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Research Article

Improving CNT-Si solar cells by metal chloride-to-oxide transformation

Huaisheng Wu1, Xuewei Zhao1, Yizeng Wu1, Qinghuan Ji1, Linxiu Dai1, Yuanyuan Shang2, Anyuan Cao1( )
Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China
School of Physical and Microelectronics, Zhengzhou University, Zhengzhou 450052, China
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Abstract

Transitional metal oxides (TMOs) are important functional materials in silicon-based and thin-film optoelectronics. Here, TMOs are applied in carbon nanotube (CNT)-Si solar cells by spin-coating solutions of metal chlorides that undergo favorable transformation in ambient conditions. An unconventional change in solar cell behavior is observed after coating two particular chlorides (MoCl5 and WCl6, respectively), characterized by an initial severe degradation followed by gradual recovery and then well surpassing the original performance. Detailed analysis reveals that the formation of corresponding oxides (MoO3 and WO3) enables two primary functions on both CNTs (p-type doping) and Si (inducing inversion layer), leading to significant improvement in open-circuit voltage and fill factor, with power conversion efficiencies up to 13.0% (MoO3) and 13.4% (WO3). Further combining with other chlorides to increase the short-circuit current, ultimate cells efficiencies achieve >16% with over 90% retention after 24 h, which are among the highest stable efficiencies reported for CNT-Si solar cells. The transformation of functional layers as demonstrated here has profound influence on the device characteristics, and represents a potential strategy in low-cost manufacturing of next-generation high efficiency photovoltaics.

Keywords

carbon nanotube (CNT)-Si solar cellchloride to oxide transformationMoO3 and WO3inversion layer

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Nano Research
Volume 13 Issue 2,
February 2020
Pages 543-550
DOI: 10.1007/s12274-020-2648-5
Cite this article:
Wu H, Zhao X, Wu Y, et al. Improving CNT-Si solar cells by metal chloride-to-oxide transformation. Nano Research, 2020, 13(2): 543-550. https://doi.org/10.1007/s12274-020-2648-5
Topics:
Carbon nanotubesChlorine compoundsCoatings Molecular biologyMolybdenum oxideSemiconductor dopingSilicon compoundsTungsten compounds

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Received: 03 November 2019
Revised: 06 January 2020
Accepted: 08 January 2020
Published: 12 February 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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