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Research Article

Flower-like C@SnOX@C hollow nanostructures with enhanced electrochemical properties for lithium storage

Yijia Wang1, Zheng Jiao2, Minghong Wu2, Kun Zheng3, Hongwei Zhang4, Jin Zou3, Chengzhong Yu4( ), Haijiao Zhang1( )
Institute of Nanochemistry and NanobiologyShanghai UniversityShanghai200444China
School of Environmental and Chemical EngineeringShanghai UniversityShanghai200444China
Materials Engineering and Centre for Microscopy and MicroanalysisThe University of QueenslandBrisbaneQLD4072Australia
Australian Institute for Bioengineering and NanotechnologyThe University of QueenslandBrisbaneQLD4072Australia
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Graphical Abstract

Abstract

Hollow nanostructures have attracted considerable attention owing to their large surface area, tunable cavity, and low density. In this study, a unique flower-like C@SnOX@C hollow nanostructure (denoted as C@SnOX@C-1) was synthesized through a novel one-pot approach. The C@SnOX@C-1 had a hollow carbon core and interlaced petals on the shell. Each petal was a SnO2 nanosheet coated with an ultrathin carbon layer ~2 nm thick. The generation of the hollow carbon core, the growth of the SnO2 nanosheets, and the coating of the carbon layers were simultaneously completed via a hydrothermal process using resorcinol-formaldehyde resin-coated SiO2 nanospheres, tin chloride, urea, and glucose as precursors. The resultant architecture with a large surface area exhibited excellent lithium-storage performance, delivering a high reversible capacity of 756.9 mA·h·g–1 at a current density of 100 mA·g–1 after 100 cycles.

Keywords

C@SnOX@Chollow nanostructurenanosheetscarbon coatinganodes

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Nano Research
Volume 10 Issue 9,
September 2017
Pages 2966-2976
DOI: 10.1007/s12274-017-1507-5
Cite this article:
Wang Y, Jiao Z, Wu M, et al. Flower-like C@SnOX@C hollow nanostructures with enhanced electrochemical properties for lithium storage. Nano Research, 2017, 10(9): 2966-2976. https://doi.org/10.1007/s12274-017-1507-5

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Received: 24 November 2016
Revised: 19 January 2017
Accepted: 03 February 2017
Published: 18 May 2017
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2017
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