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Research Article

Fabrication of rigid and flexible SrGe4O9 nanotube-based sensors for room-temperature ammonia detection

Tingting Huang1,2, Zheng Lou2, Shuai Chen1,2, Rui Li1,2, Kai Jiang3, Di Chen1( ), Guozhen Shen2,4( )
College of Physics and Mathematics and Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface ScienceUniversity of Science and Technology BeijingBeijing100083China
State Key Laboratory for Superlattices and MicrostructuresInstitute of SemiconductorsChinese Academy of SciencesBeijing100083China
Institute & Hospital of Hepatobiliary SurgeryKey Laboratory of Digital Hepatobiliary Surgery of Chinese PLAChinese PLA Medical SchoolChinese PLA General HospitalBeijing100853China
College of Materials Science and Opto-Electronic TechnologyUniversity of Chinese Academy of SciencesBeijing100049China
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Abstract

Ammonia (NH3) detection at room temperature has attracted considerable attention because of the increasing demand for health monitoring, personal safety protection, and industrial manufacturing. Herein, we report the synthesis of polycrystalline SrGe4O9 nanotubes (NTs) via an electrospinning process. These NTs are a new sensing material for the detection of ammonia at room temperature. The SrGe4O9 NTs exhibited a maximum sensing response of 2.49 for 100 ppm NH3, which was increased to 7.08 by decorating the NTs with Pt nanoparticles. Flexible gas sensors were fabricated, which exhibited comparable performance to the rigid device. Additionally, the flexible devices showed excellent flexibility, mechanical stability, and sensing stability under different bending states, manifesting their potential applications in flexible and wearable electronics.

Keywords

gas sensorsammoniananotubesflexible electronics

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References

1

Kenry; Lim, C. K. Synthesis, optical properties, and chemical-biological sensing applications of one-dimensional inorganic semiconductor nanowires. Prog. Mater. Sci. 2013, 58, 705-748.
Crossref Google Scholar
2

Shen, G. Z.; Chen, P. C.; Ryu, K.; Zhou, C. W. Devices and chemical sensing applications of metal oxide nanowires. J. Mater. Chem. 2009, 19, 828-839.
Crossref Google Scholar
3

Miller, D. R.; Akbar S. A.; Morris, P. A. Nanoscale metal oxide-based heterojunctions for gas sensing: A review. Sens. Act. B. Chem. 2014, 204, 250-272.
Crossref Google Scholar
4

Cagliani, A.; Mackenzie, D. M. A.; Tschammer, L. K.; Pizzocchero, F.; Almdal, K.; Bøggild, P. Large-area nanopatterned graphene for ultrasensitive gas sensing. Nano Res. 2014, 7, 743-754.
Crossref Google Scholar
5

Yamazoe, N.; Tamaki, J.; Miura, N. Role of heterojunctions in oxide semiconductor gas sensors. Mater. Sci. Eng. B1996, 41, 178-181.
Crossref Google Scholar
6

Fan, Z. Y.; Ho, J. C.; Takahashi, T.; Yerushalmi, R.; Takei, K.; Ford, A. C.; Chueh, Y. L.; Javey, A. Toward the development of printable nanowire electronics and sensors. Adv. Mater. 2009, 21, 3730-3743.
Crossref Google Scholar
7

Chen, P. C.; Shen, G. Z.; Zhou, C. W. Chemical sensors and electronic noses based on 1-D metal oxide nanostructures. IEEE. Trans. Nanotechnol. 2008, 7, 668-682.
Crossref Google Scholar
8

Fields, L. L.; Zheng, J. P.; Cheng, Y.; Xiong, P. Roomtemperature low-power hydrogen sensor based on a single tin dioxide nanobelt. App. Phys. Lett. 2006, 88, 263102.
Crossref Google Scholar
9

Chen, D.; Xu, J.; Xie, Z.; Shen, G. Z. Nanowires assembled SnO2 nanopolyhedrons with enhanced gas sensing properties. ACS Appl. Mater. Interfaces 2011, 3, 2112-2117.
Crossref Google Scholar
10

Zhang, J.; Liu, X. H.; Neri, G.; Pinna, N. Nanostructured materials for room-temperature gas sensors. Adv. Mater. 2016, 28, 795-831.
Crossref Google Scholar
11

Osborn, T. H.; Farajian, A. A. Silicenenanoribbons as carbon monoxide nanosensors with molecular resolution. Nano Res. 2014, 7, 945-952.
Crossref Google Scholar
12

Xu, K.; LI, N.; Zeng, D. W.; Tian, S. Q.; Zhang, S. S.; Hu, D.; Xie, C. S. Interface bonds determined gas-sensing of SnO2-SnS2 hybrids to ammonia at room temperature. ACS Appl. Mater. Interfaces 2015, 7, 11359-11368.
Crossref Google Scholar
13

Rout, C. S.; Hegde, M.; Govindaraj, A.; Rao, C. N. R. Ammonia sensors based on metal oxide nanostructures. Nanotechnology 2007, 18, 205504.
Crossref Google Scholar
14

Chatterjee, S. G.; Chtterjee, S.; Ray, A. K.; Chakraborty, A. K. Graphene-metal oxide nanohybrids for toxic gas sensor: A review. Sens. Act. B. Chem. 2015, 221, 1170-1181.
Crossref Google Scholar
15

Liu, W. L.; Liu, Y. Y.; Do, J. S.; Li, J. Highly sensitive room temperature ammonia gas sensor based on Ir-doped Pt porous ceramic electrodes. Appl. Surf. Sci. 2016, 390, 929-935.
Crossref Google Scholar
16

Sunu, S. S.; Prabhu, E.; Jayaraman, V.; Gnanasekar, K. I.; Seshagiri, T. K.; Gnanasekaran, T. Electrical conductivity and gas sensing properties of MoO3. Sens. Act. B Chem. 2004, 101, 161-174.
Crossref Google Scholar
17

Duy, L. T.; Trung, T. Q.; Dang, V. Q.; Hwang, B. U.; Siddiqui, S.; Son, I. Y.; Yoon, S. K.; Chung, D. J.; Lee, N. E. Flexible transparent reduced graphene oxide sensor coupled with organic dye molecules for rapid dual-mode ammonia gas detection. Adv. Funct. Mater. 2016, 26, 4329-4338.
Crossref Google Scholar
18

Wang, B. H.; Ding, J. Q.; Zhu, T.; Huang, W.; Cui, Z. Q.; Chen, J. M.; Huang, L. Z.; Chi, L. F. Fast patterning of oriented organic microstripes for field-effect ammonia gas sensors. Nanoscale 2016, 8, 3954-3961.
Crossref Google Scholar
19

Liu, X.; Chen, N.; Han, B. Q.; Xiao, X. C.; Chen, G.; Djerdj, I.; Wang, Y. D. Nanoparticle cluster gas sensor: Pt activated SnO2 nanoparticles for NH3 detection with ultrahigh sensitivity. Nanoscale 2015, 7, 14872-14880.
Crossref Google Scholar
20

Cui, S. M.; Pu, H. H.; Mattson, E. C.; Lu, G. H.; Mao, S.; Weinert, M.; Hirschmugl, C. J.; Gajdardziska-Hosifovska, M.; Chen, J. H. Ag nanocrystal as a promoter for carbon nanotube-based room-temperature gas sensors. Nanoscale 2012, 4, 5887-5894.
Crossref Google Scholar
21

Peng, N.; Zhang, Q.; Chow, C. L.; Tan, O. K.; Marzari, N. Sensing mechanisms for carbon nanotube based NH3 gas detection. Nano Lett. 2009, 9, 1626-1630.
Crossref Google Scholar
22

Li, W. W.; Wang, X. F.; Liu, B.; Xu, J.; Liang, B.; Luo, T.; Luo, S. J.; Chen, D.; Shen, G. Z. Single-crystalline metal germanate nanowire-carbon textiles as binder-free, selfsupported anodes for high-performance lithium storage. Nanoscale 2013, 5, 10291-10299.
Crossref Google Scholar
23

Li, W.; Yin, Y. X.; Xin, S.; Song, W. G.; Guo, Y. G. Low-cost and large-scale synthesis of alkaline earth metal germanate nanowires as a new class of lithium ion battery anode material. Energy Environ. Sci. 2012, 5, 8007-8013.
Crossref Google Scholar
24

Liang, S. S.; Shang, M. M.; Lian, H. Z.; Li, K.; Zhang, Y.; Lin J. Deep red MGe4O9: Mn4+ (M = Sr, Ba) phosphors: Structure, luminescence properties and application in warm white light emitting diodes. J. Mater. Chem. C 2016, 4, 6409-6416.
Crossref Google Scholar
25

Liu, Z.; Xu, J.; Chen, D.; Shen, G. Z. Flexible electronics based on inorganic nanowires. Chem. Soc. Rev. 2015, 44, 161-192.
Crossref Google Scholar
26

Wu, H.; Huang, Y. A.; Xu, F.; Duan, Y. Q.; Yin, Z. P. Energy harvesters for wearable and stretchable electronics: From flexibility to stretchability. Adv. Mater. 2016, 28, 9881-9919.
Crossref Google Scholar
27

Wang, X. F.; Lu, X. H.; Liu, B.; Chen, D.; Tong, Y. X.; Shen, G. Z. Flexible energy-storage devices: Design consideration and recent progress. Adv. Mater. 2014, 26, 4763-4782.
Crossref Google Scholar
28

Wang, X. L.; Liu, J. Recent advancements in liquid metal flexible printed electronics: Properties, technologies, and applications. Micromachines, 2016, 7, 206.
Crossref Google Scholar
29

Liu, B.; Zhang, J.; Wang, X. F.; Chen, G.; Chen, D.; Zhou, C. W.; Shen, G. Z. Hierarchical three-dimensional ZnCo2O4 nanowire arras/carbon cloth anodes for a novel class of high-performance flexible lithium-ion batteries. Nano Lett. , 2012, 12, 3005-3011.
Crossref Google Scholar
30

Fu, K. K.; Cheng, J.; Li, T.; Hu, L. B. Flexible batteries: From mechanics to devices. ACS Energy Lett. 2016, 1, 1065-1079.
Crossref Google Scholar
31

Sharma, B. K.; Ahn, J. H. Flexible and stretchable oxide electronics. Adv. Electron. Mater. 2016, 2, 1600105.
Crossref Google Scholar
32

Xu, S.; Kan, K.; Yang, Y.; Jiang, C.; Gao, J.; Jing, L. Q.; Shen, P. K.; Li, L.; Shi, K. Enhanced NH3 gas sensing performance based on electrospun alkaline-earth metals composited SnO2 nanofibers. J. Alloys Compd. 2015, 618, 240-247.
Crossref Google Scholar
33

Rai, P.; Yoon, J. W.; Kwak, C. H.; Lee, J. H. Role of Pd nanoparticles in gas sensing behaviour of Pd@In2O3 yolk-shell nanoreactors. J. Mater. Chem. A 2016, 4, 264-269.
Crossref Google Scholar
34

Han, D. M.; Yang, J. J.; Gu, F. B.; Wang Z. H. Effects of rare earth element doping on the ethanol gas-sensing performance of three-dimensionally ordered macroporous In2O3. RSC Adv. 2016, 6, 45085-45092.
Crossref Google Scholar
35

Liu, J. Y.; Dai, M. J.; Wang, T. S.; Sun, P.; Liang, X. S.; Lu, G. Y.; Shimanoe, K.; Yamazoe, N. Enhanced gas sensing properties of SnO2hollow spheres decorated with CeO2 nanoparticles heterostructure composite materials. ACS Appl. Mater. Interfaces 2016, 8, 6669-6677.
Crossref Google Scholar
36

Pang, Z. Y.; Nie, Q. X.; Wei, A. F.; Yang, J.; Huang, F. L.; Wei, Q. F. Effect of In2O3 nanofiber structure on the ammonia sensing performances of In2O3/PANI composite nanofibers. J. Mater. Sci. 2017, 52, 686-695.
Crossref Google Scholar
37

Wang, L. L.; Huang, H.; Xiao, S. H.; Cai, D. P.; Liu, Y.; Liu, B.; Wang, D. D.; Wang, C. X.; Li, H.; Wang, Y. R. et al. Enhanced sensitivity and stability of room-temperature NH3 sensors using core-shell CeO2 nanoparticles@ cross-linked PANI with p-n Heterojunctions. ACS Appl. Mater. Interfaces 2014, 6, 14131-14140.
Crossref Google Scholar
38

Tai, H. L.; Yuan, Z.; Zheng, W. J.; Ye, Z. B.; Liu, C. H.; Du, X. S. ZnOnanoparticles/reduced graphene oxide bilayer thin films for improved NH3-sensing performances at room temperature. Nanoscale Res. Lett. 2016, 11, 130.
Crossref Google Scholar
Nano Research
Volume 11 Issue 1,
January 2018
Pages 431-439
DOI: 10.1007/s12274-017-1650-z
Cite this article:
Huang T, Lou Z, Chen S, et al. Fabrication of rigid and flexible SrGe4O9 nanotube-based sensors for room-temperature ammonia detection. Nano Research, 2018, 11(1): 431-439. https://doi.org/10.1007/s12274-017-1650-z

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Received: 11 March 2017
Revised: 21 April 2017
Accepted: 25 April 2017
Published: 10 August 2017
© Tsinghua University Press and Springer-Verlag GmbH Germany 2017
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