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Research Article

Surface-ligand protected reduction on plasmonic tuning of one- dimensional MoO3-x nanobelts for solar steam generation

Xindian Li, Dongyang Wang, Yun Zhang, Luntao Liu, Wenshou Wang( )
National Engineering Research Center for Colloidal Materials and School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
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Abstract

Sub-stoichiometric MoO3-x nanostructures with plasmonic absorption via creating oxygen vacancies have attracted extensive attentions for many intriguing applications. However, the synthesis of one-dimensional (1D) plasmonic MoO3-x nanostructures with widely tunable plasmonic absorption has remained a significant challenge because of their serious morphological destruction and phase change with increasing the concentration of oxygen vacancies. Here we demonstrate a surface-ligand protected reduction strategy for the synthesis of 1D MoO3-x nanobelts with tunable plasmonic absorption in a wide wavelength range from 200 to 2,500 nm. Polyethylene glycol (PEG-400) is used as both the reductant to produce oxygen vacancies and the surface protected ligands to maintain 1D morphology during the formation process of MoO3-x nanobelts, enabling the widely tunable plasmonic absorption. Owing to their broad plasmonic absorption and unique 1D nanostructure, we further demonstrate the application of 1D MoO3-x nanobelts as photothermal film for interfacial solar evaporator. The surface-ligand protected reduction strategy provides a new avenue for the developing plasmonic semiconductor oxides with maintained particle morphology and thus enriching their wide applications.

Keywords

MoO3-x nanobeltssurface-ligand protected reductionoxygen vacanciesplasmonic tuninginterfacial water evaporation

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Nano Research
Volume 13 Issue 11,
November 2020
Pages 3025-3032
DOI: 10.1007/s12274-020-2967-6
Cite this article:
Li X, Wang D, Zhang Y, et al. Surface-ligand protected reduction on plasmonic tuning of one- dimensional MoO3-x nanobelts for solar steam generation. Nano Research, 2020, 13(11): 3025-3032. https://doi.org/10.1007/s12274-020-2967-6
Topics:
Ligands Molybdenum oxideMorphologyNanobelts Plasmonics

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Received: 14 May 2020
Revised: 28 June 2020
Accepted: 30 June 2020
Published: 04 August 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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