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Research Article

Interlayer-expanded MoS2 assemblies for enhanced electrochemical storage of potassium ions

Sijia Di, Pan Ding, Yeyun Wang, Yunling Wu, Jun Deng, Lin Jia, Yanguang Li( )
Institute of Functional Nano and Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, China
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Abstract

Potassium-ion batteries are regarded as the low-cost alternative to lithium-ion batteries. However, their development is hampered by the lack of suitable electrode materials. In this work, we demonstrate that MoS2 with expanded interlayers represents a promising candidate for the electrochemical storage of potassium ions. Hierarchical interlayer-expanded MoS2 assemblies supported on carbon nanotubes are prepared via a straightforward solution method. The increased interlayer spacing not only enables the better accommodation of foreign ions, but also lowers the diffusion energy barrier and improves diffusion kinetics of ions. When investigated as the anode material of potassium ion batteries, our interlayer-expanded MoS2 assemblies exhibit an excellent electrochemical performance with large capacity (up to ~ 520 mAh·g-1), good rate capability (~ 310 mAh·g-1 at 1,000 mA·g-1) and impressive cycling stability, superior to most competitors.

Keywords

molybdenum disulfideinterlayer expansionpotassium ion batterieshierarchical structure

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Nano Research
Volume 13 Issue 1,
January 2020
Pages 225-230
DOI: 10.1007/s12274-019-2604-4
Cite this article:
Di S, Ding P, Wang Y, et al. Interlayer-expanded MoS2 assemblies for enhanced electrochemical storage of potassium ions. Nano Research, 2020, 13(1): 225-230. https://doi.org/10.1007/s12274-019-2604-4
Topics:
AnodesIon batteriesIonsLayered semiconductorsLithiumMolybdenum compoundsPotassium

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Received: 13 October 2019
Revised: 01 December 2019
Accepted: 11 December 2019
Published: 02 January 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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