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Research Article

Room-temperature photodeposition of conformal transition metal based cocatalysts on BiVO4 for enhanced photoelectrochemical water splitting

Lu Wang, Tao Zhang, Jinzhan Su( ), Liejin Guo ( )
International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy & Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China
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Abstract

Photoelectrochemical (PEC) water splitting using semiconductors offers a promising way to convert renewable solar energy to clean hydrogen fuels. However, due to the sluggish reaction kinetics of water oxidation, significant charge recombination occurred at the photoanode/electrolyte interface and cause decrease of its PEC performance. To reduce the surface recombination, we deposit different transition metal complexes on BiVO4 nanocone arrays by a versatile light driven in-situ two electrode photodeposition approach without applied bias. Conformal cobalt phosphate "Co-Pi" , nickel borate "Ni-Bi" and manganese phosphate "Mn-Pi" complexes were deposited on BiVO4 nanocone arrays to form core-shell structure photoanode, all of which lead to enhanced photoelectrochemical performance. The photocurrent of the Co-Pi/BiVO4 photoanode under front-side illumination for 5 min is increased by 4 folds comparing to that of bare BiVO4 photoanode at 0.6 V vs. RHE, reaching a hole transfer efficiency as high as 94.5% at 1.23 V vs. RHE. The proposed photodeposition strategy is simple and efficient, and can be extended to deposite cocatalyst on other semiconductors with a valence band edge located at a potential more positive than the oxidation potential of transition metal ion in the cocatalyst.

Keywords

bismuth vanadatephotoelectrochemcial water splittingconformal photodepositioncocatalyst

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Nano Research
Volume 13 Issue 1,
January 2020
Pages 231-237
DOI: 10.1007/s12274-019-2605-3
Cite this article:
Wang L, Zhang T, Su J, et al. Room-temperature photodeposition of conformal transition metal based cocatalysts on BiVO4 for enhanced photoelectrochemical water splitting. Nano Research, 2020, 13(1): 231-237. https://doi.org/10.1007/s12274-019-2605-3
Topics:
Cobalt compoundsHydrogen fuelsManganese compoundsMetal complexesMetal ionsNanostructuresNickel compoundsPhotoelectrochemical cellsSolar energySolar power generationTransition metals

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Received: 27 August 2019
Revised: 12 December 2019
Accepted: 14 December 2019
Published: 27 December 2019
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019
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