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Research Article

Large unsaturated room temperature negative magnetoresistance in graphene foam composite for wearable and flexible magnetoelectronics

Rizwan Ur Rehman Sagar1,2,3, Massimiliano Galluzzi1,4, Alberto García-Peñas1,2, Masroor Ahmad Bhat1,2, Min Zhang3, Florian J. Stadler1( )
College of Materials Science and Engineering,Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, Nanshan District Key Lab for Biopolymers and Safety Evaluation, Shenzhen University,Shenzhen,518060,China;
Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province,College of Optoelectronic Engineering, Shenzhen University,Shenzhen,518060,China;
Graduate School at Shenzhen,Tsinghua University,Shenzhen,518055,China;
Shenzhen Key Laboratory of Nanobiomechanics,Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences,Shenzhen,518055,China;
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Graphical Abstract

Abstract

Room temperature positive magnetoresistance (PMR) in graphene is a conventional phenomenon but we observed large negative magnetoresistance (NMR) in graphene foam (GF)/polydimethylsiloxane (GF/PDMS) at room temperature for the first time. The largest NMR ~ 35% was detected at 250 K, while PMR is observed below 200 K. Furthermore, PMR at all temperatures is observed in regular GF specimens, hence, NMR is the result of the infiltration with the electrically insulating polymer. Forward interference and wavefunction shrinkage model has been employed to understand the transport mechanism in GF/PDMS. A critical temperature ~ 224 K for switching between NMR and PMR is observed at the crystallization temperature of PDMS, suggesting a change in polymer chain conformation may be a major reason leading to NMR in GF/PDMS specimens thus role of mechanical properties of PDMS in NMR cannot be ignored and observed locally via specially resolved atomic force microscopy. In addition, storage modulus and heat flow study shows similar transition temperature (~ 200 K) of NMR to PMR and provide an evidence of mechanical stable specimens. As is known, large, tunable, and unsaturated NMR at room temperature is very useful for future facile practical shapeable magnetoelectronic devices.

Keywords

chemical vapor depositiongraphene foamnegative magnetoresistance

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Nano Research
Volume 12 Issue 1,
January 2019
Pages 101-107
DOI: 10.1007/s12274-018-2186-6
Cite this article:
Sagar RUR, Galluzzi M, García-Peñas A, et al. Large unsaturated room temperature negative magnetoresistance in graphene foam composite for wearable and flexible magnetoelectronics. Nano Research, 2019, 12(1): 101-107. https://doi.org/10.1007/s12274-018-2186-6
Topics:
Atomic force microscopyChemical vapor depositionGrapheneSpintronics TemperatureWearable technology

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Received: 04 January 2018
Revised: 23 August 2018
Accepted: 24 August 2018
Published: 11 September 2018
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018
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