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Research Article

Fabrication of perovskite solar cell with high short-circuit current density (JSC) using moth-eye structure of SiOX

Sucheol Ju1,§, Minseop Byun1,§, Minjin Kim2,§, Junho Jun1, Daihong Huh1, Dong Suk Kim2, Yimhyun Jo2( ), Heon Lee( )
Department of Materials Science and Engineering, Korea University, Anam-ro 145, Sungbuk-Gu, Seoul 136-701, Republic of Korea
KIER-UNIST Advanced Center for Energy, Korea Institute of Energy Research (KIER), UNIST-Gil 50, Eonyang-eup, Ulju-gun, Ulsan 689-851, Republic of Korea

§ Sucheol Ju, Minseop Byun, and Minjin Kim contributed equally to this work.

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Abstract

The performance of solar cells is determined by three factors: the open-circuit voltage (VOC), short-circuit current density (JSC), and fill factor (FF). The VOC and FF are determined by the material bandgap and the series/shunt resistance, respectively. However, JSC is determined by the amount of incident light in addition to the bandgap of the material. In this study, a moth-eye pattern was formed on a glass surface via direct printing to increase the amount of incident light and thus increase JSC. The moth-eye pattern is a typical antireflection pattern that reduces the reflection by gradually increasing the refractive index. A flat perovskite solar cell (F-PSC) and a moth-eye patterned perovskite solar cell (M-PSC) had JSC values of 23.70 and 25.50 mA/cm2, respectively. The power-conversion efficiencies of the F-PSC and M-PSC were 19.81% and 21.77%, respectively.

Keywords

perovskite solar cellsdirect printingmoth-eye patternhydrogen silsesquioxane

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References

[1]
Kuwano, Y.; Okamoto, S.; Tsuda, S. Semiconductor devices save the earth-solar cells. In Proceedings of 1992 International Technical Digest on Electron Devices Meeting, San Francisco, CA, USA, 1992, pp 3-10.
Crossref
[2]
Shi, D.; Adinolfi, V.; Comin, R.; Yuan, M. J.; Alarousu, E.; Buin, A.; Chen, Y.; Hoogland, S.; Rothenberger, A.; Katsiev, K. et al. Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals. Science 2015, 347, 519-522.
Crossref Google Scholar
[3]
Dong, Q. F.; Fang, Y. J.; Shao, Y. C.; Mulligan, P.; Qiu, J.; Cao, L.; Huang, J. S. Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals. Science 2015, 347, 967-970.
Crossref Google Scholar
[4]
Yin, W. J.; Shi, T. T.; Yan, Y. F. Unique properties of halide perovskites as possible origins of the superior solar cell performance. Adv. Mater. 2014, 26, 4653-4658.
Crossref Google Scholar
[5]
Wehrenfennig, C.; Eperon, G. E.; Johnston, M. B.; Snaith, H. J.; Herz, L. M. High charge carrier mobilities and lifetimes in organolead trihalide perovskites. Adv. Mater. 2014, 26, 1584-1589.
Crossref Google Scholar
[6]
Xing, G. C.; Mathews, N.; Sun, S. Y.; Lim, S. S.; Lam, Y. M.; Grätzel, M.; Mhaisalkar, S.; Sum, T. C. Long-range balanced electron- and hole-transport lengths in organic-inorganic CH3NH3PbI3. Science 2013, 342, 344-347.
Crossref Google Scholar
[7]
Stranks, S. D.; Eperon, G. E.; Grancini, G.; Menelaou, C.; Alcocer, M. J. P.; Leijtens, T.; Herz, L. M.; Petrozza, A.; Snaith, H. J. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber. Science 2013, 342, 341-344.
Crossref Google Scholar
[8]
Kim, H. S.; Mora-Sero, I.; Gonzalez-Pedro, V.; Fabregat-Santiago, F.; Juarez-Perez, E. J.; Park, N. G.; Bisquert, J. Mechanism of carrier accumulation in perovskite thin-absorber solar cells. Nat. Commun. 2013, 4, 2242.
Crossref Google Scholar
[9]
Ji, L.; Zhang, X. Z.; Zhang, T.; Wang, Y. F.; Wang, F.; Zhong, Z. Q.; Chen, Z. D.; Xiao, Z. W.; Chen, L.; Li, S. B. Band alignment of Pb-Sn mixed triple cation perovskites for inverted solar cells with negligible hysteresis. J. Mater. Chem. A 2019, 7, 9154-9162.
Crossref Google Scholar
[10]
Green, M. A.; Ho-Baillie, A.; Snaith, H. J. The emergence of perovskite solar cells. Nat. Photonics 2014, 8, 506-514.
Crossref Google Scholar
[11]
Snaith, H. J. Perovskites: The emergence of a new era for low-cost, high-efficiency solar cells. J. Phys. Chem. Lett. 2013, 4, 3623-3630.
Google Scholar
[12]
Park, N. G. Organometal perovskite light absorbers toward a 20% efficiency low-cost solid-state mesoscopic solar cell. J. Phys. Chem. Lett. 2013, 4, 2423-2429.
Google Scholar
[13]
Mitzi, D. B. Solution-processed inorganic semiconductors. J. Mater. Chem. 2004, 14, 2355-2365.
Google Scholar
[14]
Liu, D. T.; Zheng, H. L.; Ji, L.; Chen, H.; Wang, Y. F.; Zhang, P.; Wang, F.; Wu, J.; Chen, Z.; Li, S. B. Improved crystallinity of perovskite via molecularly tailored surface modification of SnO2. J. Power Sources 2019, 441, 227161.
Google Scholar
[15]
Wang, F.; Zhang, T.; Wang, Y. F.; Liu, D. T.; Zhang, P.; Chen, H.; Ji, L.; Chen, L.; Chen, Z. D.; Wu, J. et al. Steering the crystallization of perovskites for high-performance solar cells in ambient air. J. Mater. Chem. A 2019, 7, 12166-12175.
Google Scholar
[16]
Gao, P.; Grätzel, M.; Nazeeruddin, M. K. Organohalide lead perovskites for photovoltaic applications. Energy Environ. Sci. 2014, 7, 2448-2463.
Google Scholar
[17]
Burschka, J.; Pellet, N.; Moon, S. J.; Humphry-Baker, R.; Gao, P.; Nazeeruddin, M. K.; Grätzel, M. Sequential deposition as a route to high-performance perovskite-sensitized solar cells. Nature 2013, 499, 316-319.
Google Scholar
[18]
Kim, H. S.; Lee, C. R.; Im, J. H.; Lee, K. B.; Moehl, T.; Marchioro, A.; Moon, S. J.; Humphry-Baker, R.; Yum, J. H.; Moser, J. E. et al. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci. Rep. 2012, 2, 591.
Google Scholar
[19]
Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 2009, 131, 6050-6051.
Google Scholar
[20]
Jiang, Q.; Chu, Z. M.; Wang, P. Y.; Yang, X. L.; Liu, H.; Wang, Y.; Yin, Z. G.; Wu, J. L.; Zhang, X. W.; You, J. B. Planar-structure perovskite solar cells with efficiency beyond 21%. Adv. Mater. 2017, 29, 1703852.
Google Scholar
[21]
Min, H.; Kim, M.; Lee, S. U.; Kim, H.; Kim, G.; Choi, K.; Lee, J. H.; Seok, S. I. Efficient, stable solar cells by using inherent bandgap of α-phase formamidinium lead iodide. Science 2019, 366, 749-753.
Google Scholar
[22]
Kim, M. C.; Jang, S.; Choi, J.; Kang, S. M.; Choi, M. Moth-eye structured polydimethylsiloxane films for high-efficiency perovskite solar cells. Nano-Micro Lett. 2019, 11, 53.
Google Scholar
[23]
Hou, F. H.; Han, C.; Isabella, O.; Yan, L. L.; Shi, B.; Chen, J. F.; An, S. C.; Zhou, Z. X.; Huang, W.; Ren, H. Z. et al. Inverted pyramidally-textured PDMS antireflective foils for perovskite/silicon tandem solar cells with flat top cell. Nano Energy 2019, 56, 234-240.
Google Scholar
[24]
Liu, R. T.; Lee, S. T.; Sun, B. Q. 13.8% efficiency hybrid Si/organic heterojunction solar cells with MoO3 film as antireflection and inversion induced layer. Adv. Mater. 2014, 26, 6007-6012.
Google Scholar
[25]
Luo, Q.; Deng, X. S.; Zhang, C. X.; Yu, M. D.; Zhou, X.; Wang, Z. B.; Chen, X. H.; Huang, S. M. Enhancing photovoltaic performance of perovskite solar cells with silica nanosphere antireflection coatings. Solar Energy 2018, 169, 128-135.
Google Scholar
[26]
Kim, M.; Kang, T. W.; Kim, S. H.; Jung, E. H.; Park, H. H.; Seo, J.; Lee, S. J. Antireflective, self-cleaning and protective film by continuous sputtering of a plasma polymer on inorganic multilayer for perovskite solar cells application. Solar Energy Mater. Solar Cells 2019, 191, 55-61.
Google Scholar
[27]
Schneider, B. W.; Lal, N. N.; Baker-Finch, S.; White, T. P. Pyramidal surface textures for light trapping and antireflection in perovskite-on-silicon tandem solar cells. Opt. Express 2014, 22, A1422-A1430.
Google Scholar
[28]
Kang, S. M.; Jang, S.; Lee, J. K.; Yoon, J.; Yoo, D. E.; Lee, J. W.; Choi, M.; Park, N. G. Moth-eye TiO2 layer for improving light harvesting efficiency in perovskite solar cells. Small 2016, 12, 2443-2449.
Google Scholar
[29]
Bernhard, C. G.; Gemne, G.; Sallström, J. Comparative ultrastructure of corneal surface topography in insects with aspects on phylogenesis and function. J. Comp. Physiol. A 1970, 67, 1-25.
Google Scholar
[30]
Choi, H. J.; Choo, S.; Shin, J. H.; Kim, K. I.; Lee, H. Fabrication of superhydrophobic and oleophobic surfaces with overhang structure by reverse nanoimprint lithography. J. Phys. Chem. C 2013, 117, 24354-24359.
Google Scholar
[31]
Clapham, P. B.; Hutley, M. C. Reduction of lens reflexion by the “moth eye” principle. Nature 1973, 244, 281-282.
Google Scholar
[32]
Hong, E. J.; Byeon, K. J.; Park, H.; Hwang, J.; Lee, H.; Choi, K.; Jung, G. Y. Fabrication of moth-eye structure on p-GaN layer of GaN-based LEDs for improvement of light extraction. Mater. Sci. Eng. B 2009, 163, 170-173.
Google Scholar
[33]
Haacke, G. New figure of merit for transparent conductors. J. Appl. Phys. 1976, 47, 4086-4089.
Google Scholar
[34]
Ghosh, D. S.; Chen, T. L.; Pruneri, V. High figure-of-merit ultrathin metal transparent electrodes incorporating a conductive grid. Appl. Phys. Lett. 2010, 96, 041109.
Google Scholar
[35]
Hwang, I.; Choi, D.; Lee, S.; hoon Seo, J. H.; Kim, K. H.; Yoon, I.; Seo, K. Enhancement of light absorption in photovoltaic devices using textured polydimethylsiloxane stickers. ACS Appl. Mater. Interfaces 2017, 9, 21276-21282.
Google Scholar
[36]
Dong, J.; Zhao, Y. H.; Shi, J. J.; Wei, H. Y.; Xiao, J. Y.; Xu, X.; Luo, J. H.; Xu, J.; Li, D. M.; Luo, Y. H.; Meng, Q. B. Impressive enhancement in the cell performance of ZnO nanorod-based perovskite solar cells with Al-doped ZnO interfacial modification. Chem. Commun. 2014, 50, 13381-13384.
Google Scholar
[37]
Zhou, Y. Y.; Kwun, J.; Garces, H. F.; Pang, S. P.; Padture, N. P. Observation of phase-retention behavior of the HC(NH2)2PbI3 black perovskite polymorph upon mesoporous TiO2 scaffolds. Chem. Commun. 2016, 52, 7273-7275.
Google Scholar
[38]
Zhang, X. Q.; Wu, G.; Fu, W. F.; Qin, M. C.; Yang, W. T.; Yan, J. L.; Zhang, Z. Q.; Lu, X. H.; Chen, H. Z. Orientation regulation of phenylethylammonium cation based 2D perovskite solar cell with efficiency higher than 11%. Adv. Energy Mater. 2018, 8, 1702498.
Google Scholar
Nano Research
Volume 13 Issue 4,
April 2020
Pages 1156-1161
DOI: 10.1007/s12274-020-2763-3
Cite this article:
Ju S, Byun M, Kim M, et al. Fabrication of perovskite solar cell with high short-circuit current density (JSC) using moth-eye structure of SiOX. Nano Research, 2020, 13(4): 1156-1161. https://doi.org/10.1007/s12274-020-2763-3
Topics:
Energy gapPerovskiteRefractive indexSilicon compounds

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Received: 18 November 2019
Revised: 11 February 2020
Accepted: 21 March 2020
Published: 07 April 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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