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Research Article

Co3(hexahydroxytriphenylene)2: A conductive metal-organic framework for ambient electrocatalytic N2 reduction to NH3

Wei Xiong1, Xin Cheng1, Ting Wang2, Yongsong Luo2, Jing Feng1, Siyu Lu3, Abdullah M. Asiri4, Wei Li1(), Zhenju Jiang1(), Xuping Sun2 ()
School of Science, Xihua University, Chengdu 610039, China
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Green Catalysis Center and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
Chemistry Department, Faculty of Science & Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia
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Abstract

As a carbon-neutral alternative to the Haber-Bosch process, electrochemical N2 reduction enables environment-friendly NH3 synthesis at ambient conditions but needs active electrocatalysts for the N2 reduction reaction. Here, we report that conductive metal-organic framework Co3(hexahydroxytriphenylene)2 (Co3HHTP2) nanoparticles act as an efficient catalyst for ambient electrochemical N2-to-NH3 fixation. When tested in 0.5 M LiClO4, such Co3HHTP2 achieves a large NH3 yield of 22.14 μg·h-1·mg-1cat. with a faradaic efficiency of 3.34% at -0.40 V versus the reversible hydrogen electrode. This catalyst also shows high electrochemical stability and excellent selectivity toward NH3 synthesis.

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conductive metal-organic framework Co3HHTP2 nanoparticlesN2 reduction reactionNH3 electrosynthesisambient conditions

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Nano Research
Volume 13 Issue 4,
April 2020
Pages 1008-1012
DOI: 10.1007/s12274-020-2733-9
Cite this article:
Xiong W, Cheng X, Wang T, et al. Co3(hexahydroxytriphenylene)2: A conductive metal-organic framework for ambient electrocatalytic N2 reduction to NH3. Nano Research, 2020, 13(4): 1008-1012. https://doi.org/10.1007/s12274-020-2733-9
Topics:
Catalyst selectivity Chlorine compoundsElectrocatalystsLithium compoundsMetal nanoparticlesNanocatalysts
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