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Cost-effective hydrogen production via electrolysis of water requires efficient and durable earth-abundant catalysts for the hydrogen evolution reaction (HER) over a wide pH range. Herein, we report sponge-like nickel phosphide– carbon nanotube (NixP/CNT) hybrid electrodes that were prepared by facile cyclic voltammetric deposition of amorphous NixP catalysts onto the three- dimensional (3D) porous CNT support. These compounds exhibit superior catalytic activity for sustained hydrogen evolution in acidic, neutral, and basic media. In particular, the NixP/CNT electrodes generate cathodic currents of 10 and 100 mA∙cm-2 at overpotentials of 105 and 226 mV, respectively, in a 1 M phosphate buffer solution (pH = 6.5) with a Tafel slope of 100 mV∙dec-1; the currents were stable for over 110 h without obvious decay. Our results suggest that the 3D porous CNT electrode supports could serve as a general platform for earth-abundant HER catalysts for the development of highly efficient electrodes for hydrogen production.
Lewis, N. S. Research opportunities to advance solar energy utilization. Science 2016, 351, DOI: 10.1126/science.aad1920.
Sivula, K.; van de Krol, R. Semiconducting materials for photoelectrochemical energy conversion. Nat. Rev. Mater. 2016, 1, 15010.
Zou, X. X.; Zhang, Y. Noble metal-free hydrogen evolution catalysts for water splitting. Chem. Soc. Rev. 2015, 44, 5148−5180.
Trasatti, S. Work function, electronegativity, and electrochemical behaviour of metals: III. Electrolytic hydrogen evolution in acid solutions. J. Electroanal. Chem. Interfacial Electrochem. 1972, 39, 163−184.
Vesborg, P. C. K.; Seger, B.; Chorkendorff, I. Recent development in hydrogen evolution reaction catalysts and their practical implementation. J. Phys. Chem. Lett. 2015, 6, 951−957.
Benck, J. D.; Hellstern, T. R.; Kibsgaard, J.; Chakthranont, P.; Jaramillo, T. F. Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials. ACS Catal. 2014, 4, 3957−3971.
Faber, M. S.; Jin, S. Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications. Energy Environ. Sci. 2014, 7, 3519−3542.
Morales-Guio, C. G.; Hu, X. L. Amorphous molybdenum sulfides as hydrogen evolution catalysts. Acc. Chem. Res. 2014, 47, 2671−2681.
McKone, J. R.; Sadtler, B. F.; Werlang, C. A.; Lewis, N. S.; Gray, H. B. Ni−Mo nanopowders for efficient electrochemical hydrogen evolution. ACS Catal. 2013, 3, 166−169.
Safizadeh, F.; Ghali, E.; Houlachi, G. Electrocatalysis developments for hydrogen evolution reaction in alkaline solutions—A review. Int. J. Hydrogen Energy 2015, 40, 256−274.
Kibsgaard, J.; Chen, Z. B.; Reinecke, B. N.; Jaramillo, T. F. Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis. Nat. Mater. 2012, 11, 963−969.
Laursen, A. B.; Kegnæs, S.; Dahl, S.; Chorkendorff, I. Molybdenum sulfides-efficient and viable materials for electro- and photoelectrocatalytic hydrogen evolution. Energy Environ. Sci. 2012, 5, 5577−5591.
Faber, M. S.; Lukowski, M. A.; Ding, Q.; Kaiser, N. S.; Jin, S. Earth-abundant metal pyrites (FeS2, CoS2, NiS2, and their alloys) for highly efficient hydrogen evolution and polysulfide reduction electrocatalysis. J. Phys. Chem. C 2014, 118, 21347−21356.
Merki, D.; Fierro, S.; Vrubel, H.; Hu, X. L. Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water. Chem. Sci. 2011, 2, 1262−1267.
Kong, D.; Cha, J. J.; Wang, H. T.; Lee, H. R.; Cui, Y. First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction. Energy Environ. Sci. 2013, 6, 3553−3558.
Popczun, E. J.; Mckone, J. R.; Read, C. G.; Biacchi, A. J.; Wiltrout, A. M.; Lewis, N. S.; Schaak, R. E. Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction. J. Am. Chem. Soc. 2013, 135, 9267−9270.
Feng, L. G.; Vrubel, H.; Bensimon, M.; Hu, X. L. Easily- prepared dinickel phosphide (Ni2P) nanoparticles as an efficient and robust electrocatalyst for hydrogen evolution. Phys. Chem. Chem. Phys. 2014, 16, 5917−5921.
Popczun, E. J.; Read, C. G.; Roske, C. W.; Lewis, N. S.; Schaak, R. E. Highly active electrocatalysis of the hydrogen evolution reaction by cobalt phosphide nanoparticles. Angew. Chem., Int. Ed. 2014, 53, 5427−5430.
McEnaney, J. M.; Crompton, J. C.; Callejas, J. F.; Popczun, E. J.; Biacchi, A. J.; Lewis, N. S.; Schaak, R. E. Amorphous molybdenum phosphide nanoparticles for electrocatalytic hydrogen evolution. Chem. Mater. 2014, 26, 4826−4831.
Pan, Y.; Liu, Y. R.; Zhao, J. C.; Yang, K.; Liang, J. L.; Liu, D. D.; Hu, W. H.; Liu, D. P.; Liu, Y. Q.; Liu, C. G. Monodispersed nickel phosphide nanocrystals with different phases: Synthesis, characterization and electrocatalytic properties for hydrogen evolution. J. Mater. Chem. A 2015, 3, 1656−1665.
Pan, Y.; Hu, W. H.; Liu, D. P.; Liu, Y. Q.; Liu, C. G. Carbon nanotubes decorated with nickel phosphide nanoparticles as efficient nanohybrid electrocatalysts for the hydrogen evolution reaction. J. Mater. Chem. A 2015, 3, 13087−13094.
Cabán-Acevedo, M.; Stone, M. L.; Schmidt, J. R.; Thomas, J. G.; Ding, Q.; Chang, H. -C.; Tsai, M. -L.; He, J. -H.; Jin, S. Efficient hydrogen evolution catalysis using ternary pyrite- type cobalt phosphosulphide. Nat. Mater. 2015, 14, 1245−1251.
Zhuo, J. Q.; Cabán-Acevedo, M.; Liang, H. F.; Samad, L.; Ding, Q.; Fu, Y. P.; Li, M. X.; Jin, S. High-performance electrocatalysis for hydrogen evolution reaction using Se- doped pyrite-phase nickel diphosphide nanostructures. ACS Catal. 2015, 5, 6355−6361.
Liu, Q.; Tian, J. Q.; Cui, W.; Jiang, P.; Cheng, N. Y.; Asiri, A. M.; Sun, X. P. Carbon nanotubes decorated with CoP nanocrystals: A highly active non-noble-metal nanohybrid electrocatalyst for hydrogen evolution. Angew. Chem. 2014, 126, 6828−6832.
Tian, J. Q.; Liu, Q.; Cheng, N. Y.; Asiri, A. M.; Sun, X. P. Self-supported Cu3P nanowire arrays as an integrated high-performance three-dimensional cathode for generating hydrogen from water. Angew. Chem., Int. Ed. 2014, 53, 9577−9581.
Vrubel, H.; Hu, X. L. Molybdenum boride and carbide catalyze hydrogen evolution in both acidic and basic solutions. Angew. Chem., Int. Ed. 2012, 51, 12703−12706.
Chen, W. -F.; Wang, C. -H.; Sasaki, K.; Marinkovic, N.; Xu, W.; Muckerman, J. T.; Zhu, Y.; Adzic, R. R. Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production. Energy Environ. Sci. 2013, 6, 943−951.
Michalsky, R.; Zhang, Y. -J.; Peterson, A. A. Trends in the hydrogen evolution activity of metal carbide catalysts. ACS Catal. 2014, 4, 1274−1278.
Zheng, Y.; Jiao, Y.; Zhu, Y. H.; Li, L. H.; Han, Y.; Chen, Y.; Du, A. J.; Jaroniec, M.; Qiao, S. Z. Hydrogen evolution by a metal-free electrocatalyst. Nat. Commun. 2014, 5, 3783.
Huang, Z. P.; Chen, Z. B.; Chen, Z. Z.; Lv, C. C.; Meng, H.; Zhang, C. Ni12P5 nanoparticles as an efficient catalyst for hydrogen generation via electrolysis and photoelectrolysis. ACS Nano 2014, 8, 8121−8129.
Ledendecker, M.; Krick Calderón, S.; Papp, C.; Steinrück, H. -P.; Antonietti, M.; Shalom, M. The synthesis of nanostructured Ni5P4 films and their use as a non-noble bifunctional electrocatalyst for full water splitting. Angew. Chem., Int. Ed. 2015, 54, 12361−12365.
Rolison, D. R.; Long, J. W.; Lytle, J. C.; Fischer, A. E.; Rhodes, C. P.; McEvoy, T. M.; Bourga, M. E.; Lubers, A. M. Multifunctional 3D nanoarchitectures for energy storage and conversion. Chem. Soc. Rev. 2009, 38, 226−252.
Chang, Y. -H.; Lin, C. -T.; Chen, T. -Y.; Hsu, C. -L.; Lee, Y. -H.; Zhang, W. J.; Wei, K. -H.; Li, L. -J. Highly efficient electrocatalytic hydrogen production by MoSx grown on graphene-protected 3D Ni foams. Adv. Mater. 2013, 25, 756−760.
Cao, X. H.; Yin, Z. Y.; Zhang H. Three-dimensional graphene materials: Preparation, structures and application in supercapacitors. Energy Environ. Sci. 2014, 7, 1850−1865.
Nardecchia, S.; Carriazo, D.; Ferrer, M. L.; Gutiérrez, M. C.; del Monte, F. Three dimensional macroporous architectures and aerogels built of carbon nanotubes and/or graphene: Synthesis and applications. Chem. Soc. Rev. 2013, 42, 794−830.
Gui, X. C.; Wei, J. Q.; Wang, K. L.; Cao, A. Y.; Zhu, H. W.; Jia, Y.; Shu, Q. K.; Wu, D. H. Carbon nanotube sponges. Adv. Mater. 2010, 22, 617−621.
Li, P. X.; Kong, C. Y.; Shang, Y. Y.; Shi, E. Z.; Yu, Y. T.; Qian, W. Z.; Wei, F.; Wei, J. Q.; Wang, K. L.; Zhu, H. W. et al. Highly deformation-tolerant carbon nanotube sponges as supercapacitor electrodes. Nanoscale 2013, 5, 8472−8479.
Zou, M. C.; Ma, Z. M.; Wang, Q. F.; Yang, Y. B.; Wu, S. T.; Yang, L. S.; Hu, S.; Xu, W. J.; Han, P. C.; Zou, R. Q. et al. Caxialo TiO2−carbon nanotube sponges as compressible anodes for lithium-ion batteries. J. Mater. Chem. A 2016, 4, 7398−7405.
Gui, X. C.; Cao, A. Y.; Wei, J. Q.; Li, H. B.; Jia, Y.; Li, Z.; Fan, L. L.; Wang, K. L.; Zhu, H. W.; Wu, D. H. Soft, highly conductive nanotube sponges and composites with controlled compressibility. ACS Nano 2010, 4, 2320−2326.
Zhong, J.; Yang, Z. Y.; Mukherjee, R.; Thomas, A. V.; Zhu, K.; Sun, P. Z.; Lian, J.; Zhu, H. W.; Koratkar, N. Carbon nanotube sponges as conductive networks for supercapacitor devices. Nano Energy 2013, 2, 1025−1030.
Ma, L.; Ting, L. R. L.; Molinari, V.; Giordano, C.; Yeo, B. S. Efficient hydrogen evolution reaction catalyzed by molybdenum carbide and molybdenum nitride nanocatalysts synthesized via the urea glass route. J. Mater. Chem. A 2015, 3, 8361−8368.
McCrory, C. C. L.; Jung, S.; Peters, J. C.; Jaramillo, T. F. Benchmarking heterogeneous electrocatalysts for the oxygen evolution reaction. J. Am. Chem. Soc. 2013, 135, 16977− 16987
Benck, J. D.; Chen, Z. B.; Kuritzky, L. Y.; Forman, A. J.; Jaramillo, T. F. Amorphous molybdenum sulfide catalysts for electrochemical hydrogen production: Insights into the origin of their catalytic activity. ACS Catal. 2012, 2, 1916−1923.
Sawhill, S. J.; Layman, K. A.; Van Wyk, D. R.; Engelhard, M. H.; Wang, C. M.; Bussell, M. E. Thiophene hydridesulfurization over nickel phosphide catalysts: Effect of the precursor composition and support. J. Catal. 2005, 231, 300−313.
Korányi, T. I.; Vit, Z.; Poduval, D. G.; Ryoo, R.; Kim, H. S.; Hensen, E. J. M. SBA-15-supported nickel phosphide hydrotreating catalysts. J. Catal. 2008, 253, 119−131.
Yu, X. -Y.; Feng, Y.; Guan, B. Y.; Lou, X. W. D.; Paik, U. Carbon coated porous nickel phosphides nanoplates for highly efficient oxygen evolution reaction. Energy Environ. Sci. 2016, 9, 1246−1250.
Stern, L. -A.; Feng, L. G.; Song, F.; Hu, X. L. Ni2P as a Janus catalyst for water splitting; the oxygen evolution activity of Ni2P nanoparticles. Energy Environ. Sci. 2015, 8, 2347−2351.
Zhu, Y. -P.; Liu, Y. -P.; Ren, T. -Z.; Yuan, Z. -Y. Self-supported cobalt phosphide mesoporous nanorod arrays: A flexible and bifunctional electrode for highly active electrocatalytic water reduction and oxidation. Adv. Funct. Mater. 2015, 25, 7337−7347.
Cobo, S.; Heidkamp, J.; Jacques, P. -A.; Fize, J.; Fourmond, V.; Guetaz, L.; Jousselme, B.; Ivanova, V.; Dau, H.; Palacin, S. et al. A Janus cobalt-based catalytic material for electro- splitting of water. Nat. Mater. 2012, 11, 802−807.
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