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Research Article

Growth of 12-inch uniform monolayer graphene film on molten glass and its application in PbI2-based photodetector

Zhaolong Chen1,2, Haina Ci1,2, Zhenjun Tan1,2, Zhipeng Dou3, Xu-dong Chen1, Bingzhi Liu1,2, Ruojuan Liu1,2, Li Lin1,2, Lingzhi Cui1,2, Peng Gao3,4, Hailin Peng1,2,4, Yanfeng Zhang4,5( ), Zhongfan Liu1,2,4( )
Center for Nanochemistry (CNC),Beijing Science and Engineering Center for Nanocarbons, College of Chemistry and Molecular Engineering, Peking University,Beijing,100871,China;
Beijing National Laboratory for Molecular Sciences,Beijing,100871,China;
Electron Microscopy Laboratory,School of Physics, Peking University,Beijing,100871,China;
Beijing Graphene Insititue (BGI),Beijing,100095,China;
Department of Materials Science and Engineering,College of Engineering, Peking University,Beijing,100871,China;
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Abstract

Direct growth of large area uniform graphene on functional insulating materials is essential for engineering versatile applications of graphene. However, the existing synthesis approaches can hardly avoid the generation of non-uniform multilayer graphene along the gas flow direction, affording huge challenges for further scaling up. Herein, by exploiting the molten state of soda-lime glass, we have accomplished the direct growth of large area uniform (up to 30 cm × 6 cm) graphene via a facile chemical vapor deposition route on low cost soda-lime glass. The use of molten glass eliminates the chemically active sites (surface corrugations, scratches, defects), and improves the mobility of carbon precursors, affording uniform nucleation and growth of monolayer graphene. Intriguingly, thus-obtained graphene acts as an ideal coating layer for the surface crystallographic modification of soda-lime glass, making it epitaxy substrates for synthesizing high-quality PbI2 nanoplates and continues films. Accordingly, a prototype photodetector was fabricated to present excellent photoelectrical properties of high responsivity (~ 600 on/off current ratio) and fast response speed (18 μs). This work hereby paves ways for the batch production and the direct applications of graphene glass as platforms for constructing high performance electronic and optoelectronic devices.

Keywords

graphenechemical vapor depositiondielectric substratelead iodidephotodetector

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Nano Research
Volume 12 Issue 8,
August 2019
Pages 1888-1893
DOI: 10.1007/s12274-019-2453-1
Cite this article:
Chen Z, Ci H, Tan Z, et al. Growth of 12-inch uniform monolayer graphene film on molten glass and its application in PbI2-based photodetector. Nano Research, 2019, 12(8): 1888-1893. https://doi.org/10.1007/s12274-019-2453-1
Topics:
Chemical vapor depositionFilm growthIodine compoundsLayered semiconductorsLead compoundsMonolayersPhotodetectorsPhotonsSubstrates

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Received: 27 April 2019
Revised: 02 June 2019
Accepted: 03 June 2019
Published: 14 June 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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