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Research Article

Red/orange dual-emissive carbon dots for pH sensing and cell imaging

Miaoran Zhang1Rigu Su1Jian Zhong2,3Ling Fei4Wei Cai1Qingwen Guan1Weijun Li1Neng Li5Yusheng Chen6Lulu Cai2()Quan Xu1()
State Key Laboratory of Heavy Oil Processing,Beijing Key Laboratory of Biogas Upgrading Utilization, China University of Petroleum (Beijing),Beijing,102249,China;
Personalized Drug Therapy Key Laboratory of Sichuan Province,Department of Pharmacy, Sichuan Provincial People's Hospital, University of Electronic Science and Technology of China,Chengdu,611731,China;
School of Pharmacy,North Sichuan Medical College,Nanchong,637000,China;
Chemical Engineering Department,University of Louisiana at Lafayette, Lafayette,LA 70504,USA;
State Key Laboratory of Silicate Materials for Architectures,Wuhan University of Technology,Wuhan,430070,China;
Department of Chemistry,University of Akron,Akron,OH 44325,USA;
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Abstract

The dual-emissive N, S co-doped carbon dots (N, S-CDs) with a long emission wavelength were synthesized via solvothermal method. The N, S-CDs possess relatively high photoluminescence (PL) quantum yield (QY) (35.7%) towards near-infrared fluorescent peak up to 648 nm. With the advanced characterization techniques including X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), etc. It is found that the doped N, S elements play an important role in the formation of high QY CDs. The N, S-CDs exist distinct pH-sensitive feature with reversible fluorescence in a good linear relationship with pH values in the range of 1.0–13.0. What is more, N, S-CDs can be used as an ultrasensitive Ag+ probe sensor with the resolution up to 0.4 μM. This finding will expand the application of as prepared N, S-CDs in sensing and environmental fields.

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Nano Research
Pages 815-821
Cite this article:
Zhang M, Su R, Zhong J, et al. Red/orange dual-emissive carbon dots for pH sensing and cell imaging. Nano Research, 2019, 12(4): 815-821. https://doi.org/10.1007/s12274-019-2293-z
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