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Research Article

In-situ formation of MOF derived mesoporous Co3N/amorphous N-doped carbon nanocubes as an efficient electrocatalytic oxygen evolution reaction

Bong Kyun Kang1,†, Seo Young Im2,†, Jooyoung Lee2, Sung Hoon Kwag2, Seok Bin Kwon2, SintayehuNibret Tiruneh2, Min-Jun Kim3, Jung Ho Kim4,5, Woo Seok Yang1, Byungkwon Lim2, Dae Ho Yoon2( )
Nano Materials and Components Research Center,Korea Electronics Technology Institute,Seongnam,463-816,Republic of Korea;
School of Advanced Materials Science and Engineering,Sungkyunkwan University,Suwon,440-746,Republic of Korea;
Advanced Materials & Processing Center,Institute for Advanced Engineering (IAE),Yongin,175-28,Republic of Korea;
Australian Institute for Innovative Materials (AIIM),University of Wollongong,Squires Way, North Wollongong, NSW,2500,Australia;
Department of Advanced Materials Engineering for Information and Electronics,Kyung Hee University,1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do,17104,Republic of Korea;

† Present address: Nano Materials and Components Research Center, Korea Electronics Technology Institute, Seongnam 463-816, Republic of Korea, School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746, Republic of Korea

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Graphical Abstract

Abstract

The suitable materials, metal nitrides, are a promising class of electrocatalyst materials for a highly efficient oxygen evolution reaction (OER) because they exhibit superior intrinsic conductivity and have higher sustainability than oxide-based materials. To our knowledge, for the first time, we report a designable synthesis of three-dimensional (3D) and mesoporous Co3N@amorphous N-doped carbon (AN-C) nanocubes (NCs) with well-controlled open-framework structures via monodispersed Co3[Co(CN)6]2 Prussian blue analogue (PBA) NC precursors using in situ nitridation and calcination processes. Co3N@AN-C NCs (2 h) demonstrate better OER activity with a remarkably low Tafel plot (69.6 mV∙dec-1), low overpotential of 280 mV at a current density of 10 mA∙cm-2. Additionally, excellent cycling stability in alkaline electrolytes was exhibited without morphological changes and voltage elevations, superior to most reported hierarchical structures of transition-metal nitride particles. The presented strategy for synergy effects of metal-organic frameworks (MOFs)-derived transition-metal nitrides-carbon hybrid nanostructures provides prospects for developing high-performance and advanced electrocatalyst materials.

Keywords

transition-metal nitridemetal organic frameworkmesoporousoxygen evaluation reactionalkaline water electrolysis

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Nano Research
Volume 12 Issue 7,
July 2019
Pages 1605-1611
DOI: 10.1007/s12274-019-2399-3
Cite this article:
Kang BK, Im SY, Lee J, et al. In-situ formation of MOF derived mesoporous Co3N/amorphous N-doped carbon nanocubes as an efficient electrocatalytic oxygen evolution reaction. Nano Research, 2019, 12(7): 1605-1611. https://doi.org/10.1007/s12274-019-2399-3
Topics:
Aluminum nitrideCarbonElectrocatalystsMesoporous materials NitridesOrganic polymersOrganometallicsOxygenRefractory metal compoundsTransition metals

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Received: 11 December 2018
Revised: 08 March 2019
Accepted: 01 April 2019
Published: 23 April 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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