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In this report, we demonstrate a simple chemical bath deposition approach for the synthesis of layered SnS nanosheets (typically 6 nm or ~10 layers thick) at very low temperature (40 ℃). We successfully synthesized SnS/C hybrid electrodes using a solution-based carbon precursor coating with subsequent carbonization strategy. Our data showed that the ultrathin carbon shell was critical to the cycling stability of the SnS electrodes. As a result, the as-prepared binder-free SnS/C electrodes showed excellent performance as sodium ion battery anodes. Specifically, the SnS/C anodes delivered a reversible capacity as high as 792 mAh·g−1 after 100 cycles at a current density of 100 mA·g−1. They also had superior rate capability (431 mAh·g−1 at 3, 000 mA·g−1) and stable long-term cycling performance under a high current density (345 mAh·g−1 after 500 cycles at 3 A·g−1). Our approach opens up a new route to synthesize SnS-based hybrid materials at low temperatures for energy storage and other applications. Our process will be particularly useful for chalcogenide matrix materials that are sensitive to high temperatures during solution synthesis.
Wang, Q.; Wang, C. Y.; Zhang, M. C.; Jian, M. Q.; Zhang, Y. Y. Feeding single-walled carbon nanotubes or graphene to silkworms for reinforced silk fibers. Nano Lett. 2016, 16, 6695–6700.
Chen, Y. N.; Luo, W.; Carter, M.; Zhou, L. H.; Dai, J. Q.; Fu, K.; Lacey, S.; Li, T.; Wan, J. Y.; Han, X. G. et al. Organic electrode for non-aqueous potassium-ion batteries. Nano Energy 2015, 18, 205–211.
Kim, S. W.; Seo, D. H.; Ma, X. H.; Ceder, G.; Kang, K. Electrode materials for rechargeable sodium-ion batteries: Potential alternatives to current lithium-ion batteries. Adv. Energy Mater. 2012, 2, 710–721.
Yabuuchi, N.; Kubota, K.; Dahbi, M.; Komaba, S. Research development on sodium-ion batteries. Chem. Rev. 2014, 114, 11636–11682.
Dutta, P. K.; Sen, U. K.; Mitra, S. Excellent electrochemical performance of tin monosulphide (SnS) as a sodium-ion battery anode. RSC Adv. 2014, 4, 43155–43159.
Pan, H. L.; Hu, Y. S.; Chen, L. Q. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage. Energ Environ. Sci. 2013, 6, 2338–2360.
Peng, L. L.; Zhu, Y.; Chen, D. H.; Ruoff, R. S.; Yu, G. H. Two-dimensional materials for beyond-lithium-ion batteries. Adv. Energy Mater. 2016, 6, 1600025.
Li, H. S.; Zhu, Y.; Dong, S. Y.; Shen, L. F.; Chen, Z. J.; Zhang, X. G.; Yu, G. H. Self-assembled Nb2O5 nanosheets for high energy-high power sodium ion capacitors. Chem. Mater. 2016, 28, 5753–5760.
Park, Y. U.; Seo, D. H.; Kwon, H. S.; Kim, B.; Kim, J.; Kim, H.; Kim, I.; Yoo, H. I.; Kang, K. A new high-energy cathode for a Na-ion battery with ultrahigh stability. J. Am. Chem. Soc. 2013, 135, 13870–13878.
Li, H. S.; Peng, L. L.; Zhu, Y.; Chen, D. H.; Zhang, X. G.; Yu, G. H. An advanced high-energy sodium ion full battery based on nanostructured Na2Ti3O7/VOPO4 layered materials. Energy Environ. Sci. 2016, 9, 3399–3405.
Li, Z.; Ding, J.; Mitlin, D. Tin and tin compounds for sodium ion battery anodes: Phase transformations and performance. Acc. Chem. Res. 2015, 48, 1657–1665.
Wang, J. W.; Liu, X. H.; Mao, S. X.; Huang, J. Y. Microstructural evolution of tin nanoparticles during in situ sodium insertion and extraction. Nano Lett. 2012, 12, 5897–5902.
Zheng, Y.; Zhou, T. F.; Zhang, C. F.; Mao, J. F.; Liu, H. K.; Guo, Z. P. Boosted charge transfer in SnS/SnO2 heterostructures: Toward high rate capability for sodium-ion batteries. Angew. Chem. , Int. Ed. 2016, 55, 3408–3413.
Su, D. W.; Ahn, H. J.; Wang, G. X. SnO2@ graphene nanocomposites as anode materials for Na-ion batteries with superior electrochemical performance. Chem. Commun. 2013, 49, 3131–3133.
Hildenbrand, D. L.; Murad, E. Dissociation energy of NaO(g) and the heat of atomization of Na2O(g). J. Chem. Phys. 1970, 53, 3403–3408.
Wu, L.; Lu, H. Y.; Xiao, L. F.; Qian, J. F.; Ai, X. P.; Yang, H. X.; Cao, Y. L. A tin(Ⅱ) sulfide-carbon anode material based on combined conversion and alloying reactions for sodium-ion batteries. J. Mater. Chem. A 2014, 2, 16424–16428.
Zhu, C. B.; Kopold, P.; Li, W. H.; van Aken, P. A.; Maier, J.; Yu, Y. A general strategy to fabricate carbon-coated 3D porous interconnected metal sulfides: Case study of SnS/C nanocomposite for high-performance lithium and sodium ion batteries. Adv. Sci. 2015, 2, 1500200.
Burton, L. A.; Colombara, D.; Abellon, R. D.; Grozema, F. C.; Peter, L. M.; Savenije, T. J.; Dennler, G.; Walsh, A. Synthesis, characterization, and electronic structure of single-crystal SnS, Sn2S3, and SnS2. Chem. Mater. 2013, 25, 4908–4916.
Zhou, T. F.; Pang, W. K.; Zhang, C. F.; Yang, J. P.; Chen, Z. X.; Liu, H. K.; Guo, Z. P. Enhanced sodium-ion battery performance by structural phase transition from two- dimensional hexagonal-SnS2 to orthorhombic-SnS. ACS Nano 2014, 8, 8323–8333.
Im, H. S.; Cho, Y. J.; Lim, Y. R.; Jung, C. S.; Jang, D. M.; Park, J.; Shojaei, F.; Kang, H. S. Phase evolution of tin nanocrystals in lithium ion batteries. ACS Nano 2013, 7, 11103–11111.
Xin, S.; Guo, Y. G.; Wan, L. J. Nanocarbon networks for advanced rechargeable lithium batteries. Acc. Chem. Res. 2012, 45, 1759–1769.
Xie, X. Q.; Su, D. W.; Chen, S. Q.; Zhang, J. Q.; Dou, S. X.; Wang, G. X. SnS2 nanoplatelet@ graphene nanocomposites as high-capacity anode materials for sodium-ion batteries. Chem. –Asian J. 2014, 9, 1611–1617.
Choi, S. H.; Kang, Y. C. Aerosol-assisted rapid synthesis of SnS-C composite microspheres as anode material for Na-ion batteries. Nano Res. 2015, 8, 1595–1603.
Liu, Y. C.; Kang, H. Y.; Jiao, L. F.; Chen, C. C.; Cao, K. Z.; Wang, Y. J.; Yuan, H. T. Exfoliated-SnS2 restacked on graphene as a high-capacity, high-rate, and long-cycle life anode for sodium ion batteries. Nanoscale 2015, 7, 1325–1332.
Liu, S.; Yin, X. M.; Hao, Q. Y.; Zhang, M.; Li, L. M.; Chen, L. B.; Li, Q. H.; Wang, Y. G.; Wang, T. H. Chemical bath deposition of SnS2 nanowall arrays with improved electrochemical performance for lithium ion battery. Mater. Lett. 2010, 64, 2350–2353.
Bang, G. S.; Nam, K. W.; Kim, J. Y.; Shin, J.; Choi, J. W.; Choi, S. Y. Effective liquid-phase exfoliation and sodium ion battery application of MoS2 nanosheets. ACS Appl. Mater. Interfaces 2014, 6, 7084–7089.
Chen, L.; Zhou, G. M.; Liu, Z. B.; Ma, X. M.; Chen, J.; Zhang, Z. Y.; Ma, X. L.; Li, F.; Cheng, H. M.; Ren, W. C. Scalable clean exfoliation of high-quality few-layer black phosphorus for a flexible lithium ion battery. Adv. Mater. 2016, 28, 510–517.
Wang, Q.; Pan, J.; Li, M.; Luo, Y. Y.; Wu, H.; Zhong, L.; Li, G. H. VO2 (B) nanosheets as a cathode material for Li-ion battery. J. Mater. Sci. Technol. 2015, 31, 630–633.
Chao, D. L.; Liang, P.; Chen, Z.; Bai, L. Y.; Shen, H.; Liu, X. X.; Xia, X. H.; Zhao, Y. L.; Savilov, S. V.; Lin, J. Y. et al. Pseudocapacitive Na-ion storage boosts high rate and areal capacity of self-branched 2D layered metal chalcogenide nanoarrays. ACS Nano 2016, 10, 10211–10219.
Yang, W. L.; Zhang, L.; Hu, Y.; Zhong, Y. J.; Wu, H. B.; Lou, X. W. D. Microwave-assisted synthesis of porous Ag2S–Ag hybrid nanotubes with high visible-light photocatalytic activity. Angew. Chem. , Int. Ed. 2012, 51, 11501–11504.
Reddy, N. K. Growth-temperature dependent physical properties of SnS nanocrystalline thin films. ECS J. Solid State Sci. Technol. 2013, 2, P259–P263.
Devika, M.; Reddy, N. K.; Prashantha, M.; Ramesh, K.; Reddy, S. V.; Hahn, Y. B.; Gunasekhar, K. R. The physical properties of SnS films grown on lattice-matched and amorphous substrates. Phys. Status Solidi (A) 2010, 207, 1864–1869.
Alam, F.; Dutta, V. Tin sulfide (SnS) nanostructured films deposited by continuous spray pyrolysis (CoSP) technique for dye-sensitized solar cells applications. Appl. Surf. Sci. 2015, 358, 491–497.
Yue, G. H.; Lin, Y. D.; Wen, X.; Wang, L. S.; Chen, Y. Z.; Peng, D. L. Synthesis and characterization of the SnS nanowires via chemical vapor deposition. Appl. Phys. A 2012, 106, 87–91.
Aricò, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J. M.; Van Schalkwijk, W. Nanostructured materials for advanced energy conversion and storage devices. Nat. Mater. 2005, 4, 366–377.
Rangappa, D.; Murukanahally, K. D.; Tomai, T.; Unemoto, A.; Honma, I. Ultrathin nanosheets of Li2MSiO4 (M = Fe, Mn) as high-capacity Li-ion battery electrode. Nano Lett. 2012, 12, 1146–1151.
Zhang, K.; Kim, H. J.; Shi, X. J.; Lee, J. T.; Choi, J. M.; Song, M. S.; Park, J. H. Graphene/acid coassisted synthesis of ultrathin MoS2 nanosheets with outstanding rate capability for a lithium battery anode. Inorg. Chem. 2013, 52, 9807–9812.
Ryu, J.; Hong, D. K.; Choi, S.; Park, S. Synthesis of ultrathin Si nanosheets from natural clays for lithium-ion battery anodes. ACS Nano 2016, 10, 2843–2851.
Li, H. Q.; Zhou, H. S. Enhancing the performances of Li-ion batteries by carbon-coating: Present and future. Chem. Commun. 2012, 48, 1201–1217.
Zhang, Z. H.; Dua, R.; Zhang, L. B.; Zhu, H. B.; Zhang, H. N.; Wang, P. Carbon-layer-protected cuprous oxide nanowire arrays for efficient water reduction. ACS Nano 2013, 7, 1709–1717.
Li, Z. Q.; Guo, H. C.; Qian, H. S.; Hu, Y. Facile microemulsion route to coat carbonized glucose on upconversion nanocrystals as high luminescence and biocompatible cell- imaging probes. Nanotechnology 2010, 21, 315105.
Wang, J. J.; Luo, C.; Mao, J. F.; Zhu, Y. J.; Fan, X. L.; Gao, T.; Mignerey, A. C.; Wang, C. S. Solid-state fabrication of SnS2/C nanospheres for high-performance sodium ion battery anode. ACS Appl. Mater. Interfaces 2015, 7, 11476–11481.
Qu, B. H.; Ma, C. Z.; Ji, G.; Xu, C. H.; Xu, J.; Meng, Y. S.; Wang, T. H.; Lee, J. Y. Layered SnS2-reduced graphene oxide composite-a high-capacity, high-rate, and long-cycle life sodium-ion battery anode material. Adv. Mater. 2014, 26, 3854–3859.
Zhang, Y. D.; Zhu, P. Y.; Huang, L. L.; Xie, J.; Zhang, S. C.; Cao, G. S.; Zhao, X. B. Few-layered SnS2 on few-layered reduced graphene oxide as na-ion battery anode with ultralong cycle life and superior rate capability. Adv. Funct. Mater. 2015, 25, 481–489.
Zhou, N. J.; Lin, H.; Lou, S. J.; Yu, X. G.; Guo, P. J.; Manley, E. F.; Loser, S.; Hartnett, P.; Huang, H.; Wasielewski, M. R. et al. Morphology-performance relationships in high- efficiency all-polymer solar cells. Adv. Energy Mater. 2014, 4, 130078.
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