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Review Article

Defect-rich MoS2 nanowall catalyst for efficient hydrogen evolution reaction

Junfeng Xie1,2( ), Haichao Qu1, Jianping Xin1, Xinxia Zhang1, Guanwei Cui1, Xiaodong Zhang2, Jian Bao2, Bo Tang1, Yi Xie2( )
College of ChemistryChemical Engineering and Materials ScienceCollaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of ShandongKey Laboratory of Molecular and Nano ProbesMinistry of EducationInstitute of Molecular and Nano ScienceShandong Normal UniversityJinan250014China
Hefei National Laboratory for Physical Sciences at the MicroscaleDepartment of ChemistryUniversity of Science and Technology of ChinaHefei230026China
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Abstract

Designing efficient electrocatalysts for the hydrogen evolution reaction (HER) has attracted substantial attention owing to the urgent demand for clean energy to face the energy crisis and subsequent environmental issues in the near future. Among the large variety of HER catalysts, molybdenum disulfide (MoS2) has been regarded as the most famous catalyst owing to its abundance, low price, high efficiency, and definite catalytic mechanism. In this study, defect-engineered MoS2 nanowall (NW) catalysts with controllable thickness were fabricated and exhibited a significantly enhanced HER performance. Benefiting from the highly exposed active edge sites and the rough surface accompanied by the robust NW structure, the defect-rich MoS2 NW catalyst with an optimized thickness showed an ultralow onset overpotential of 85 mV, a high current density of 310.6 mA·cm-2 at η = 300 mV, and a low potential of 95 mV to drive a 10 mA·cm-2 cathodic current. Additionally, excellent electrochemical stability was realized, making this freestanding NW catalyst a promising candidate for practical water splitting and hydrogen production.

Keywords

molybdenum disulfide (MoS2)nanowallwater splittingelectrocatalysishydrogen evolution reaction

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Nano Research
Volume 10 Issue 4,
April 2017
Pages 1178-1188
DOI: 10.1007/s12274-017-1421-x
Cite this article:
Xie J, Qu H, Xin J, et al. Defect-rich MoS2 nanowall catalyst for efficient hydrogen evolution reaction. Nano Research, 2017, 10(4): 1178-1188. https://doi.org/10.1007/s12274-017-1421-x
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Received: 20 November 2016
Revised: 10 December 2016
Accepted: 15 December 2016
Published: 07 March 2017
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2017
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