AI Chat Paper
Discover the SciOpen Platform and Achieve Your Research Goals with Ease.
Search articles, authors, keywords, DOl and etc.
{{expandStatus?'Exit ':''}}Advanced Search
Vertically-oriented graphene (VG) has many advantages over flat lying graphene, including a large surface area, exposed sharp edges, and non-stacking three-dimensional geometry. Recently, VG nanosheets assembled on specific substrates have been used for applications in supersensitive gas sensors and high-performance energy storage devices. However, to realize these intriguing applications, the direct growth of high-quality VG on a functional substrate is highly desired. Herein, we report the direct synthesis of VG nanosheets on traditional soda-lime glass due to its low-cost, good transparency, and compatibility with many applications encountered in daily life. This synthesis was achieved by a direct-current plasma enhanced chemical vapor deposition (dc-PECVD) route at 580 ℃, which is right below the softening point of the glass, and featured a scale-up size ~6 inches. Particularly, the fabricated VG nanosheets/glass hybrid materials at a transmittance range of 97%–34% exhibited excellent solarthermal performances, reflected by a 70%–130% increase in the surface temperature under simulated sunlight irradiation. We believe that this graphene glass hybrid material has great potential for use in future transparent "green-warmth" construction materials.
Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Electric field effect in atomically thin carbon films. Science 2004, 306, 666–669.
Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A. A. Two-dimensional gas of massless Dirac fermions in graphene. Nature 2005, 438, 197–200.
Geim, A. K.; Novoselov, K. S. The rise of graphene. Nat. Mater. 2007, 6, 183–191.
Novoselov, K. S.; Fal'ko, V. I.; Colombo, L.; Gellert, P. R.; Schwab, M. G.; Kim, K. A roadmap for graphene. Nature 2012, 490, 192–200.
Sun, J. Y.; Chen, Y. B.; Priydarshi, M. K.; Chen, Z.; Bachmatiuk, A.; Zou, Z. Y.; Chen, Z. L.; Song, X. J.; Gao, Y. F.; Rümmeli, M. H. et al. Direct chemical vapor deposition-derived graphene glasses targeting wide ranged applications. Nano Lett. 2015, 15, 5846–5854.
Chen, Y. B.; Sun, J. Y.; Gao, J. F.; Du, F.; Han, Q.; Nie, Y. F.; Chen, Z. L.; Bachmatiuk, A.; Priydarshi, M. K.; Ma, D. L. et al. Growing uniform graphene disks and films on molten glass for heating devices and cell culture. Adv. Mater. 2015, 27, 7839–7846.
Sun, J. Y.; Chen, Y. B.; Cai, X.; Ma, B. J.; Chen, Z. L.; Priydarshi, M. K.; Chen, K.; Gao, T.; Song, X. J.; Ji, Q. Q. et al. Direct low-temperature synthesis of graphene on various glasses by plasma-enhanced chemical vapor deposition for versatile, cost-effective electrodes. Nano Res. 2015, 8, 3496–3504.
Sun, J. Y.; Chen, Z. L.; Yuan, L.; Chen, Y. B.; Ning, J.; Liu, S. W.; Ma, D. L.; Song, X. J.; Priydarshi, M. K.; Bachmatiuk, A. et al. Direct chemical-vapor-deposition-fabricated, large-scale graphene glass with high carrier mobility and uniformity for touch panel applications. ACS Nano 2016, 10, 11136– 11144.
Chen, X. D.; Chen, Z. L.; Jiang, W. S.; Zhang, C. H.; Sun, J. Y.; Wang, H. H.; Xin, W.; Lin, L.; Priydarshi, M. K.; Yang, H. et al. Fast growth and broad applications of 25-inch uniform graphene glass. Adv. Mater. 2017, 29, 1603428.
Miller, J. R.; Outlaw, R. A.; Holloway, B. C. Graphene double-layer capacitor with ac line-filtering performance. Science 2010, 329, 1637–1639.
Yu, K. H.; Bo, Z.; Lu, G. H.; Mao, S.; Cui, S. M.; Zhu, Y. W.; Chen, X. Q.; Ruoff, R. S.; Chen, J. H. Growth of carbon nanowalls at atmospheric pressure for one-step gas sensor fabrication. Nanoscale Res. Lett. 2011, 6, 202.
Soin, N.; Roy, S. S.; Lim, T. H.; McLaughlin, J. A. D. Microstructural and electrochemical properties of vertically aligned few layered graphene (FLG) nanoflakes and their application in methanol oxidation. Mater. Chem. Phys. 2011, 129, 1051–1057.
Shang, N. G.; Papakonstantinou, P.; McMullan, M.; Chu, M.; Stamboulis, A.; Potenza, A.; Dhesi, S. S.; Marchetto, H. Catalyst-free efficient growth, orientation and biosensing properties of multilayer graphene nanoflake films with sharp edge planes. Adv. Funct. Mater. 2008, 18, 3506–3514.
Yang, C. Y.; Bi, H.; Wan, D. Y.; Huang, F. Q.; Xie, X. M.; Jiang, M. H. Direct PECVD growth of vertically erected graphene walls on dielectric substrates as excellent multifunctional electrodes. J. Mater. Chem. A 2013, 1, 770–775.
Wu, Y.; Qiao, P.; Chong, T.; Shen, Z. Carbon nanowalls grown by microwave plasma enhanced chemical vapor deposition. Adv. Mater. 2002, 14, 64–67.
Wang, J. J.; Zhu, M. Y.; Outlaw, R. A.; Zhao, X.; Manos, D. M.; Holloway, B. C. Synthesis of carbon nanosheets by inductively coupled radio-frequency plasma enhanced chemical vapor deposition. Carbon 2004, 42, 2867–2872.
Liu, W. H.; Dang, T.; Xiao, Z. H.; Li, X.; Zhu, C. C.; Wang, X. L. Carbon nanosheets with catalyst-induced wrinkles formed by plasma-enhanced chemical-vapor deposition. Carbon 2011, 49, 884–889.
Ma, Y. F.; Jang, H.; Kim, S. J.; Pang, C.; Chae, H. Copper-assisted direct growth of vertical graphene nanosheets on glass substrates by low-temperature plasma-enhanced chemical vapour deposition process. Nanoscale Res. Lett. 2015, 10, 308.
Bo, Z.; Yu, K. H.; Lu, G. H.; Wang, P. X.; Mao, S.; Chen, J. H. Understanding growth of carbon nanowalls at atmospheric pressure using normal glow discharge plasma-enhanced chemical vapor deposition. Carbon 2011, 49, 1849–1858.
Obraztsov, A. N.; Zolotukhin, A. A.; Ustinov, A. O.; Volkov, A. P.; Svirko, Y.; Jefimovs, K. DC discharge plasma studies for nanostructured carbon CVD. Diamond Relat. Mater. 2003, 12, 917–920.
Zhao, J.; Shaygan, M.; Eckert, J.; Meyyappan, M.; Rummeli, M. H. A growth mechanism for free-standing vertical graphene. Nano Lett. 2014, 14, 3064–3071.
Louchev, O. A.; Sato, Y.; Kanda, H. Growth mechanism of carbon nanotube forests by chemical vapor deposition. Appl. Phys. Lett. 2002, 80, 2752–2754.
Wu, Y. H.; Yang, B. J. Effects of localized electric field on the growth of carbon nanowalls. Nano Lett. 2002, 2, 355–359.
Wu, Y. H.; Yang, B. J.; Zong, B. Y.; Sun, H.; Shen, Z. X.; Feng, Y. P. Carbon nanowalls and related materials. J. Mater. Chem. 2004, 14, 469–477.
Zhu, M. Y.; Wang, J. J.; Holloway, B. C.; Outlaw, R. A.; Zhao, X.; Hou, K.; Shutthanandan, V.; Manos, D. M. A mechanism for carbon nanosheet formation. Carbon 2007, 45, 2229–2234.
Ni, Z. H.; Fan, H. M.; Feng, Y. P.; Shen, Z. X.; Yang, B. J.; Wu, Y. H. Raman spectroscopic investigation of carbon nanowalls. J. Chem. Phys. 2006, 124, 204703.
Bo, Z.; Yang, Y.; Chen, J. H.; Yu, K. H.; Yan, J. H.; Cen, K. F. Plasma-enhanced chemical vapor deposition synthesis of vertically oriented graphene nanosheets. Nanoscale 2013, 5, 5180–5204.
Bae, K.; Kang, G. M.; Cho, S. K.; Park, W.; Kim, K.; Padilla, W. J. Flexible thin-film black gold membranes with ultrabroadband plasmonic nanofocusing for efficient solar vapour generation. Nat. Commun. 2015, 6, 10103.
Raut, H. K.; Ganesh, V. A.; Nair, A. S.; Ramakrishna, S. Anti-reflective coatings: A critical, in-depth review. Energy Environ. Sci. 2011, 4, 3779–3804.
Hoch, L. B.; O'Brien, P. G.; Jelle, A.; Sandhel, A.; Perovic, D. D.; Mims, C. A.; Ozin, G. A. Nanostructured indium oxide coated silicon nanowire arrays: A hybrid photothermal/ photochemical approach to solar fuels. ACS Nano 2016, 10, 9017–9025.
京公网安备11010802044758号