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Research Article

Superior wide-temperature lithium storage in a porous cobalt vanadate

Haoliang Chen1, Dan Yang1, Xueye Zhuang1, Dong Chen1, Weiling Liu2, Qi Zhang1, Huey Hoon Hng2, Xianhong Rui1,3( ), Qingyu Yan2( ), Shaoming Huang1( )
Guangzhou Key Laboratory of Low-Dimensional Materials and Energy Storage Devices, Collaborative Innovation Center of Advanced Energy Materials, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore
State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, China
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Abstract

Lithium ion batteries (LIBs) that can be operated under extended temperature range hold significant application potentials. Here in this work, we successfully synthesized Co2V2O7 electrode with rich porosity from a facile hydrothermal and combustion process. When applied as anode for LIBs, the electrode displayed excellent stability and rate performance in a wide range of temperatures. Remarkably, a stable capacity of 206 mAh·g-1 was retained after cycling at a high current density of 10 A·g-1 for 6,000 cycles at room temperature (25 °C). And even when tested under extreme conditions, i.e., -20 and 60 °C, the battery still maintained its remarkable stability and rate capability. For example, at -20 °C, a capacity of 633 mAh·g-1 was retained after 50 cycles at 0.1 A·g-1; and even after cycling at 60 °C at 10 A·g-1 for 1,000 cycles, a reversible capacity of 885 mAh·g-1 can be achieved. We believe the development of such electrode material will facilitate progress of the next-generation LIBs with wide operating windows.

Keywords

lithium-ion batteryanode materialcobalt vanadateporous structurewide-temperature performance

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Nano Research
Volume 13 Issue 7,
July 2020
Pages 1867-1874
DOI: 10.1007/s12274-019-2547-9
Cite this article:
Chen H, Yang D, Zhuang X, et al. Superior wide-temperature lithium storage in a porous cobalt vanadate. Nano Research, 2020, 13(7): 1867-1874. https://doi.org/10.1007/s12274-019-2547-9
Topics:
AnodesCobaltCobalt compoundsCobalt depositsPorosityVanadium compounds
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Received: 10 September 2019
Revised: 10 October 2019
Accepted: 16 October 2019
Published: 26 October 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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