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Research Article

A robust soc-MOF platform exhibiting high gravimetric uptake and volumetric deliverable capacity for on-board methane storage

Gaurav Verma1, Sanjay Kumar1,†( ), Harsh Vardhan1, Junyu Ren1, Zheng Niu1, Tony Pham1,‡, Lukasz Wojtas1, Sydney Butikofer1,⊥, Jose C Echeverria Garcia1, Yu-Sheng Chen2, Brian Space1, Shengqian Ma1( )
Department of Chemistry, University of South Florida, 4202 E. Fowler Ave., Tampa, FL 33637, USA
ChemMatCARS, Center for Advanced Radiation Sources, The University of Chicago, 9700 South Cass Avenue, Argonne, IL 60439, USA

† Present address: Department of Chemistry, Multani Mal Modi College, Patiala 147001, India

‡ Present address: Department of Chemistry, Biochemistry, and Physics, The University of Tampa, 401 W. Kennedy Blvd., Tampa, FL 33606-1490, USA

⊥ Present address: Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Champaign, IL 61801, USA

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Graphical Abstract

Abstract

Emerging as an outperformed class of metal-organic frameworks (MOFs), square-octahedron (soc) topology MOFs (soc-MOFs) feature superior properties of high porosity, large gas storage capacity, and excellent thermal/chemical stability. We report here an iron based soc-MOF, denoted as Fe-pbpta (H4pbpta = 4,4',4'',4'''-(1,4-phenylenbis(pyridine-4,2-6-triyl))-tetrabenzoic acid) possessing a very high Brunauer, Emmett and Teller (BET) surface area of 4,937 m2/g and a large pore volume of 2.15 cm3/g. The MOF demonstrates by far the highest gravimetric uptake of 369 cm3(STP)/g under the DOE operational storage conditions (35 bar and 298 K) and a high volumetric deliverable capacity of 192 cc/cc at 298 K and 65 bar. Furthermore, Fe-pbpta exhibits high thermal and aqueous stability making it a promising candidate for on-board methane storage.

Keywords

metal-organic framework (MOF)reticular chemistrymethane storageaqueous stabilityhigh gravimetric and volumetric uptake

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Nano Research
Volume 14 Issue 2,
February 2021
Pages 512-517
DOI: 10.1007/s12274-020-2794-9
Cite this article:
Verma G, Kumar S, Vardhan H, et al. A robust soc-MOF platform exhibiting high gravimetric uptake and volumetric deliverable capacity for on-board methane storage. Nano Research, 2021, 14(2): 512-517. https://doi.org/10.1007/s12274-020-2794-9
Topics:
MetalsOrganic frameworks Organometallics

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Received: 01 February 2020
Revised: 24 March 2020
Accepted: 02 April 2020
Published: 24 April 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
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