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Research Article

A microporous aluminum-based metal-organic framework for high methane, hydrogen, and carbon dioxide storage

Bin Wang1,2, Xin Zhang2, Hongliang Huang4, Zhangjing Zhang1, Taner Yildirim3, Wei Zhou3, Shengchang Xiang1( ), Banglin Chen2( )
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, China
Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-6102, USA
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, China
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Abstract

We report a microporous aluminum-based metal-organic framework (MOF), BUT-22 for high methane (CH4), hydrogen (H2), and carbon dioxide (CO2) storage. At 296 K and 80 bar, BUT-22 exhibits a high gravimetric CH4 storage capacity of 530 cm3 (STP)/g (0.379 g/g). BUT-22 also has a high gravimetric H2 storage capacity of 12 wt.% at 100 bar and 77 K. In addition, the CO2 adsorption studies revealed that BUT-22 exhibits a high absolute gravimetric CO2 uptake of 1.7 g/g at 296 K and 40 bar.

Keywords

metal-organic frameworks (MOFs)gas storagemethanehydrogencarbon dioxide

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Nano Research
Volume 14 Issue 2,
February 2021
Pages 507-511
DOI: 10.1007/s12274-020-2713-0
Cite this article:
Wang B, Zhang X, Huang H, et al. A microporous aluminum-based metal-organic framework for high methane, hydrogen, and carbon dioxide storage. Nano Research, 2021, 14(2): 507-511. https://doi.org/10.1007/s12274-020-2713-0
Topics:
AluminumCarbon dioxideHydrogenHydrogen storageMicroporosity Organic polymersOrganometallics

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Received: 29 January 2020
Accepted: 11 February 2020
Published: 09 March 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
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