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Research Article

Ni@N-doped graphene nanosheets and CNTs hybrids modified separator as efficient polysulfide barrier for high-performance lithium sulfur batteries

Xintao Zuo1, Mengmeng Zhen1,2( ), Cheng Wang1( )
Tianjin Key Laboratory of Advanced Functional Porous Materials and Center for Electron Microscopy,Institute for New Energy Materials & Low-Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology,Tianjin,300071,China;
Tianjin Key Laboratory of Clean Energy and Pollution Control,School of Energy and Environmental Engineering, Hebei University of Technology,Tianjin,300401,China;
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Abstract

Lithium-sulfur batteries (LSBs) have been regarded as one of the most promising energy storage systems to break through the upper limit of lithium-ion batteries. However, the rampant diffusions of soluble lithium polysulfides (LiPSs) in the electrolyte induced the shuttle effect between anode and cathode, resulting in low sulfur utilization, low energy efficiency and short cycling life. Herein, we prove the rational design and construction of Ni nanoparticles filled in vertically grown N-doped bamboo-like carbon nanotubes (CNTs) on graphene nanosheets (Ni@NG-CNTs) as efficient polysulfide barrier for high-performance LSBs. The unique design integrates graphene nanosheets and CNTs into hierarchical architectures with one-dimensional (1D) CNTs, two-dimensional (2D) ultrathin nanosheets and abundant carbon nanocages. This design provides large surface area for lithium polysulfides (LiPSs) adsorption, accelerates electron transport and enhances electrochemical redox of LiPSs. Benefiting from the unique structural features, the LSBs with the Ni@NG-CNTs as polysulfide barrier keep high reversible specific capacities of 309.1 and 265.0 mAh·g−1 at 5 and 10 C rates after 500 cycles. This work provides a new strategy for constructing self-assembled hybrids of CNTs and graphene nanosheets with abundant carbon nanocages for high-performance LSBs.

Keywords

lithium-sulfur batteriesself-assembled hierarchical architectureconfined Ni nanoparticlesabundant carbon nanocagesmodified separator

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Nano Research
Volume 12 Issue 4,
April 2019
Pages 829-836
DOI: 10.1007/s12274-019-2298-7
Cite this article:
Zuo X, Zhen M, Wang C. Ni@N-doped graphene nanosheets and CNTs hybrids modified separator as efficient polysulfide barrier for high-performance lithium sulfur batteries. Nano Research, 2019, 12(4): 829-836. https://doi.org/10.1007/s12274-019-2298-7
Topics:
Carbon nanotubesDoping (additives)ElectrodesElectrolytesEnergy efficiencyGrapheneIon batteriesLithiumLithium compoundsNanoparticlesNanosheetsNickel compoundsPolysulfides

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Received: 12 November 2018
Revised: 21 December 2018
Accepted: 11 January 2019
Published: 25 January 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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