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Research Article

Blue emitting CsPbBr3 perovskite quantum dot inks obtained from sustained release tablets

Hewei Yang1,2Yaqing Feng1,2Zhiyu Tu1Kuo Su1,2Xiaozhi Fan3Bingjie Liu1Zhiping Shi1,2Yuzhe Zhang1,2Chenyang Zhao1Bao Zhang1( )
School of Chemical Engineering and TechnologyTianjin UniversityTianjin300350China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)Tianjin300072China
School of Life SciencesTianjin UniversityTianjin300072China
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Abstract

Blue emitting perovskite ink obtained from cesium lead halide quantum dots bearing chlorine (CsPbClxBr3-x, 0 < x ≤ 3) suffers from the low photoluminescence quantum yield and poor stability. Cesium lead bromine (CsPbBr3) quantum dots free of chlorine have more stable crystal structure and fewer crystal defects. Precise control of crystal sizes and surface passivation components of CsPbBr3 quantum dots is crucial for the best use of quantum confinement effect and blueshift of emission wavelength to blue region. Here, by polymerizing acrylamide under UV-light irradiation to form polymer gel networks in dimethyl sulfoxide (DMSO) with CsPbBr3 precursors and passivating agents trapped, we successfully prepared novel sustained release tablets with different shapes and sizes. Thanks to the limitation of the polymer networks on solvent releasing, the resulting CsPbBr3 quantum dots have the average size of 1.1 ± 0.2 nm. On the basis of the excellent quantum confinement effect and optimized surface passivation, the obtained PQD ink can emit high quality blue light for more than 6 weeks. This work elucidates a new and convenient technique to prepare blue emission perovskite quantum dots ink with high stability and photoluminescence quantum yield and provides a great potential technology for the preparation of perovskite optoelectronic devices.

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Nano Research
Pages 3129-3134
Cite this article:
Yang H, Feng Y, Tu Z, et al. Blue emitting CsPbBr3 perovskite quantum dot inks obtained from sustained release tablets. Nano Research, 2019, 12(12): 3129-3134. https://doi.org/10.1007/s12274-019-2566-6
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Received: 26 August 2019
Revised: 08 November 2019
Accepted: 10 November 2019
Published: 18 November 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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