AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
PDF (48.6 MB)
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript AI Chat Paper
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article | Open Access

Phase boundary engineering of metal-organic-framework-derived carbonaceous nickel selenides for sodium-ion batteries

Shiyao Lu1,4,§, Hu Wu1,§, Jingwei Hou2,7, Limin Liu1, Jiao Li1, Chris J. Harris2, Cheng-Yen Lao2, Yuzheng Guo5, Kai Xi2,3( ), Shujiang Ding1( ), Guoxin Gao1( ), Anthony K. Cheetham2,6, R. Vasant Kumar2
Xi'an Key Laboratory of Sustainable Energy Materials Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, State Key Laboratory of Electrical Insulation and Power Equipment, School of Chemistry, Xi’an Jiaotong University & Shaanxi Quantong Joint Research Institute of New Energy Vehicles Power, Xi’an Jiaotong University, Xi’an 710049, China
Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB3 0FS, UK
Cambridge Graphene Centre, Department of Engineering, University of Cambridge, Cambridge CB3 0FA, UK
Department of Chemistry, City University of Hong Kong, Hong Kong 999077, Hong Kong, China
School of Electrical Engineering and Automation, Wuhan University, Wuhan 430072, China
Materials Research Laboratory, University of California, Santa Barbara, CA 93106, USA
School of Chemical Engineering, University of Queensland, St Lucia, QLD 4072, Australia

§ Shiyao Lu and Hu Wu contributed equally to this work.

Show Author Information

Graphical Abstract

Abstract

Sodium-ion batteries (SIBs) are promising power sources due to the low cost and abundance of battery-grade sodium resources, while practical SIBs suffer from intrinsically sluggish diffusion kinetics and severe volume changes of electrode materials. Metal-organic framework (MOFs) derived carbonaceous metal compound offer promising applications in electrode materials due to their tailorable composition, nanostructure, chemical and physical properties. Here, we fabricated hierarchical MOF-derived carbonaceous nickel selenides with bi-phase composition for enhanced sodium storage capability. As MOF formation time increases, the pyrolyzed and selenized products gradually transform from a single-phase Ni3Se4 into bi-phase NiSex then single-phase NiSe2, with concomitant morphological evolution from solid spheres into hierarchical urchin-like yolk-shell structures. As SIBs anodes, bi-phase NiSex@C/CNT-10h (10 h of hydrothermal synthesis time) exhibits a high specific capacity of 387.1 mAh/g at 0.1 A/g, long cycling stability of 306.3 mAh/g at a moderately high current density of 1 A/g after 2,000 cycles. Computational simulation further proves the lattice mismatch at the phase boundary facilitates more interstitial space for sodium storage. Our understanding of the phase boundary engineering of transformed MOFs and their morphological evolution is conducive to fabricate novel composites/hybrids for applications in batteries, catalysis, sensors, and environmental remediation.

Keywords

metal organic frameworksphase boundarycarbon nanotubemetal selenidessodium ion batteries

Electronic Supplementary Material

Download File(s)
12274_2020_2848_MOESM1_ESM.pdf (5.5 MB)

References

[1]
Hwang, J. Y.; Myung, S. T.; Sun, Y. K. Sodium-ion batteries: Present and future. Chem. Soc. Rev. 2017, 46, 3529-3614.
Crossref Google Scholar
[2]
Kim, H.; Kim, H.; Ding, Z.; Lee, M. H.; Lim, K.; Yoon, G.; Kang, K. Recent progress in electrode materials for sodium-ion batteries. Adv. Energy Mater. 2016, 6, 1600943.
Crossref Google Scholar
[3]
Xie, F. X.; Zhang, L.; Ye, C.; Jaroniec, M.; Qiao, S. Z. The application of hollow structured anodes for sodium-ion batteries: From simple to complex systems. Adv. Mater. 2019, 31, 1800492.
Crossref Google Scholar
[4]
Liu, Y. Y.; Zhou, G. M.; Liu, K.; Cui, Y. Design of complex nanomaterials for energy storage: Past success and future opportunity. Acc. Chem. Res. 2017, 50, 2895-2905.
Crossref Google Scholar
[5]
Deng, J. Q.; Luo, W. B.; Chou, S. L.; Liu, H. K.; Dou, S. X. Sodium-ion batteries: From academic research to practical commercialization. Adv. Energy Mater. 2018, 8, 1701428.
Crossref Google Scholar
[6]
Chen, S. Q.; Wu, C.; Shen, L. F.; Zhu, C. B.; Huang, Y. Y.; Xi, K.; Maier, J.; Yu, Y. Challenges and perspectives for NASICON-type electrode materials for advanced sodium-ion batteries. Adv. Mater. 2017, 29, 1700431.
Crossref Google Scholar
[7]
Deng, J.; Gong, Q. F.; Ye, H. L.; Feng, K.; Zhou, J. H.; Zha, C. Y.; Wu, J. H.; Chen, J. M.; Zhong, J.; Li, Y. G. Rational synthesis and assembly of Ni3S4 nanorods for enhanced electrochemical sodium-ion storage. ACS Nano 2018, 12, 1829-1836.
Crossref Google Scholar
[8]
Zhou, L. M.; Zhang, K.; Sheng, J. Z.; An, Q. Y.; Tao, Z. L.; Kang, Y. M.; Chen, J.; Mai, L. Q. Structural and chemical synergistic effect of CoS nanoparticles and porous carbon nanorods for high-performance sodium storage. Nano Energy 2017, 35, 281-289.
Crossref Google Scholar
[9]
Liu, D. H.; Li, W. H.; Zheng, Y. P.; Cui, Z.; Yan, X.; Liu, D. S.; Wang, J. W.; Zhang, Y.; Lü, H. Y.; Bai, F. Y. et al. In situ encapsulating α-MnS into N,S-codoped nanotube-like carbon as advanced anode material: α→β phase transition promoted cycling stability and superior Li/Na-storage performance in half/full cells. Adv. Mater. 2018, 30, 1706317.
Crossref Google Scholar
[10]
Chao, D. L.; Ouyang, B.; Liang, P.; Huong, T. T. T.; Jia, G. C.; Huang, H.; Xia, X. H.; Rawat, R. S.; Fan, H. J. C-plasma of hierarchical graphene survives SnS bundles for ultrastable and high volumetric Na-Ion storage. Adv. Mater. 2018, 30, 1804833.
Crossref Google Scholar
[11]
Wang, Q. H.; Zhang, W. C.; Guo, C.; Liu, Y. J.; Wang, C.; Guo, Z. P. In Situ construction of 3D interconnected FeS@Fe3C@Graphitic carbon networks for high-performance sodium-ion batteries. Adv. Funct. Mater. 2017, 27, 1703390.
Google Scholar
[12]
Su, D. W.; Kretschmer, K.; Wang, G. X. Improved electrochemical performance of Na-Ion batteries in ether-based electrolytes: A case study of ZnS nanospheres. Adv. Energy Mater. 2016, 6, 1501785.
Google Scholar
[13]
Dong, S. H.; Li, C. X.; Ge, X. L.; Li, Z. Q.; Miao, X. G.; Yin, L. W. ZnS-Sb2S3@C core-double shell polyhedron structure derived from metal-organic framework as anodes for high performance sodium ion batteries. ACS Nano 2017, 11, 6474-6482.
Google Scholar
[14]
Hou, H. S.; Banks, C. E.; Jing, M. J.; Zhang, Y.; Ji, X. B. Carbon quantum dots and their derivative 3D porous carbon frameworks for sodium-ion batteries with ultralong cycle life. Adv. Mater. 2015, 27, 7861-7866.
Google Scholar
[15]
Hu, Z.; Liu, Q. N.; Chou, S. L.; Dou, S. X. Advances and challenges in metal sulfides/selenides for next-generation rechargeable sodium-ion batteries. Adv. Mater. 2017, 29, 1700606.
Google Scholar
[16]
Xi, K.; He, D. Q.; Harris, C.; Wang, Y. K.; Lai, C.; Li, H. L.; Coxon, P. R.; Ding, S. J.; Wang, C.; Kumar, R. V. Enhanced sulfur transformation by multifunctional FeS2/FeS/S composites for high-volumetric capacity cathodes in lithium-sulfur batteries. Adv. Sci. 2019, 6, 1800815.
Google Scholar
[17]
Xi, K.; Chen, B. A.; Li, H. L.; Xie, R. S.; Gao, C. L.; Zhang, C.; Kumar, R. V.; Robertson, J. Soluble polysulphide sorption using carbon nanotube forest for enhancing cycle performance in a lithium- sulphur battery. Nano Energy 2015, 12, 538-546.
Google Scholar
[18]
Hu, X.; Jia, J. C.; Wang, G. X.; Chen, J. X.; Zhan, H. B.; Wen, Z. H. Reliable and general route to inverse opal structured nanohybrids of carbon-confined transition metal sulfides quantum dots for high-performance sodium storage. Adv. Energy Mater. 2018, 8, 1801452.
Google Scholar
[19]
Ge, P.; Hou, H. S.; Li, S. J.; Yang, L.; Ji, X. B. Tailoring rod-like FeSe2 coated with nitrogen-doped carbon for high-performance sodium storage. Adv. Funct. Mater. 2018, 28, 1801765.
Google Scholar
[20]
Lu, S. Y.; Zhu, T. X.; Wu, H.; Wang, Y. K.; Li, J.; Abdelkader, A.; Xi, K.; Wang, W.; Li, Y. G.; Ding, S. J. et al. Construction of ultrafine ZnSe nanoparticles on/in amorphous carbon hollow nanospheres with high-power-density sodium storage. Nano Energy 2019, 59, 762-772.
Google Scholar
[21]
Wei, X. J.; Tang, C. J.; An, Q. Y.; Yan, M. Y.; Wang, X. P.; Hu, P.; Cai, X. Y.; Mai, L. Q. FeSe2 clusters with excellent cyclability and rate capability for sodium-ion batteries. Nano Res. 2017, 10, 3202-3211.
Google Scholar
[22]
Liu, H.; Guo, H.; Liu, B. H.; Liang, M. F.; Lv, Z. L.; Adair, K. R.; Sun, X. L. Few-layer MoSe2 nanosheets with expanded (002) planes confined in hollow carbon nanospheres for ultrahigh-performance Na-Ion batteries. Adv. Funct. Mater. 2018, 28, 1707480.
Google Scholar
[23]
Niu, F. E.; Yang, J.; Wang, N. N.; Zhang, D. P.; Fan, W. L.; Yang, J.; Qian, Y. T. MoSe2-covered N,P-doped carbon nanosheets as a long-life and high-rate anode material for sodium-ion batteries. Adv. Funct. Mater. 2017, 27, 1700522.
Google Scholar
[24]
Tang, C. J.; Wei, X. J.; Cai, X. Y.; An, Q. Y.; Hu, P.; Sheng, J. Z.; Zhu, J. X.; Chou, S. L.; Wu, L. M.; Mai, L. Q. ZnSe microsphere/multiwalled carbon nanotube composites as high-rate and long-life anodes for sodium-ion batteries. ACS Appl. Mater. Interfaces 2018, 10, 19626-19632.
Google Scholar
[25]
Yi, Y. Y.; Sun, Z. T.; Li, C.; Tian, Z. N.; Lu, C.; Shao, Y. L.; Li, J.; Sun, J. Y.; Liu, Z. F. Designing 3D biomorphic nitrogen-doped MoSe2/graphene composites toward high-performance potassium-ion capacitors. Adv. Funct. Mater. 2020, 30, 1903878.
Google Scholar
[26]
Xia, Z.; Sun, H.; He, X.; Sun, Z. T.; Lu, C.; Li, J.; Peng, Y.; Dou, S. X.; Sun, J. Y.; Liu, Z. F. In situ construction of CoSe2@vertical-oriented graphene arrays as self-supporting electrodes for sodium-ion capacitors and electrocatalytic oxygen evolution. Nano Energy 2019, 60, 385-393.
Google Scholar
[27]
Lu, C.; Li, Z. Z.; Xia, Z.; Ci, H. N.; Cai, J. S.; Song, Y. Z.; Yu, L. H.; Yin, W. J.; Dou, S. X.; Sun, J. Y. et al. Confining MOF-derived SnSe nanoplatelets in nitrogen-doped graphene cages via direct CVD for durable sodium ion storage. Nano Res. 2019, 12, 3051-3058.
Google Scholar
[28]
Li, Y.; Xu, Y. H.; Wang, Z. H.; Bai, Y.; Zhang, K.; Dong, R. Q.; Gao, Y. N.; Ni, Q.; Wu, F.; Liu, Y. J. et al. Stable carbon-selenium bonds for enhanced performance in Tremella-like 2D chalcogenide battery anode. Adv. Energy Mater. 2018, 8, 1800927.
Google Scholar
[29]
Zhang, Y. F.; Pan, A. Q.; Ding, L.; Zhou, Z. L.; Wang, Y. P.; Niu, S. Y.; Liang, S. Q.; Cao, G. Z. Nitrogen-doped yolk-shell-structured CoSe/C dodecahedra for high-performance sodium ion batteries. ACS Appl. Mater. Interfaces 2017, 9, 3624-3633.
Google Scholar
[30]
Wu, C.; Jiang, Y.; Kopold, P.; van Aken, P. A.; Maier, J.; Yu, Y. Peapod-like carbon-encapsulated cobalt chalcogenide nanowires as cycle-stable and high-rate materials for sodium-ion anodes. Adv. Mater. 2016, 28, 7276-7283.
Google Scholar
[31]
Chen, Y. Y.; Ji, S. F.; Zhao, S.; Chen, W. X.; Dong, J. C.; Cheong, W. C.; Shen, R. A.; Wen, X. D.; Zheng, L. R.; Rykov, A. I. et al. Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell. Nat. Commun. 2018, 9, 5422.
Google Scholar
[32]
Jagadeesh, R. V.; Murugesan, K.; Alshammari, A. S.; Neumann, H.; Pohl, M. M.; Radnik, J.; Beller, M. MOF-derived cobalt nanoparticles catalyze a general synthesis of amines. Science 2017, 358, 326-332.
Google Scholar
[33]
Sun, L. M.; Li, R.; Zhan, W. W.; Yuan, Y. S.; Wang, X. J.; Han, X. G.; Zhao, Y. L. Double-shelled hollow rods assembled from nitrogen/sulfur-codoped carbon coated indium oxide nanoparticles as excellent photocatalysts. Nat. Commun. 2019, 10, 2270.
Google Scholar
[34]
Du, M.; Song, D.; Huang, A. M.; Chen, R. X.; Jin, D. Q.; Rui, K.; Zhang, C.; Zhu, J. X.; Huang, W. Stereoselectively assembled Metal-Organic Framework (MOF) host for catalytic synthesis of carbon hybrids for alkaline-metal-ion batteries. Angew. Chem., Int. Ed. 2019, 58, 5307-5311.
Google Scholar
[35]
Wang, S. Z.; McGuirk, C. M.; d'Aquino, A.; Mason, J. A.; Mirkin, C. A. Metal-organic framework nanoparticles. Adv. Mater. 2018, 30, 1800202.
Google Scholar
[36]
Guan, B. Y.; Yu, X. Y.; Wu, H. B.; Lou, X. W. Complex nanostructures from materials based on metal-organic frameworks for electrochemical energy storage and conversion. Adv. Mater. 2017, 29, 1703614.
Google Scholar
[37]
Kaneti, Y. V.; Tang, J.; Salunkhe, R. R.; Jiang, X. C.; Yu, A. B.; Wu, K. C. W.; Yamauchi, Y. Nanoarchitectured design of porous materials and nanocomposites from metal-organic frameworks. Adv. Mater. 2017, 29, 1604898.
Google Scholar
[38]
Park, S. K.; Kim, J. K.; Chan Kang, Y. Metal-organic framework-derived CoSe2/(NiCo)Se2 box-in-box hollow nanocubes with enhanced electrochemical properties for sodium-ion storage and hydrogen evolution. J. Mater. Chem. A 2017, 5, 18823-18830.
Google Scholar
[39]
Xi, K.; Cao, S.; Peng, X. Y.; Ducati, C.; Kumar, R. V.; Cheetham, A. K. Carbon with hierarchical pores from carbonized metal-organic frameworks for lithium sulphur batteries. Chem. Commun. 2013, 49, 2192-2194.
Google Scholar
[40]
Chen, R. J.; Zhao, T.; Tian, T.; Cao, S.; Coxon, P. R.; Xi, K.; Fairen-Jimenez, D.; Kumar, R. V.; Cheetham, A. K. Graphene-wrapped sulfur/metal organic framework-derived microporous carbon composite for lithium sulfur batteries. APL Mater. 2014, 2, 124109.
Google Scholar
[41]
Tang, Y. C.; Zhao, Z. B.; Hao, X. J.; Wang, Y. W.; Liu, Y.; Hou, Y. N.; Yang, Q.; Wang, X. Z; Qiu, J. S. Engineering hollow polyhedrons structured from carbon-coated CoSe2 nanospheres bridged by CNTs with boosted sodium storage performance. J. Mater. Chem. A 2017, 5, 13591-13600.
Google Scholar
[42]
Zhang, J.; Wan, J. W.; Wang, J. Y.; Ren, H.; Yu, R. B.; Gu, L.; Liu, Y. L.; Feng, S. H.; Wang, D. Hollow multi-shelled structure with metal-organic-framework-derived coatings for enhanced lithium storage. Angew. Chem., Int. Ed. 2019, 58, 5266-5271.
Google Scholar
[43]
Xu, X. J.; Liu, J.; Liu, J. W.; Ouyang, L. Z.; Hu, R. Z.; Wang, H.; Yang, L. C.; Zhu, M. A general Metal-Organic Framework (MOF)-derived selenidation strategy for in situ carbon-encapsulated metal selenides as high-rate anodes for Na-Ion batteries. Adv. Funct. Mater. 2018, 28, 1707573.
Google Scholar
[44]
Zou, F.; Chen, Y. M.; Liu, K. W.; Yu, Z. T.; Liang, W. F.; Bhaway, S. M.; Gao, M.; Zhu, Y. Metal organic frameworks derived hierarchical hollow NiO/Ni/Graphene composites for lithium and sodium storage. ACS Nano 2016, 10, 377-386.
Google Scholar
[45]
Guan, B. Y.; Yu, L.; Lou, X. W. A dual-metal-organic-framework derived electrocatalyst for oxygen reduction. Energy Environ. Sci. 2016, 9, 3092-3096.
Google Scholar
[46]
Meng, J. S.; Niu, C. J.; Xu, L. H.; Li, J. T.; Liu, X.; Wang, X. P.; Wu, Y. Z.; Xu, X. M.; Chen, W. Y.; Li, Q. et al. General oriented formation of carbon nanotubes from metal-organic frameworks. J. Am. Chem. Soc. 2017, 139, 8212-8221.
Google Scholar
[47]
Park, S. K.; Kim, J. K.; Kang, Y. C. Excellent sodium-ion storage performances of CoSe2 nanoparticles embedded within N-doped porous graphitic carbon nanocube/carbon nanotube composite. Chem. Eng. J. 2017, 328, 546-555.
Google Scholar
[48]
Kong, S. F.; Dai, R. L.; Li, H.; Sun, W. W.; Wang, Y. Microwave hydrothermal synthesis of Ni-based metal-organic frameworks and their derived yolk-shell NiO for Li-Ion storage and supported ammonia borane for hydrogen desorption. ACS Sustainable Chem. Eng. 2015, 3, 1830-1838.
Google Scholar
[49]
Ou, X.; Li, J.; Zheng, F. H.; Wu, P.; Pan, Q. C.; Xiong, X. H.; Yang, C. H.; Liu, M. L. In situ X-ray diffraction characterization of NiSe2 as a promising anode material for sodium ion batteries. J. Power Sources 2017, 343, 483-491.
Google Scholar
[50]
Zhu, S. H.; Li, Q. D.; Wei, Q. L.; Sun, R. M.; Liu, X. Q.; An, Q. Y.; Mai, L. Q. NiSe2 nanooctahedra as an anode material for high-rate and long-life sodium-ion battery. ACS Appl. Mater. Interfaces 2017, 9, 311-316.
Google Scholar
[51]
Lu, S. Y; Zhu, T. X.; Li, Z. Y.; Pang, Y. C.; Shi, L.; Ding, S. J.; Gao, G. X. Ordered mesoporous carbon supported Ni3V2O8 composites for lithium-ion batteries with long-term and high-rate performance. J. Mater. Chem. A 2018, 6, 7005-7013.
Google Scholar
[52]
Zhu, G. Y.; Chen, T.; Wang, L.; Ma, L. B.; Hu, Y.; Chen, R. P.; Wang, Y. R.; Wang, C. X.; Yan, W.; Tie, Z. X. et al. High energy density hybrid lithium-ion capacitor enabled by Co3ZnC@N-doped carbon nanopolyhedra anode and microporous carbon cathode. Energy Storage Mater. 2018, 14, 246-252.
Google Scholar
[53]
Zhao, W. X.; Guo, C. X.; Li, C. M. Lychee-like FeS2@FeSe2 core- shell microspheres anode in sodium ion batteries for large capacity and ultralong cycle life. J. Mater. Chem. A 2017, 5, 19195-19202.
Google Scholar
[54]
Fang, G. Z.; Wu, Z. X.; Zhou, J.; Zhu, C. Y.; Cao, X. X.; Lin, T. Q.; Chen, Y. M.; Wang, C.; Pan, A. Q.; Liang, S. Q. Observation of pseudocapacitive effect and fast ion diffusion in bimetallic sulfides as an advanced sodium-ion battery Anode. Adv. Energy Mater. 2018, 8, 1703155.
Google Scholar
[55]
Fang, Y. J.; Yu, X. Y.; Lou, X. W. Formation of hierarchical Cu-doped CoSe2 microboxes via sequential ion exchange for high-performance sodium-ion batteries. Adv. Mater. 2018, 30, 1706668.
Google Scholar
[56]
Liu, S. T.; Li, D.; Zhang, G. J.; Sun, D. D.; Zhou, J. S.; Song, H. H. Two-dimensional NiSe2/N-Rich carbon nanocomposites derived from Ni-hexamine frameworks for superb Na-Ion storage. ACS Appl. Mater. Interfaces 2018, 10, 34193-34201.
Google Scholar
Nano Research
Volume 13 Issue 8,
August 2020
Pages 2289-2298
DOI: 10.1007/s12274-020-2848-z
Cite this article:
Lu S, Wu H, Hou J, et al. Phase boundary engineering of metal-organic-framework-derived carbonaceous nickel selenides for sodium-ion batteries. Nano Research, 2020, 13(8): 2289-2298. https://doi.org/10.1007/s12274-020-2848-z
Topics:
AnodesLattice mismatch Metal ionsMetalsNickel compoundsOrganic frameworks OrganometallicsSelenium compounds

798

Views

36

Downloads

58

Crossref

N/A

Web of Science

61

Scopus

1

CSCD

Altmetrics
Received: 16 March 2020
Revised: 23 April 2020
Accepted: 30 April 2020
Published: 05 August 2020
© The Author(s) 2020

This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made.

The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.

To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
Return