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Research Article

Iron sulfides with dopamine-derived carbon coating as superior performance anodes for sodium-ion batteries

Aihua Jin1,2<, Seung-Ho Yu3<, Jae-Hyuk Park1,2, Seok Mun Kang1,2, Mi-Ju Kim1,2, Tae-Yeol Jeon4, Junyoung Mun5( ), Yung-Eun Sung1,2( )
Center for Nanoparticle Research,Institute for Basic Science (IBS),Seoul,08826,Republic of Korea;
School of Chemical and Biological Engineering,Seoul National University,Seoul,08826,Republic of Korea;
Department of Chemical and Biological Engineering,Korea University, 145 Anam-ro, Seongbuk-gu, Seoul,02841,Republic of Korea;
Beamline Department,Pohang Accelerator Laboratory (PAL),Pohang,37673,Republic of Korea;
Department of Energy and Chemical Engineering,Incheon National University, 12-1,Songdo-dong, Yeonsu-gu, Incheon,22012,Republic of Korea;

§ Aihua Jin and Seung-Ho Yu contributed equally to this work.

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Graphical Abstract

Abstract

High energy ball-milled iron sulfides with thin carbon layer coating (BM-FeS/C composites) were prepared by the simple and economical process. Ball-milled process, followed by carbon coating, reduced the particle size and increased the electrical conductivity. When employed as sodium-ion battery anodes, BM-FeS/C composites showed extremely high electrochemical performance with reversible specific capacity of 589.8 mAh·g-1 after 100 cycles at a current density of 100 mA·g-1. They also exhibited superior rate capabilities of 375.9 mAh·g-1 even at 3.2 A·g-1 and 423.6 mAh·g-1 at 1.5 A·g-1. X-ray absorption near edge structure analysis confirmed the electrochemical pathway for conversion reaction of BM-FeS/C composites.

Keywords

sodium-ion batteriesiron sulfideshigh energy ball-millingdopamineX-ray absorption near edge structure

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Nano Research
Volume 12 Issue 10,
October 2019
Pages 2609-2613
DOI: 10.1007/s12274-019-2495-4
Cite this article:
Jin A, Yu S-H, Park J-H, et al. Iron sulfides with dopamine-derived carbon coating as superior performance anodes for sodium-ion batteries. Nano Research, 2019, 12(10): 2609-2613. https://doi.org/10.1007/s12274-019-2495-4
Topics:
Absorption spectrumAnodesBall millingCarbonCoatings Iron compoundsMetal ionsNeurophysiologyParticle sizeParticle size analysisSulfur compoundsX-ray absorption

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Received: 01 May 2019
Revised: 05 July 2019
Accepted: 27 July 2019
Published: 15 August 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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