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Review Article

Practical considerations of Si-based anodes for lithium-ion battery applications

Jaegeon Ryu§, Dongki Hong§, Hyun-Wook Lee( ), Soojin Park( )
Department of Energy EngineeringSchool of Energy and Chemical EngineeringUlsan National Institute of Science and Technology (UNIST)Ulsan44919Republic of Korea

§ Jaegeon Ryu and Dongki Hong contributed equally to this work.

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Graphical Abstract

Abstract

Using Si-based anodes in Li-ion batteries is one of the most feasible approaches to achieve high energy densities despite their disadvantages, such as low conductivity and massive volume expansion, which cause unstable solid electrolyte interphase layers with mechanical failure. The forefront in research and development to address the above challenges suggests the possibility of fully commercially viable cells using various structural and interfacial modifications. In particular, we present a discussion of each dimension of Si-based anodes in multiple controlled systems, including plain, hollow, porous, and uniquely engineered structures, which are further evaluated based on their anode performances, such as initial reversibility, capacity retention for extended cycles with its efficiency, degree of volume expansion tolerance, and rate capabilities, by several practical standards in half cells. With these practical considerations, multi-dimensional structures with uniform size distributions (micrometers, on average) are strongly desired to satisfy the rigorous requirements for widespread applications. Furthermore, we closely examined several full cells composed of Si-based multicomponent anodes coupled with suitable cathodes based on practical standards to propose future research directions for Si-based anodes to keep pace with the rapidly changing market demands for diverse energy storage systems.

Keywords

lithium-ion batteriesfull cellsilicon anodedimensional controlpracticality

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Nano Research
Volume 10 Issue 12,
December 2017
Pages 3970-4002
DOI: 10.1007/s12274-017-1692-2
Cite this article:
Ryu J, Hong D, Lee H-W, et al. Practical considerations of Si-based anodes for lithium-ion battery applications. Nano Research, 2017, 10(12): 3970-4002. https://doi.org/10.1007/s12274-017-1692-2

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Received: 27 March 2017
Revised: 21 May 2017
Accepted: 25 May 2017
Published: 05 August 2017
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2017
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