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Research Article

Self-magnetic-attracted NixFe(1-x)@NixFe(1-x)O nanoparticles on nickel foam as highly active and stable electrocatalysts towards alkaline oxygen evolution reaction

Zuobo Yang, Xin Liang( )
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
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Abstract

A facile self-magnetic-attracted approach was developed for highly active and stable NixFe(1-x)@NixFe(1-x)O/NF electrocatalysts towards alkaline oxygen evolution reaction. Firstly, a low-cost and scalable synthesis method was developed to synthesis 4-5 nm hydrophilic NixFe(1-x)@NixFe(1-x)O core-shell nanocrystals with superparamagnetism. Then, these NixFe(1-x)@NixFe(1-x)O nanoparticles (NPs) could be easily supported on nickel foam without any binders or additives. Optimized by the composition effect, the Ni0.7Fe0.3@Ni0.7Fe0.3O/NF exhibits excellent activity for oxygen evolution reaction (OER), requires only 215 mV at 10 mA·cm-2 and 260 mV at 100 mA·cm-2, with a Tafel slope of 47.4 mV·dec-1 in 1.0 M KOH. Moreover, the underlying mechanism was carefully studied by X-ray diffraction (XRD), Raman, X-ray photoelectron spectroscopy (XPS) and X-ray absorption near-edge spectra (XANES) analysis and density functional theory (DFT) calculations. Due to the self-magnetic attraction, the catalyst shows outstanding stability throughout the electrocatalysis, surpassing than most self-supported catalysts. This work provides a new strategy for the construction of highly active and stable OER electrocatalysts, the nearly monodisperse magnetic NixFe(1-x)@NixFe(1-x)O NPs also serve an ideal building block for fundamental research of nickel-iron based catalyst.

Keywords

nearly monodisperse magnetic nanoparticlesself-magnetic-attracted approachoxygen evolution reaction

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Nano Research
Volume 13 Issue 2,
February 2020
Pages 461-466
DOI: 10.1007/s12274-020-2630-2
Cite this article:
Yang Z, Liang X. Self-magnetic-attracted NixFe(1-x)@NixFe(1-x)O nanoparticles on nickel foam as highly active and stable electrocatalysts towards alkaline oxygen evolution reaction. Nano Research, 2020, 13(2): 461-466. https://doi.org/10.1007/s12274-020-2630-2
Topics:
Density functional theoryElectrocatalysis ElectrocatalystsElectrolysis Iron researchNanoparticlesNickelOxygenPhotoelectron spectroscopyPotassium hydroxideX-ray absorptionX-ray photoelectron spectroscopy

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Received: 19 November 2019
Revised: 26 December 2019
Accepted: 28 December 2019
Published: 17 January 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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