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Research Article

A facile strategy of in-situ anchoring of Co3O4 on N doped carbon cloth for an ultrahigh electrochemical performance

Junlin Lu1, Jien Li1, Jing Wan1, Xiangyu Han1, Peiyuan Ji1, Shuang Luo1, Mingxin Gu2, Dapeng Wei2( ), Chenguo Hu1( )
Chongqing Key Laboratory of Soft Condensed Matter Physics and Smart Materials, Department of Applied Physics, Chongqing University, Chongqing 400044, China
Key Laboratory of Multi-Scale Manufacturing Technology, Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China
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Abstract

Enhancement of supercapacitors (SCs) with high-energy density and high-power density is still a great challenge. In this paper, a facile strategy for in situ anchoring of Co3O4 particles on N doped carbon cloth (pCoNCC) is reported. Due to the interaction of the doped N and Co3O4, the electrochemical performance improves significantly, reaching 1,940.13 mF·cm-2 at 1 mA·cm-2 and energy density of 172.46 µWh·cm-2 at the power density of 400 µW·cm-2, much larger than that without N doping electrode of 28.5 mF·cm-2. An aqueous symmetric supercapacitor (ASSC) assembled by two pCoNCC electrodes achieves a maximum energy density of 447.42 µWh·cm-2 and a highest power density of 8,000 µW·cm-2. Utilizing such a high-energy storage ASSC, a digital watch and a temperature-humidity detector are powered for nearly 1 and 2 h, respectively. Moreover, the ASSC displays a superb electrochemical stability of 87.7% retention after 10,000 cycles at 40 mA·cm-2. This work would provide a new sight to enhance active materials performance and be beneficial for the future energy storage and supply systems.

Keywords

Co3O4N dopingcarbon clothsupercapacitor

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Nano Research
Volume 14 Issue 7,
July 2021
Pages 2410-2417
DOI: 10.1007/s12274-019-3242-6
Cite this article:
Lu J, Li J, Wan J, et al. A facile strategy of in-situ anchoring of Co3O4 on N doped carbon cloth for an ultrahigh electrochemical performance. Nano Research, 2021, 14(7): 2410-2417. https://doi.org/10.1007/s12274-019-3242-6
Topics:
CarbonDoping (additives)Energy storageSupercapacitor

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Received: 14 September 2020
Revised: 12 November 2020
Accepted: 13 November 2020
Published: 05 July 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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