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Research Article

Multi-shelled CuO microboxes for carbon dioxide reduction to ethylene

Dongxing Tan1,2, Jianling Zhang1,2,3( ), Lei Yao4, Xiuniang Tan1,2, Xiuyan Cheng1,2, Qiang Wan1,2, Buxing Han1,2,3, Lirong Zheng4, Jing Zhang4
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Physical Science Laboratory, Huairou National Comprehensive Science Center, Beijing 101400, China
Beijng Synchrotron Radiation Facility (BSRF), Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
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Abstract

The electroreduction of CO2 to valuable chemicals and fuels offers an effective mean for energy storage. Although CO2 has been efficiently converted into C1 products (e.g., carbon monoxide, formic acid, methane and methanol), its convention into high value-added multicarbon hydrocarbons with high selectivity and activity still remains challenging. Here we demonstrate the formation of multi-shelled CuO microboxes for the efficient and selective electrocatalytic CO2 reduction to C2H4. Such a structure favors the accessibility of catalytically active sites, improves adsorption of reaction intermediate (CO), inhibits the diffusion of produced OH- and promotes C-C coupling reaction. Owing to these unique advantages, the multi-shelled CuO microboxes can effectively convert CO2 into C2H4 with a maximum faradaic efficiency of 51.3% in 0.1 M K2SO4. This work provides an effective way to improve CO2 reduction efficiency via constructing micro- and nanostructures of electrocatalysts.

Keywords

multi-shelled CuO microboxesnanocrystalsCO2 reductionC2H4

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Nano Research
Volume 13 Issue 3,
March 2020
Pages 768-774
DOI: 10.1007/s12274-020-2692-1
Cite this article:
Tan D, Zhang J, Yao L, et al. Multi-shelled CuO microboxes for carbon dioxide reduction to ethylene. Nano Research, 2020, 13(3): 768-774. https://doi.org/10.1007/s12274-020-2692-1
Topics:
Copper oxidesElectrocatalystsElectrolytic reduction Fuel storageNanocrystalsReaction intermediates

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Received: 01 December 2019
Revised: 06 January 2020
Accepted: 29 January 2020
Published: 26 February 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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