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Research Article

Interfacial engineering of Ni/V2O3 for hydrogen evolution reaction

Yang Chen1,§, Yuan Rao1,§, Rongzhi Wang1, Yanan Yu1, Qiulin Li2, Shujuan Bao2, Maowen Xu2, Qin Yue1, Yanning Zhang1(), Yijin Kang1()
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Key Laboratory of Luminescent and Real-Time Analytical Chemistry, Ministry of Education, Institute for Clean Energy and Advanced Materials, Faculty of Materials and Energy, Southwest University, Chongqing 400715, China

§ Yang Chen and Yuan Rao contributed equally to this work.

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Abstract

Electrocatalytic water splitting offers a sustainable route for hydrogen production, enabling the clean and renewable alternative energy system of hydrogen economy. The scarcity and high-cost of platinum-group-metal (PGM) materials urge the exploration of high-performance non-PGM electrocatalysts. Herein, a unique hierarchical structure of Ni/V2O3 with extraordinary electrocatalytic performance (e.g., overpotentials as low as 22 mV at 20 mA·cm-2 and 94 mV at 100 mA·cm-2) toward hydrogen evolution reaction in alkaline electrolyte (1 M KOH) is reported. The investigation on the hierarchical Ni/V2O3 with a bimodal size-distribution also offers insight of interfacial engineering that only proper Ni/V2O3 interface can effectively improve H2O adsorption, H2O dissociation as well as H adsorption, for an efficient hydrogen production.

Keywords

hydrogen evolution reactionhierarchical materialsinterfaceelectrocatalysisvanadium oxide

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Nano Research
Volume 13 Issue 9,
September 2020
Pages 2407-2412
DOI: 10.1007/s12274-020-2865-y
Cite this article:
Chen Y, Rao Y, Wang R, et al. Interfacial engineering of Ni/V2O3 for hydrogen evolution reaction. Nano Research, 2020, 13(9): 2407-2412. https://doi.org/10.1007/s12274-020-2865-y
Topics:
ElectrocatalystsElectrolytesHydrogen economyHydrogen evolution reaction Nickel compoundsPotassium hydroxide
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