various conditions, illustrating the promising application as electrodes for wearable energy storage.

Keywords

nanoplatesNi(OH)2 microsupercapacitorson-chipflexibleall-solid-state

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References

1

Patten, B.; Sánchez, I. A.; Tangney, B. Designing collaborative, constructionist and contextual applications for handheld devices. Comput. Educ. 2006, 46, 294-308.
Crossref Google Scholar
2

Yao, S. C.; Tang, X. D.; Hsieh, C. C.; Alyousef, Y.; Vladimer, M.; Fedder, G. K.; Amon, C. H. Micro-electro-mechanical systems (MEMS)-based micro-scale direct methanol fuel cell development. Energy 2006, 31, 636-649.
Crossref Google Scholar
3

Zhang, J.; Tan, K. L.; Gong, H. Q. Characterization of the polymerization of SU-8 photoresist and its applications in micro-electro-mechanical systems (MEMS). Polym. Test. 2001, 20, 693-701.
Crossref Google Scholar
4

Henzen, A.; van der Kamer, J.; Nakamura, T.; Tsuji, T.; Yasui, M.; Pitt, M.; Duthaler, G.; Amundson, K.; Gates, H.; Zehner, R. Development of active-matrix electronic-ink displays for handheld devices. J. Soc. Inf. Display 2004, 12, 17-22.
Crossref Google Scholar
5

Zhu, Y. G.; Wang, Y.; Shi, Y. M.; Wong, J. I.; Yang, H. Y. CoO nanoflowers woven by CNT network for high energy density flexible micro-supercapacitor. Nano Energy 2014, 3, 46-54.
Crossref Google Scholar
6

Meng, Q. H.; Wu, H. Q.; Meng, Y. N.; Xie, K.; Wei, Z. X.; Guo, Z. X. High-performance all-carbon yarn micro- supercapacitor for an integrated energy system. Adv. Mater. 2014, 26, 4100-4106.
Crossref Google Scholar
7

Sumboja, A.; Foo, C. Y.; Wang, X.; Lee, P. S. Large areal mass, flexible and free-standing reduced graphene oxide/ manganese dioxide paper for asymmetric supercapacitor device. Adv. Mater. 2013, 25, 2809-2815.
Crossref Google Scholar
8

Wu, Z. S.; Parvez, K.; Feng, X. L.; Müllen, K. Graphene- based in-plane micro-supercapacitors with high power and energy densities. Nat. Commun. 2013, 4, 2487.
Crossref Google Scholar
9

Rolison, D. R.; Long, J. W.; Lytle, J. C.; Fischer, A. E.; Rhodes, C. P.; McEvoy, T. M.; Bourgm, M. E.; Lubers, A. M. Multifunctional 3D nanoarchitectures for energy storage and conversion. Chem. Soc. Rev. 2009, 38, 226-252.
Crossref Google Scholar
10

Wang, Y.; Shi, Y. M.; Zhao, C. X.; Wong, J. I.; Sun, X. W.; Yang, H. Y. Printed all-solid flexible microsupercapacitors: Towards the general route for high energy storage devices. Nanotechnology 2014, 25, 094010.
Crossref Google Scholar
11

Sung, J. H.; Kim, S. J.; Jeong, S. H.; Kim, E. H.; Lee, K. H. Flexible micro-supercapacitors. J. Power Sources 2006, 162, 1467-1470.
Crossref Google Scholar
12

Chmiola, J.; Largeot, C.; Taberna, P. L.; Simon, P.; Gogotsi, Y. Monolithic carbide-derived carbon films for micro- supercapacitors. Science 2010, 328, 480-483.
Crossref Google Scholar
13

Pech, D.; Brunet, M.; Durou, H.; Huang, P. H.; Mochalin, V.; Gogotsi, Y.; Taberna, P. L.; Simon, P. Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. Nat. Nanotechnol. 2010, 5, 651-654.
Crossref Google Scholar
14

Xu, J.; Shen, G. Z. A flexible integrated photodetector system driven by on-chip microsupercapacitors. Nano Energy 2015, 13, 131-139.
Crossref Google Scholar
15

El-Kady, M. F.; Kaner, R. B. Scalable fabrication of high- power graphene micro-supercapacitors for flexible and on- chip energy storage. Nat. Commun. 2013, 4, 1475.
Crossref Google Scholar
16

Lee, G.; Kim, D.; Yun, J.; Ko, Y. M.; Cho, J.; Ha, J. S. High-performance all-solid-state flexible micro-supercapacitor arrays with layer-by-layer assembled MWNT/MnOx nanocomposite electrodes. Nanoscale 2014, 6, 9655-9664.
Crossref Google Scholar
17

Wu, Z. K.; Lin, Z. Y.; Li, L. Y.; Song, B.; Moon, K. S.; Bai, S. L.; Wong, C. P. Flexible micro-supercapacitor based on in-situ assembled graphene on metal template at room temperature. Nano Energy 2014, 10, 222-228.
Crossref Google Scholar
18

Peng, L. L.; Peng, X.; Liu, B. R.; Wu, C. Z.; Xie, Y.; Yu, G. H. Ultrathin two-dimensional MnO2/graphene hybrid nanostructures for high-performance, flexible planar supercapacitors. Nano Lett. 2013, 13, 2151-2157.
Crossref Google Scholar
19

Liu, W. W.; Feng, Y. Q.; Yan, X. B.; Chen, J. T.; Xue, Q. J. Superior micro-supercapacitors based on graphene quantum dots. Adv. Funct. Mater. 2013, 23, 4111-4122.
Crossref Google Scholar
20

Huang, P. H.; Pech, D.; Lin, R. Y.; McDonough, J. K.; Brunet, M.; Taberna, P. L.; Gogotsi, Y.; Simon, P. On-chip micro- supercapacitors for operation in a wide temperature range. Electrochem. Commun. 2013, 36, 53-56.
Crossref Google Scholar
21

Hsia, B.; Marschewski, J.; Wang, S.; In, J. B.; Carraro, C.; Poulikakos, D.; Grigoropoulos, C. P.; Maboudian, R. Highly flexible, all solid-state micro-supercapacitors from vertically aligned carbon nanotubes. Nanotech 2014, 25, 055401.
Crossref Google Scholar
22

Xiong, G. P.; Meng, C. Z.; Reifenberger, R. G.; Irazoqui, P. P.; Fisher, T. S. A review of graphene-based electrochemical microsupercapacitors. Electroanalysis 2014, 26, 30-51.
Crossref Google Scholar
23

Niu, Z. Q.; Zhang, L.; Liu, L. L.; Zhu, B. W.; Dong, H. B.; Chen, X. D. All-solid-state flexible ultrathin micro- supercapacitors based on graphene. Adv. Mater. 2013, 25, 4035-4042.
Crossref Google Scholar
24

Gao, W.; Singh, N.; Song, L.; Liu, Z.; Reddy, A. L. M.; Ci, L. J.; Vajtai, R.; Zhang, Q.; Wei, B. Q.; Ajayan, P. M. Direct laser writing of micro-supercapacitors on hydrated graphite oxide films. Nat. Nanotechnol. 2011, 6, 496-500.
Crossref Google Scholar
25

Lin, J.; Zhang, C. G.; Yan, Z.; Zhu, Y.; Peng, Z. W.; Hauge, R. H.; Natelson, D.; Tour, J. M. 3-dimensional graphene carbon nanotube carpet-based microsupercapacitors with high electrochemical performance. Nano Lett. 2013, 13, 72-78.
Crossref Google Scholar
26

Beidaghi, M.; Wang, C. L. Micro-supercapacitors based on three dimensional interdigital polypyrrole/C-MEMS electrodes. Electrochim. Acta 2011, 56, 9508-9514.
Crossref Google Scholar
27

Beidaghi, M.; Wang, C. L. Micro-supercapacitors based on interdigital electrodes of reduced graphene oxide and carbon nanotube composites with ultrahigh power handling performance. Adv. Funct. Mater. 2012, 22, 4501-4510.
Crossref Google Scholar
28

Wu, C. Z.; Lu, X. L.; Peng, L. L.; Xu, K.; Peng, X.; Huang, J. L.; Yu, G. H.; Xie, Y. Two-dimensional vanadyl phosphate ultrathin nanosheets for high energy density and flexible pseudocapacitors. Nat. Commun. 2013, 4, 2431.
Crossref Google Scholar
29

Han, J. H.; Lin, Y. C.; Chen, L. Y.; Tsai, Y. C.; Ito, Y.; Guo, X. W.; Hirata, A.; Fujita, T.; Esashi, M.; Gessner, T. et al. On- chip micro-pseudocapacitors for ultrahigh energy and power delivery. Adv. Sci. 2015, 2, DOI: 10.1002/advs.201500067.
Crossref Google Scholar
30

Zhang, G. Q.; Yu, L.; Hoster, H. E.; Lou, X. W. Synthesis of one-dimensional hierarchical NiO hollow nanostructures with enhanced supercapacitive performance. Nanoscale 2013, 5, 877-881.
Crossref Google Scholar
31

Wang, B.; Chen, J. S.; Wang, Z. Y.; WMadhavi, S.; Lou, X. W. Green synthesis of NiO nanobelts with exceptional pseudo-capacitive properties. Adv. Energy Mater. 2012, 2, 1188-1192.
Crossref Google Scholar
32

Shen, L. F.; Yu, L.; Yu, X. Y.; Zhang, X. G.; Lou, X. W. Self- templated formation of uniform NiCo2O4 hollow spheres with complex interior structures for lithium-ion batteries and supercapacitors. Angew. Chem., Int. Ed. 2015, 54, 1868-1872.
Crossref Google Scholar
33

Xu, Y. X.; Huang, X. Q.; Lin, Z. Y.; Zhong, X.; Huang, Y.; Duan, X. F. One-step strategy to graphene/Ni(OH)2 composite hydrogels as advanced hree-dimensional supercapacitor electrode materials. Nano Res. 2013, 6, 65-76.
Crossref Google Scholar
34

Zhu, J. W.; Chen, S.; Zhou, H.; Wang, X. Fabrication of a low defect density graphene-nickel hydroxide nanosheet hybrid with enhanced electrochemical performance. Nano Res. 2012, 5, 11-19.
Crossref Google Scholar
35

Wang, H. L.; Holt, C. M. B.; Li, Z.; Tan, X. H.; Amirkhiz, B. S.; Xu, Z. W.; Olsen, B. C.; Stephenson, T.; Mitlin, D. Graphene-nickel cobaltite nanocomposite asymmetrical supercapacitor with commercial level mass loading. Nano Res. 2012, 5, 605-617.
Crossref Google Scholar
36

Xiao, X. L.; Liu, X. F.; Wang, L.; Zhao, H.; Hu, Z. B.; He, X. M.; Li, Y. D. LiCoO2 nanoplates with exposed (001) planes and high rate capability for lithium-ion batteries. Nano Res. 2012, 5, 395-401.
Crossref Google Scholar
37

Su, D. W.; Dou, S. X.; Wang, G. X. Mesocrystal Co3O4 nanoplatelets as high capacity anode materials for Li-ion batteries. Nano Res. 2014, 7, 794-803.
Crossref Google Scholar
38

Lee, C. W.; Seo, S. D.; Kim, D. W.; Park, S.; Jin, K.; Kim, D. W; Hong, K. S. Heteroepitaxial growth of ZnO nanosheet bands on ZnCo2O4 submicron rods toward high-performance Li ion battery electrodes. Nano Res. 2013, 6, 348-355.
Crossref Google Scholar
39

Wang, Q. F.; Wang, X. F.; Xu, J.; Ouyang, X.; Hou, X. J.; Chen, D.; Wang, R. M.; Shen, G. Z. Flexible coaxial-type fiber supercapacitor based on NiCo2O4 nanosheets electrodes. Nano Energy 2014, 8, 44-51.
Crossref Google Scholar
40

Ren, Y. M.; Wang, L.; Dai, Z. J.; Huang, X. K.; Li, J. J.; Chen, N.; Gao, J.; Zhao, H. L.; Sun, X. M.; He, X. M. Hydrothermal synthesis of β-Ni(OH)2 nanoplates as electrochemical pseudocapacitor materials. Int. J. Electrochem. Sci. 2012, 7, 12236-12243.
Google Scholar
41

Alhebshi, N. A.; Rakhi, R. B.; Alshareef, H. N. Conformal coating of Ni(OH)2 nanoflakes on carbon fibers by chemical bath deposition for efficient supercapacitor electrodes. J. Mater. Chem. A. 2013, 1, 14897-14903.
Crossref Google Scholar
42

Xu, J.; Wu, H.; Lu, L. F.; Leung, S. F.; Chen, D.; Chen, X. Y.; Fan, Z. Y.; Shen, G. Z.; Li, D. D. Integrated photo- supercapacitor based on Bi-polar TiO2 nanotube arrays with selective one-side plasma-assisted hydrogenation. Adv. Funct. Mater. 2014, 24, 1840-1846.
Crossref Google Scholar
43

Wu, H.; Lou, Z.; Yang, H.; Shen, G. Z. A flexible spiral-type supercapacitor based on ZnCo2O4 nanorod electrodes. Nanoscale 2015, 7, 1921-1926.
Crossref Google Scholar
44

Kurra, N.; Alhebshi, N. A.; Alshareef, H. N. Microfabricated pseudocapacitors using Ni(OH)2 electrodes exhibit remarkable volumetric capacitance and energy density. Adv. Energy Mater. 2015, 5, DOI: 10.1002/aenm.201401303.
Crossref Google Scholar
45

Jiang, H.; Zhao, T.; Li, C. Z.; Ma, J. Hierarchical self-assembly of ultrathin nickel hydroxide nanoflakes for high-performance supercapacitors. J. Mater. Chem. 2011, 21, 3818-3823.
Crossref Google Scholar
46

Lim, B. Y.; Yoon, J. Y.; Yun, J. Y.; Kim, D.; Hong, S. Y.; Lee, S. J.; Zi, G.; Ha, J. S. Biaxially stretchable, integrated array of high performance microsupercapacitors. ACS Nano 2014, 8, 11639-11650.
Crossref Google Scholar
47

Sun, C. L.; Shi, J.; Bayerl, D. J.; Wang, X. D. PVDF microbelts for harvesting energy from respiration. Energy Environ. Sci. 2011, 4, 4508-4512.
Crossref Google Scholar
Nano Research
Volume 8 Issue 11,
November 2015
Pages 3544-3552
DOI: 10.1007/s12274-015-0854-3
Cite this article:
Wu H, Jiang K, Gu S, et al. Two-dimensional Ni(OH)2 nanoplates for flexible on-chip microsupercapacitors. Nano Research, 2015, 8(11): 3544-3552. https://doi.org/10.1007/s12274-015-0854-3

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Received: 05 May 2015
Revised: 29 June 2015
Accepted: 05 July 2015
Published: 14 September 2015
© Tsinghua University Press and Springer‐Verlag Berlin Heidelberg 2015
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