AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

Direct synthesis of L10-FePt nanoparticles from single-source bimetallic complex and their electrocatalytic applications in oxygen reduction and hydrogen evolution reactions

Zhengong Meng1,§, Fei Xiao2,§, Zhuoxun Wei1, Xuyun Guo3, Ye Zhu3, Yurong Liu1, Guijun Li4, Zhen-Qiang Yu1( ), Minhua Shao2( ), Wai-Yeung Wong5,6( )
College of Chemistry and Environmental Engineering and Institute of Low-dimensional Materials Genome InitiativeShenzhen UniversityShenzhen518060China
Department of Chemical and Biological EngineeringHong Kong University of Science and TechnologyClear Water BayKowloon999077Hong Kong, China
Department of Applied Biology and Chemical TechnologyThe Hong Kong Polytechnic UniversityHung Hom, Hong KongChina
Department of Applied PhysicsThe Hong Kong Polytechnic UniversityHung Hom, Hong KongChina
State Key Laboratory of Ultra-precision Machining TechnologyDepartment of Industrial and Systems EngineeringThe Hong Kong Polytechnic UniversityHung Hom, Hong KongChina
The Hong Kong Polytechnic University Shenzhen Research InstituteShenzhen518057China

§ Zhengong Meng and Fei Xiao contributed equally to this work.

Show Author Information

Graphical Abstract

Abstract

L10-FePt nanoparticles (NPs) with high chemical ordering represent effective electrocatalysts to reduce the cost and enhance their catalytic performance in fuel cells. A molecular strategy of preparing highly ordered FePt NPs was used by direct pyrolysis of a Fe, Pt-containing bimetallic complex. The resultant L10-FePt NPs had very high crystallinity as reflected by the obvious diffraction patterns, clear lattice fringes and characteristic X-ray diffraction peaks, etc. Besides, the strong ferromagnetism with room temperature coercivity of 27 kOe further confirmed the face-centered tetragonal (fct) phase in good agreement with the ordered nanostructures. The FePt NPs can be used as electrocatalysts to catalyze oxygen reduction reaction (ORR) in an O2-saturated 0.1 M HClO4 solution and hydrogen evolution reaction (HER) in the 0.5 M H2SO4 electrolyte with much better performance than commercial Pt/C, and showed quite high stability after 10, 000 cycles. The strategy utilizing organometallic precursors to prepare metal alloy NPs was demonstrated to be a reliable approach for improving the catalytic efficiency in fuel cells.

Keywords

bimetallic complexsingle-source precursorFePt nanoparticleoxygen reduction reactionhydrogen evolution reaction

Electronic Supplementary Material

Download File(s)
12274_2019_2537_MOESM1_ESM.pdf (1.5 MB)

References

1

Shao, M. H.; Chang, Q. W.; Dodelet, J. P.; Chenitz, R. Recent advances in electrocatalysts for oxygen reduction reaction. Chem. Rev., 2016, 116, 3594–3657.
Crossref Google Scholar
2

Zhou, M.; Wang, H. L.; Guo, S. J. Towards high-efficiency nanoelectrocatalysts for oxygen reduction through engineering advanced carbon nanomaterials. Chem. Soc. Rev., 2016, 45, 1273–1307.
Crossref Google Scholar
3

Li, D. G.; Lv, H. F.; Kang, Y. J.; Markovic, N. M.; Stamenkovic, V. R. Progress in the development of oxygen reduction reaction catalysts for low-temperature fuel cells. Annu. Rev. Chem. Biomol. Eng., 2016, 7, 509–532.
Crossref Google Scholar
4

Martínez-Huerta, M. V.; Lázaro, M. J. Electrocatalysts for low temperature fuel cells. Catal. Today, 2017, 285, 3–12.
Crossref Google Scholar
5

Debe, M. K. Electrocatalyst approaches and challenges for automotive fuel cells. Nature, 2012, 486, 43–51.
Crossref Google Scholar
6

Chaudhari, N. K.; Joo, J.; Kwon, H. B.; Kim, B.; Kim, H. Y.; Joo, S. H.; Lee, K. Nanodendrites of platinum-group metals for electrocatalytic applications. Nano Res., 2018, 11, 6111–6140.
Crossref Google Scholar
7

Xia, W.; Mahmood, A.; Liang, Z. B.; Zou, R. Q.; Guo, S. J. Earth-abundant nanomaterials for oxygen reduction. Angew. Chem., Int. Ed., 2016, 55, 2650–2676.
Crossref Google Scholar
8

Xia, Z. H.; An, L.; Chen, P. K.; Xia, D. G. Non-Pt nanostructured catalysts for oxygen reduction reaction: Synthesis, catalytic activity and its key factors. Adv. Energy Mater., 2016, 6, 1600458.
Crossref Google Scholar
9

Hu, F.; Yang, H. C.; Wang, C. H.; Zhang, Y. J.; Lu, H.; Wang, Q. B. Co-N-doped mesoporous carbon hollow spheres as highly efficient electrocatalysts for oxygen reduction reaction. Small, 2017, 13, 1602507.
Crossref Google Scholar
10

Yan, D. F.; Guo, L.; Xie, C.; Wang, Y. Y.; Li, Y. X.; Li, H.; Wang, S. Y. N, P-dual doped carbon with trace Co and rich edge sites as highly efficient electrocatalyst for oxygen reduction reaction. Sci. China Mater., 2018, 61, 679–685.
Crossref Google Scholar
11

Wang, X. Q.; Wang, W. Y.; Qiao, M.; Wu, G.; Chen, W. X.; Yuan, T. W.; Xu, Q.; Chen, M.; Zhang, Y.; Wang, X. et al. Atomically dispersed Au1 catalyst towards efficient electrochemical synthesis of ammonia. Sci. Bull., 2018, 63, 1246–1253.
Crossref Google Scholar
12

Shao, Q.; Li, F. M.; Chen, Y.; Huang, X. Q. The advanced designs of high-performance platinum-based electrocatalysts: Recent progresses and challenges. Adv. Mater. Interfaces, 2018, 5, 1800486.
Crossref Google Scholar
13

Yao, Y. C.; Hu, S. L.; Chen, W. X.; Huang, Z. Q.; Wei, W. C.; Yao, T.; Liu, R. R.; Zang, K. T.; Wang, X. Q.; Wu, G. et al. Engineering the electronic structure of single atom Ru sites via compressive strain boosts acidic water oxidation electrocatalysis. Nat. Catal., 2019, 2, 304–313.
Crossref Google Scholar
14

Therrien, A. J.; Hensley, A. J. R.; Marcinkowski, M. D.; Zhang, R. Q.; Lucci, F. R.; Coughlin, B.; Schilling, A. C.; McEwen, J. S.; Sykes, E. C. H. An atomic-scale view of single-site Pt catalysis for low-temperature CO oxidation. Nat. Catal., 2018, 1, 192–198.
Crossref Google Scholar
15

Zhu, Y. Q.; Cao, T.; Cao, C. B.; Luo, J.; Chen, W. X.; Zheng, L. R.; Dong, J. C.; Zhang, J.; Han, Y. H.; Li, Z. et al. One-pot pyrolysis to N-doped graphene with high-density Pt single atomic sites as heterogeneous catalyst for alkene hydrosilylation. ACS Catal., 2018, 8, 10004–10011.
Crossref Google Scholar
16

Zhang, L.; Doyle-Davis, K.; Sun, X. L. Pt-based electrocatalysts with high atom utilization efficiency: From nanostructures to single atoms. Energy Environ. Sci., 2019, 12, 492–517.
Crossref Google Scholar
17

Xia, B. Y.; Ng, W. T.; Wu, H. B.; Wang, X.; Lou, X. W. Self-supported interconnected Pt nanoassemblies as highly stable electrocatalysts for low-temperature fuel cells. Angew. Chem., Int. Ed., 2012, 51, 7213–7216.
Crossref Google Scholar
18

Li, M. F.; Zhao, Z. P.; Cheng, T.; Fortunelli, A.; Chen, C. Y.; Yu, R.; Zhang, Q. H.; Gu, L.; Merinov, B. V.; Lin, Z. Y. et al. Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction. Science, 2016, 354, 1414–1419.
Crossref Google Scholar
19

Singh, A. K.; Xu, Q. Synergistic catalysis over bimetallic alloy nanoparticles. ChemCatChem, 2013, 5, 652–676.
Crossref Google Scholar
20

Sulaiman, J. E.; Zhu, S. Q.; Xiang, Z. L.; Chang, Q. W.; Shao, M. H. Pt-Ni octahedra as electrocatalysts for the ethanol electro-oxidation reaction. ACS Catal., 2017, 7, 5134–5141.
Crossref Google Scholar
21

Martins, M.; Šljukić, B.; Sequeira, C. A. C.; Soylu, G. S. P.; Yurtcan, A. B.; Bozkurt, G.; Sener, T.; Santos, D. M. F. PtNi supported on binary metal oxides: Potential bifunctional electrocatalysts for low-temperature fuel cells? Appl. Surf. Sci. 2018, 428, 31–40.
Crossref Google Scholar
22

Du, N. N.; Wang, C. M.; Long, R.; Xiong, Y. J. N-doped carbon-stabilized PtCo nanoparticles derived from Pt@ZIF-67: Highly active and durable catalysts for oxygen reduction reaction. Nano Res., 2017, 10, 3228–3237.
Crossref Google Scholar
23

Yao, Y. C.; He, D. S.; Lin, Y.; Feng, X. Q.; Wang, X.; Yin, P. Q.; Hong, X.; Zhou, G.; Wu, Y. E.; Li, Y. D. Modulating fcc and hcp ruthenium on the surface of palladium-copper alloy through tunable lattice mismatch. Angew. Chem., Int. Ed., 2016, 55, 5501–5505.
Crossref Google Scholar
24

Sandstrom, R.; Hu, G. Z.; Wågberg, T. Compositional evaluation of coreduced Fe-Pt metal acetylacetonates as PEM fuel cell cathode catalyst. ACS Appl. Energy Mater., 2018, 1, 7106–7115.
Crossref Google Scholar
25

Li, Q.; Wu, L. H.; Wu, G.; Su, D.; Lv, H. F.; Zhang, S.; Zhu, W. L.; Casimir, A.; Zhu, H. Y.; Mendoza-Garcia, A. et al. New approach to fully ordered fct-FePt nanoparticles for much enhanced electrocatalysis in acid. Nano Lett., 2015, 15, 2468–2473.
Crossref Google Scholar
26

Hong, Y.; Kim, H. J.; Yang, D.; Lee, G.; Nam, K. M.; Jung, M. H.; Kim, Y. M.; Choi, S. I.; Seo, W. S. Facile synthesis of fully ordered L10-FePt nanoparticles with controlled Pt-shell thicknesses for electrocatalysis. Nano Res., 2017, 10, 2866–2880.
Crossref Google Scholar
27

Li, J. R.; Xi, Z.; Pan, Y. T.; Spendelow, J. S.; Duchesne, P. N.; Su, D.; Li, Q.; Yu, C.; Yin, Z. Y.; Shen, B. et al. Fe Stabilization by intermetallic L10-FePt and Pt catalysis enhancement in L10-FePt/Pt nanoparticles for efficient oxygen reduction reaction in fuel cells. J. Am. Chem. Soc., 2018, 140, 2926–2932.
Crossref Google Scholar
28

Lin, F.; Sun, Y. J.; Lai, J. P.; Wang, K.; Tang, Y. H.; Chao, Y. G.; Yang, Y.; Feng, J. R.; Lv, F.; Zhou, P. et al. 3D PtFe clusters with cube-in-cube structure enhance oxygen reduction catalysis and electrochemical sensing. Small Methods, 2018, 2, 1800073.
Crossref Google Scholar
29

He, Y.; Wu, Y. L.; Zhu, X. X.; Wang, J. N. Remarkable improvement of the catalytic performance of PtFe nanoparticles by structural ordering and doping. ACS Appl. Mater. Interfaces, 2019, 11, 11527–11536.
Crossref Google Scholar
30

Chung, D. Y.; Jun, S. W.; Yoon, G.; Kwon, S. G.; Shin, D. Y.; Seo, P.; Yoo, J. M.; Shin, H.; Chung, Y. H.; Kim, H. et al. Highly durable and active PtFe nanocatalyst for electrochemical oxygen reduction reaction. J. Am. Chem. Soc., 2015, 137, 15478–15485.
Crossref Google Scholar
31

Sun, S. H. Recent advances in chemical synthesis, self-assembly, and applications of FePt nanoparticles. Adv. Mater., 2006, 18, 393–403.
Crossref Google Scholar
32

Ghosh, S.; Basu, R. N. Multifunctional nanostructured electrocatalysts for energy conversion and storage: Current status and perspectives. Nanoscale, 2018, 10, 11241–11280.
Crossref Google Scholar
33

Yan, Y.; He, T.; Zhao, B.; Qi, K.; Liu, H. F.; Xia, B. Y. Metal/covalent-organic frameworks-based electrocatalysts for water splitting. J. Mater. Chem. A, 2018, 6, 15905–15926.
Crossref Google Scholar
34

Li, K.; Li, Y.; Wang, Y. M.; Ge, J. J.; Liu, C. P.; Xing W. Enhanced electrocatalytic performance for the hydrogen evolution reaction through surface enrichment of platinum nanoclusters alloying with ruthenium in situ embedded in carbon. Energy Environ. Sci., 2018, 11, 1232–1239.
Crossref Google Scholar
35

Wu, L. H.; Mendoza-Garcia, A.; Li, Q.; Sun, S. H. Organic phase syntheses of magnetic nanoparticles and their applications. Chem. Rev., 2016, 116, 10473–10512.
Crossref Google Scholar
36

Zhu, K.; Ju, Y. M.; Xu, J. J.; Yang, Z. Y.; Gao, S.; Hou, Y. L. Magnetic nanomaterials: Chemical design, synthesis, and potential applications. Acc. Chem. Res., 2018, 51, 404–413.
Crossref Google Scholar
37

Zhou, M.; Wang, H. L.; Vara, M.; Hood, Z. D.; Luo, M.; Yang, T. H.; Bao, S. X.; Chi, M. F.; Xiao, P.; Zhang, Y. H. et al. Quantitative analysis of the reduction kinetics responsible for the one-pot synthesis of Pd-Pt bimetallic nanocrystals with different structures. J. Am. Chem. Soc., 2016, 138, 12263–12270.
Crossref Google Scholar
38

Kang, E.; Jung, H.; Park, J. G.; Kwon, S.; Shim, J.; Sai, H.; Wiesner, U.; Kim, J. K.; Lee, J. Block copolymer directed one-pot simple synthesis of L10-phase FePt nanoparticles inside ordered mesoporous aluminosilicate/carbon composites. ACS Nano, 2011, 5, 1018–1025.
Crossref Google Scholar
39

Dong, Q. C.; Meng, Z. G.; Ho, C. L.; Guo, H. E.; Yang, W. Y.; Manners, I.; Xu, L. L.; Wong, W. Y. A molecular approach to magnetic metallic nanostructures from metallopolymer precursors. Chem. Soc. Rev., 2018, 47, 4934–4953.
Crossref Google Scholar
40

Lee, E.; Huang, Z. G.; Ryu, J. H.; Lee, M. Rigid-flexible block molecules based on a laterally extended aromatic segment: Hierarchical assembly into single fibers, flat ribbons, and twisted ribbons. Chem. —Eur. J., 2008, 14, 6957–6966.
Crossref Google Scholar
41

Zopes, D.; Hegemann, C.; Schläfer, J.; Tyrra, W.; Mathur, S. Single-source precursors for alloyed gold-silver nanocrystals-a molecular metallurgy approach. Inorg. Chem., 2015, 54, 3781–3787.
Crossref Google Scholar
42

Zhu, Z. Q.; Wang, S. W.; Du, J.; Jin, Q.; Zhang, T. R.; Cheng, F. Y.; Chen, J. Ultrasmall Sn nanoparticles embedded in nitrogen-doped porous carbon as high-performance anode for lithium-ion batteries. Nano Lett., 2014, 14, 153–157.
Crossref Google Scholar
43

Meng, Z. G.; Ho, C. L.; Wong, H. F.; Yu, Z. Q.; Zhu, N. Y.; Li, G. J.; Leung, C. W.; Wong, W. Y. Lithographic patterning of ferromagnetic FePt nanoparticles from a single-source bimetallic precursor containing hemiphasmidic structure for magnetic data recording media. Sci. China Mater., 2019, 62, 566–576.
Crossref Google Scholar
44

Ferrari, A. C.; Robertson, J. Resonant Raman spectroscopy of disordered, amorphous, and diamondlike carbon. Phys. Rev. B, 2001, 64, 075414.
Crossref Google Scholar
45

Rutledge, R. D.; Morris III, W. H.; Wellons, M. S.; Gai, Z.; Shen, J.; Bentley, J.; Wittig, J. E.; Lukehart, C. M. Formation of FePt nanoparticles having high coercivity. J. Am. Chem. Soc., 2006, 128, 14210–14211.
Crossref Google Scholar
46

Medwal, R.; Sehdev, N.; Annapoorni, G. S. Electronic states of self stabilized L10 FePt alloy nanoparticles. Appl. Phys. A, 2012, 109, 403–408.
Crossref Google Scholar
47

Staunton, J. B.; Ostanin, S.; Razee, S. S. A.; Gyorffy, B. L.; Szunyogh, L.; Ginatempo, B.; Bruno, E. Temperature dependent magnetic anisotropy in metallic magnets from an ab initio electronic structure theory: L10-ordered FePt. Phys. Rev. Lett., 2004, 93, 257204.
Crossref Google Scholar
Nano Research
Volume 12 Issue 12,
December 2019
Pages 2954-2959
DOI: 10.1007/s12274-019-2537-y
Cite this article:
Meng Z, Xiao F, Wei Z, et al. Direct synthesis of L10-FePt nanoparticles from single-source bimetallic complex and their electrocatalytic applications in oxygen reduction and hydrogen evolution reactions. Nano Research, 2019, 12(12): 2954-2959. https://doi.org/10.1007/s12274-019-2537-y
Topics:
Binary alloysChlorine compoundsCrystallinityElectrocatalystsElectrolytesElectrolytic reduction Fuel cellsHydrogenNanoparticlesOrganometallicsOxygenPlatinum compoundsSynthesis (chemical)

744

Views

61

Crossref

N/A

Web of Science

58

Scopus

4

CSCD

Altmetrics
Received: 29 July 2019
Revised: 20 September 2019
Accepted: 07 October 2019
Published: 24 October 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
Return