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Research Article

Self-supporting, eutectic-like, nanoporous biphase bismuth-tin film for high-performance magnesium storage

Meijia Song1,§, Jiazheng Niu1,§, Kuibo Yin2, Hui Gao1, Chi Zhang3, Wensheng Ma1, Fakui Luo1, Zhangquan Peng4, Zhonghua Zhang1( )
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education),School of Materials Science and Engineering, Shandong University, Jingshi Road 17923,Jinan,250061,China;
SEU-FEI Nano-Pico Center,Key Lab of MEMS of Ministry of Education, Southeast University,Nanjing,210096,China;
School of Applied Physics and Materials,Wuyi University, Dongcheng Village 22,Jiangmen,529020,China;
State Key Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry, Chinese Academy of Sciences,Changchun,130022,China;

§ Meijia Song and Jiazheng Niu contributed equally to this work.

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Graphical Abstract

Abstract

Magnesium ion batteries are emerging as promising alternatives to lithium ion batteries because of their advantages including high energy density, dendrite-free features and low cost. Nevertheless, one of the major challenges for magnesium ion batteries is the kinetically sluggish magnesium insertion/extraction and diffusion in electrode materials. Aiming at this issue, biphase eutectic-like bismuth-tin film is designed herein to construct a self-supporting anode with interdigitated phase distribution and hierarchically porous structure, and further fabricated by a facile one-step magnetron cosputtering route. As benchmarked with single-phase bismuth or tin film, the biphase bismuth-tin film delivers high specific capacity (538 mAh/g at 50 mA/g), excellent rate performance (417 mAh/g at 1, 000 mA/g) and good cycling stability (233 mAh/g at the 200th cycle). The superior magnesium storage performance of the sputtered bismuth-tin film could be attributed to the synergetic effect of the interdigitated bismuth/tin phase distribution, hierarchically porous structure and biphase buffering matrices, which could increase ionic transport channels, shorten diffusion lengths and reduce total volume changes.

Keywords

magnesium ion batteriesalloying-type anodebiphase bismuth-tin filmhierarchically porous structuremagnetron cosputtering

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Nano Research
Volume 12 Issue 4,
April 2019
Pages 801-808
DOI: 10.1007/s12274-019-2291-1
Cite this article:
Song M, Niu J, Yin K, et al. Self-supporting, eutectic-like, nanoporous biphase bismuth-tin film for high-performance magnesium storage. Nano Research, 2019, 12(4): 801-808. https://doi.org/10.1007/s12274-019-2291-1
Topics:
AnodesBismuthMagnesiumMetal ionsMetallic films PorosityTin

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Received: 13 October 2018
Revised: 12 December 2018
Accepted: 04 January 2019
Published: 25 January 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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