AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

Hierarchical Sb-Ni nanoarrays as robust binder-free anodes for high-performance sodium-ion half and full cells

Liying Liang1, Yang Xu1, Liaoyong Wen1, Yueliang Li2, Min Zhou1, Chengliang Wang1, Huaping Zhao1, Ute Kaiser2, Yong Lei1( )
Institute of Physics & IMN MacroNano (ZIK) Ilmenau University of Technology, Professor Schmidt Strasse 26 98693 Ilmenau Germany
Central Facility for Electron Microscopy, Electron Microscopy Group of Materials Science Ulm University, Albert-Einstein-Allee 11 89081 Ulm Germany
Show Author Information

Graphical Abstract

Abstract

A novel hierarchical electrode material for Na-ion batteries composed of Sb nanoplates on Ni nanorod arrays is developed to tackle the issues of the rapid capacity fading and poor rate capability of Sb-based materials. The three- dimensional (3D) Sb-Ni nanoarrays as anodes exhibit the synergistic effects of the two-dimensional nanoplates and the open and conductive array structure as well as strong structural integrity. Further, their capacitive behavior is confirmed through a kinetics analysis, which shows that their excellent Na-storage performance is attributable to their unique nanostructure. When used as binder-free sodium-ion battery (SIB) anodes, the nanoarrays exhibit a high capacity retention rate (more than 80% over 200 cycles) at a current density of 0.5 A·g–1 and excellent rate capacity (up to 20 A·g–1), with their capacity being 580 mAh·g–1. Moreover, a P2-Na2/3Ni1/3Mn2/3O2//3D Sb-Ni nanoarrays full cell delivers a highly reversible capacity of 579.8 mAh·g–1 over 200 cycles and an energy density as high as 100 Wh·kg–1. This design strategy for ensuring fast and stable Na storage may work with other electrode materials as well.

Keywords

hierarchical Sb-Ni nanoarraysbinder-free anodecapacitive charge storageNa-ion full cell

Electronic Supplementary Material

Download File(s)
nr-10-9-3189_ESM.pdf (2.9 MB)

References

1

Hasa, I.; Passerini, S.; Hassoun, J. A rechargeable sodium-ion battery using a nanostructured Sb–C anode and P2-type layered Na0.6Ni0.22Fe0.11Mn0.66O2 cathode. RSC Adv. 2015, 5, 48928–48934.
Crossref Google Scholar
2

Palomares, V.; Serras, P.; Villaluenga, I.; Hueso, K. B.; Carretero-González, J.; Rojo, T. Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ. Sci. 2012, 5, 5884–5901.
Crossref Google Scholar
3

Kim, S. W.; Seo, D. H.; Ma, X. H.; Ceder, G.; Kang, K. Electrode materials for rechargeable sodium-ion batteries: Potential alternatives to current lithium-ion batteries. Adv. Energy Mater. 2012, 2, 710–721.
Crossref Google Scholar
4

Hong, S. Y.; Kim, Y.; Park, Y.; Choi, A.; Choi, N.-S.; Lee, K. T. Charge carriers in rechargeable batteries: Na ions vs. Li ions. Energy Environ. Sci. 2013, 6, 2067–2081.
Crossref Google Scholar
5

Slater, M. D.; Kim, D.; Lee, E.; Johnson, C. S. Sodium-ion batteries. Adv. Funct. Mater. 2013, 23, 947–958.
Crossref Google Scholar
6

Stevens, D. A.; Dahn, J. R. High capacity anode materials for rechargeable sodium-ion batteries. J. Electrochem. Soc. 2000, 147, 1271–1273.
Crossref Google Scholar
7

Jeong, G.; Kim, Y.-U.; Kim, H.; Kim, Y.-J.; Sohn, H.-J. Prospective materials and applications for Li secondary batteries. Energy Environ. Sci. 2011, 4, 1986–2002.
Crossref Google Scholar
8

Hu, L. Y.; Zhu, X. S.; Du, Y. C.; Li, Y. F.; Zhou, X. S.; Bao, J. C. A chemically coupled antimony/multilayer graphene hybrid as a high-performance anode for sodium-ion batteries. Chem. Mater. 2015, 27, 8138–8145.
Crossref Google Scholar
9

Xu, Y. H.; Liu, Q.; Zhu, Y. J.; Liu, Y. H.; Langrock, A.; Zachariah, M. R.; Wang, C. S. Uniform nano-Sn/C composite anodes for lithium ion batteries. Nano Lett. 2013, 13, 470–474.
Crossref Google Scholar
10

Xiao, L. F.; Cao, Y. L.; Xiao, J.; Wang, W.; Kovarik, L.; Nie, Z. M.; Liu, J. High capacity, reversible alloying reactions in SnSb/C nanocomposites for Na-ion battery applications. Chem. Commun. 2012, 48, 3321–3323.
Crossref Google Scholar
11

Chevrier, V. L.; Ceder, G. Challenges for Na-ion negative electrodes. J. Electrochem. Soc. 2011, 158, A1011–A1014.
Crossref Google Scholar
12

Wu, L.; Lu, H. Y.; Xiao, L. F.; Ai, X. P.; Yang, H. X.; Cao, Y. L. Electrochemical properties and morphological evolution of pitaya-like Sb@C microspheres as high-performance anode for sodium ion batteries. J. Mater. Chem. A 2015, 3, 5708–5713.
Crossref Google Scholar
13

Xie, X. Q.; Kretschmer, K.; Zhang, J. Q.; Sun, B.; Su, D. W.; Wang, G. X. Sn@CNT nanopillars grown perpendicularly on carbon paper: A novel free-standing anode for sodium ion batteries. Nano Energy 2015, 13, 208–217.
Crossref Google Scholar
14

Chao, D. L.; Zhu, C. R.; Yang, P. H.; Xia, X. H.; Liu, J. L.; Wang, J.; Fan, X. F.; Savilov, S. V.; Lin, J. Y.; Fan, H. J. et al. Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance. Nat. Commun. 2016, 7, 12122.
Crossref Google Scholar
15

Lee, G.-H.; Shim, H.-W.; Kim, D.-W. Superior long-life and high-rate Ge nanoarrays anchored on Cu/C nanowire frameworks for Li-ion battery electrodes. Nano Energy 2015, 13, 218–225.
Crossref Google Scholar
16

Song, X. S.; Li, X. F.; Bai, Z. M.; Yan, B.; Li, D. J.; Sun, X. L. Morphology-dependent performance of nanostructured Ni3S2/Ni anode electrodes for high performance sodium ion batteries. Nano Energy 2016, 26, 533–540.
Crossref Google Scholar
17

Ko, Y. N.; Kang, Y. C. Electrochemical properties of ultrafine Sb nanocrystals embedded in carbon microspheres for use as Na-ion battery anode materials. Chem. Commun. 2014, 50, 12322–12324.
Crossref Google Scholar
18

He, M.; Kravchyk, K.; Walter, M.; Kovalenko, M. V. Monodisperse antimony nanocrystals for high-rate Li-ion and Na-ion battery anodes: Nano versus bulk. Nano Lett. 2014, 14, 1255–1262.
Crossref Google Scholar
19

Hou, H. S.; Jing, M. J.; Yang, Y. C.; Zhu, Y. R.; Fang, L. B.; Song, W. X.; Pan, C. C.; Yang, X. M.; Ji, X. B. Sodium/ lithium storage behavior of antimony hollow nanospheres for rechargeable batteries. ACS Appl. Mater. Interfaces 2014, 6, 16189–16196.
Crossref Google Scholar
20

Wang, N.; Bai, Z. C.; Qian, Y. T.; Yang, J. Double-walled Sb@TiO2−x nanotubes as a superior high-rate and ultralong- lifespan anode material for Na-ion and Li-ion batteries. Adv. Mater. 2016, 28, 4126–4133.
Crossref Google Scholar
21

Liu, J.; Yang, Z. Z.; Wang, J. Q.; Gu, L.; Maier, J.; Yu, Y. Three-dimensionally interconnected nickel–antimony inter­metallic hollow nanospheres as anode material for high-rate sodium-ion batteries. Nano Energy 2015, 16, 389–398.
Crossref Google Scholar
22

Zhang, N.; Liu, Y. C.; Lu, Y. Y.; Han, X. P.; Cheng, F. Y.; Chen, J. Spherical nano-Sb@C composite as a high-rate and ultra-stable anode material for sodium-ion batteries. Nano Res. 2015, 8, 3384–3393.
Crossref Google Scholar
23

Liu, S.; Feng, J. K.; Bian, X. F.; Liu, J.; Xu, H. The morphology-controlled synthesis of a nanoporous-antimony anode for high-performance sodium-ion batteries. Energy Environ. Sci. 2016, 9, 1229–1236.
Crossref Google Scholar
24

Wang, J. Z.; Du, N.; Zhang, H.; Yu, J. X.; Yang, D. R. Cu–Ge core–shell nanowire arrays as three-dimensional electrodes for high-rate capability lithium-ion batteries. J. Mater. Chem. 2012, 22, 1511–1515.
Crossref Google Scholar
25

Lee, C. W.; Kim, J.-C.; Park, S.; Song, H. J.; Kim, D.-W. Highly stable sodium storage in 3-D gradational Sb–NiSb–Ni heterostructures. Nano Energy 2015, 15, 479–489.
Crossref Google Scholar
26

Xu, Y.; Zhou, M.; Wen, L. Y.; Wang, C. L.; Zhao, H. P.; Mi, Y.; Liang, L. Y.; Fu, Q.; Wu, M. H.; Lei, Y. Highly ordered three-dimensional Ni-TiO2 nanoarrays as sodium ion battery anodes. Chem. Mater. 2015, 27, 4274–4280.
Crossref Google Scholar
27

Ke, F.-S.; Huang, L.; Solomon, B. C.; Wei, G.-Z.; Xue, L.-J.; Zhang, B.; Li, J.-T.; Zhou, X.-D.; Sun, S.-G. Three- dimensional nanoarchitecture of Sn–Sb–Co alloy as an anode of lithium-ion batteries with excellent lithium storage performance. J. Mater. Chem. 2012, 22, 17511–17517.
Crossref Google Scholar
28

Wang, J. Z.; Du, N.; Zhang, H.; Yu, J. X.; Yang, D. R. Cu–Sn core–shell nanowire arrays as three-dimensional electrodes for lithium-ion batteries. J. Phys. Chem. C 2011, 115, 23620–23624.
Crossref Google Scholar
29

Ryou, M. H.; Kim, J.; Lee, I.; Kim, S.; Jeong, Y. K.; Hong, S.; Ryu, J. H.; Kim, T. S.; Park, J. K.; Lee, H. et al. Mussel-inspired adhesive binders for high-performance silicon nanoparticle anodes in lithium-ion batteries. Adv. Mater. 2013, 25, 1571–1576.
Crossref Google Scholar
30

Zhao, F. P.; Han, N.; Huang, W. J.; Li, J. J.; Ye, H. L.; Chen, F. J.; Li, Y. G. Nanostructured CuP2/C composites as high-performance anode materials for sodium ion batteries. J. Mater. Chem. A 2015, 3, 21754–21759.
Crossref Google Scholar
31

Ellis, B. L.; Knauth, P.; Djenizian, T. Three-dimensional self-supported metal oxides for advanced energy storage. Adv. Mater. 2014, 26, 3368–3397.
Crossref Google Scholar
32

Fan, M. P.; Chen, Y.; Xie, Y. H.; Yang, T. Z.; Shen, X. W.; Xu, N.; Yu, H. Y.; Yan, C. L. Half-cell and full-cell applications of highly stable and binder-free sodium ion batteries based on Cu3P nanowire anodes. Adv. Funct. Mater. 2016, 26, 5019–5027.
Crossref Google Scholar
33

Liu, Y. H.; Xu, Y. H.; Zhu, Y. J.; Culver, J. N.; Lundgren, C. A.; Xu, K.; Wang, C. S. Tin-coated viral nanoforests as sodium-ion battery anodes. ACS Nano 2013, 7, 3627–3634.
Crossref Google Scholar
34

Liang, L. Y.; Xu, Y.; Wang, C. L.; Wen, L. Y.; Fang, Y. G.; Mi, Y.; Zhou, M.; Zhao, H. P.; Lei, Y. Large-scale highly ordered Sb nanorod array anodes with high capacity and rate capability for sodium-ion batteries. Energy Environ. Sci. 2015, 8, 2954–2962.
Crossref Google Scholar
35

Darwiche, A.; Marino, C.; Sougrati, M. T.; Fraisse, B.; Stievano, L.; Monconduit, L. Better cycling performances of bulk Sb in Na-ion batteries compared to Li-ion systems: An unexpected electrochemical mechanism. J. Am. Chem. Soc. 2012, 134, 20805–20811.
Crossref Google Scholar
36

Baggetto, L.; Ganesh, P.; Sun, C. N.; Meisner, R. A.; Zawodzinski, T. A.; Veith, G. M. Intrinsic thermodynamic and kinetic properties of Sb electrodes for Li-ion and Na-ion batteries: Experiment and theory. J. Mater. Chem. A 2013, 1, 7985–7994.
Crossref Google Scholar
37

Baggetto, L.; Hah, H.-Y.; Jumas, J. C.; Johnson, C. E.; Johnson, J. A.; Keum, J. K.; Bridges, C. A.; Veith, G. M. The reaction mechanism of SnSb and Sb thin film anodes for Na-ion batteries studied by X-ray diffraction, 119Sn and 121Sb Mössbauer spectroscopies. J. Power Sources 2014, 267, 329–336.
Crossref Google Scholar
38

Ji, L. W.; Gu, M.; Shao, Y. Y.; Li, X. L.; Engelhard, M. H.; Arey, B. W.; Wang, W.; Nie, Z. M.; Xiao, J.; Wang, C. M. et al. Controlling SEI formation on SnSb-porous carbon nanofibers for improved Na ion storage. Adv. Mater. 2014, 26, 2901–2908.
Crossref Google Scholar
39

Zhou, X. L.; Zhong, Y. R.; Yang, M.; Hu, M.; Wei, J. P.; Zhou, Z. Sb nanoparticles decorated N-rich carbon nanosheets as anode materials for sodium ion batteries with superior rate capability and long cycling stability. Chem. Commun. 2014, 50, 12888–12891.
Crossref Google Scholar
40

Luo, B.; Wang, B.; Li, X. L.; Jia, Y. Y.; Liang, M. H.; Zhi, L. J. Graphene-confined Sn nanosheets with enhanced lithium storage capability. Adv. Mater. 2012, 24, 3538–3543.
Crossref Google Scholar
41

Zhu, Y. J.; Han, X. G.; Xu, Y. H.; Liu, Y. H.; Zheng, S. Y.; Xu, K.; Hu, L. B.; Wang, C. S. Electrospun Sb/C fibers for a stable and fast sodium-ion battery anode. ACS Nano 2013, 7, 6378–6386.
Crossref Google Scholar
42

He, C. N.; Wu, S.; Zhao, N. Q.; Shi, C. S.; Liu, E. Z.; Li, J. J. Carbon-encapsulated Fe3O4 nanoparticles as a high-rate lithium ion battery anode material. ACS Nano 2013, 7, 4459–4469.
Crossref Google Scholar
43

Jia, X. L.; Chen, Z.; Cui, X.; Peng, Y. T.; Wang, X. L.; Wang, G.; Wei, F.; Lu, Y. F. Building robust architectures of carbon and metal oxide nanocrystals toward high- performance anodes for lithium-ion batteries. ACS Nano 2012, 6, 9911–9919.
Crossref Google Scholar
44

Zhang, W.; Liu, Y. T.; Chen, C. J.; Li, Z.; Huang, Y. H.; Hu, X. L. Flexible and binder-free electrodes of Sb/rGO and Na3V2(PO4)3/rGO nanocomposites for sodium-ion batteries. Small 2015, 11, 3822–3829.
Crossref Google Scholar
45

Zhang, K.; Hu, Z.; Liu, X.; Tao, Z. L.; Chen, J. FeSe2 microspheres as a high-performance anode material for Na-ion batteries. Adv. Mater. 2015, 27, 3305–3309.
Crossref Google Scholar
46

Ardizzone, S.; Fregonara, G.; Trasatti, S. "Inner" and "outer" active surface of RuO2 electrodes. Electrochim. Acta 1990, 35, 263–267.
Crossref Google Scholar
47

Brezesinski, T.; Wang, J.; Tolbert, S. H.; Dunn, B. Ordered mesoporous α-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors. Nat. Mater. 2010, 9, 146–151.
Crossref Google Scholar
48

Chen, Z.; Augustyn, V.; Jia, X. L.; Xiao, Q. F.; Dunn, B.; Lu, Y. F. High-performance sodium-ion pseudocapacitors based on hierarchically porous nanowire composites. ACS Nano 2012, 6, 4319–4327.
Crossref Google Scholar
49

Yu, D. Y. W.; Prikhodchenko, P. V.; Mason, C. W.; Batabyal, S. K.; Gun, J.; Sladkevich, S.; Medvedev, A. G.; Lev, O. High-capacity antimony sulphide nanoparticle- decorated graphene composite as anode for sodium-ion batteries. Nat. Commun. 2013, 4, 2922.
Crossref Google Scholar
50

Yang, Y.; Fan, X. J.; Casillas, G.; Peng, Z. W.; Ruan, G. D.; Wang, G.; Yacaman, M. J.; Tour, J. M. Three-dimensional nanoporous Fe2O3/Fe3C-graphene heterogeneous thin films for lithium-ion batteries. ACS Nano 2014, 8, 3939–3946.
Crossref Google Scholar
51

Zhukoskii, Y. F.; Balaya, P.; Kotomin, E. A.; Maier, J. Evidence for interfacial-storage anomaly in nanocomposites for lithium batteries from first-principles simulations. Phys. Rev. Lett. 2006, 96, 058302.
Crossref Google Scholar
52

Jamnik, J.; Maier, J. Nanocrystallinity effects in lithium battery materials: Aspects of nano-ionics. Part Ⅳ. Phys. Chem. Chem. Phys. 2003, 5, 5215–5220.
Crossref Google Scholar
53

Shin, J. Y.; Samuelis, D.; Maier, J. Sustained lithium-storage performance of hierarchical, nanoporous anatase TiO2 at high rates: Emphasis on interfacial storage phenomena. Adv. Funct. Mater. 2011, 21, 3464–3472.
Crossref Google Scholar
54

Balaya, P. Size effects and nanostructured materials for energy applications. Energy Environ. Sci. 2008, 1, 645–654.
Crossref Google Scholar
55

Nam, D. H.; Hong, K. S.; Lim, S. J.; Kim, M. J.; Kwon, H. S. High-performance Sb/Sb2O3 anode materials using a polypyrrole nanowire network for Na-ion batteries. Small 2015, 11, 2885–2892.
Crossref Google Scholar
Nano Research
Volume 10 Issue 9,
September 2017
Pages 3189-3201
DOI: 10.1007/s12274-017-1536-0
Cite this article:
Liang L, Xu Y, Wen L, et al. Hierarchical Sb-Ni nanoarrays as robust binder-free anodes for high-performance sodium-ion half and full cells. Nano Research, 2017, 10(9): 3189-3201. https://doi.org/10.1007/s12274-017-1536-0

643

Views

47

Crossref

N/A

Web of Science

45

Scopus

2

CSCD

Altmetrics
Received: 28 November 2016
Revised: 10 February 2017
Accepted: 13 February 2017
Published: 20 May 2017
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2017
Return