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Research Article

Accelerated oxygen reduction on Fe/N/C catalysts derived from precisely-designed ZIF precursors

Ergui Luo1,2, Chen Wang1, Yang Li1,2, Xian Wang1,2, Liyuan Gong1,2, Tuo Zhao1,2, Zhao Jin1, Junjie Ge1,2( ), Changpeng Liu1,2( ), Wei Xing1,2,3( )
Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
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Abstract

Fe/N/C material is the most competitive alternative to precious-metal catalysts for oxygen reduction. In view of the present consensus on active centers, further effort is directed at maximizing the density of single Fe atoms. Here, the imperfections in commonly used doping strategy of Fe for the synthesis of zeolitic imidazolateframework (ZIF)-derived Fe/N/C catalysts are revealed. More importantly, a strikingly improved catalyst is obtained by a 'second pyrolysis’ method and delivers a half-wave potential of 0.825 V (vs. RHE) in acidic media. The strong confinement effect of carbonaceous host accounts for the formation of dense single-atom sites and thus the high activity. Our findings will potentially facilitate future improvement of M/N/C catalysts.

Keywords

fuel cellsoxygen reductionelectrocatalysissingle-atom catalystsFe/N/C

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Nano Research
Volume 13 Issue 9,
September 2020
Pages 2420-2426
DOI: 10.1007/s12274-020-2868-8
Cite this article:
Luo E, Wang C, Li Y, et al. Accelerated oxygen reduction on Fe/N/C catalysts derived from precisely-designed ZIF precursors. Nano Research, 2020, 13(9): 2420-2426. https://doi.org/10.1007/s12274-020-2868-8
Topics:
Electrolytic reduction Oxygen

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Received: 11 January 2020
Revised: 20 April 2020
Accepted: 10 May 2020
Published: 16 June 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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