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Research Article

Confined growth of Li4Ti5O12 nanoparticles in nitrogen-doped mesoporous graphene fibers for high-performance lithium-ion battery anodes

Xilai Jia1, Yunfeng Lu3( ), Fei Wei2 ( )
State Key Laboratory of Heavy Oil ProcessingChina University of PetroleumBeijing102249China
Beijing Key Laboratory of Green Chemical Reaction Engineering and TechnologyDepartment of Chemical EngineeringTsinghua UniversityBeijing100084China
Department of Chemical and Biomolecular EngineeringUniversity of CaliforniaLos AngelesCA90095USA
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Abstract

Nanomaterials with electrochemical activity are always suffering from aggregations, particularly during the high-temperature synthesis processes, which will lead to decreased energy-storage performance. Here, hierarchically structured lithium titanate/nitrogen-doped porous graphene fiber nanocomposites were synthesized by using confined growth of Li4Ti5O12 (LTO) nanoparticles in nitrogen-doped mesoporous graphene fibers (NPGF). NPGFs with uniform pore structure are used as templates for hosting LTO precursors, followed by high-temperature treatment at 800 ℃ under argon (Ar). LTO nanoparticles with size of several nanometers are successfully synthesized in the mesopores of NPGFs, forming nanostructured LTO/NPGF composite fibers. As an anode material for lithium-ion batteries, such nanocomposite architecture offers effective electron and ion transport, and robust structure. Such nanocomposites in the electrodes delivered a high reversible capacity (164 mAh·g–1 at 0.3 C), excellent rate capability (102 mAh·g–1 at 10 C), and long cycling stability.

Keywords

lithium titanatenitrogen-doped porous graphene fiberslithium-ion batteries

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Nano Research
Volume 9 Issue 1,
January 2016
Pages 230-239
DOI: 10.1007/s12274-016-1001-5
Cite this article:
Jia X, Lu Y, Wei F. Confined growth of Li4Ti5O12 nanoparticles in nitrogen-doped mesoporous graphene fibers for high-performance lithium-ion battery anodes. Nano Research, 2016, 9(1): 230-239. https://doi.org/10.1007/s12274-016-1001-5
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Received: 30 October 2015
Revised: 04 January 2016
Accepted: 04 January 2016
Published: 19 January 2016
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2016
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