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Research Article

Controlling N-doping type in carbon to boost single-atom site Cu catalyzed transfer hydrogenation of quinoline

Jian Zhang1,§, Caiyan Zheng2,§, Maolin Zhang3, Yajun Qiu1, Qi Xu1, Weng-Chon Cheong4, Wenxing Chen5, Lirong Zheng6, Lin Gu7, Zhengpeng Hu2, Dingsheng Wang1( ), Yadong Li1( )
Department of Chemistry, Tsinghua University, Beijing 100084, China
School of Physics, Nankai University, Tianjin 300071, China
KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
Department of Physics and Chemistry, Faculty of Science and Technology, University of Macau, Taipa, Macau SAR, China
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

§ Jian Zhang and Caiyan Zheng contributed equally to this work.

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Graphical Abstract

Abstract

Single-atom site (SA) catalysts on N-doped carbon (CN) materials exhibit prominent performance for their active sites being M-Nx. Due to the commonly random doping behaviors of N species in these CN, it is a tough issue to finely regulate their doping types and clarify their effect on the catalytic property of such catalysts. Herein, we report that the N-doping type in CN can be dominated as pyrrolic-N and pyridinic-N respectively through compounding with different metal oxides. It is found that the proportion of distinct doped N species in CN depends on the acidity and basicity of compounded metal oxide host. Owing to the coordination by pyrrolic-N, the SA Cu catalyst displays an enhanced activity (two-fold) for transfer hydrogenation of quinoline to access the valuable molecule tetrahydroquinoline with a good selectivity (99%) under mild conditions. The higher electron density of SA Cu species induced by the predominate pyrrolic-N coordination benefits the hydrogen transfer process and reduces the energy barrier of the hydrogenation pathway, which accounts for the improved catalytic effeciency.

Keywords

nitrogen-doping typemetal oxidenitrogen-doped carbonsingle-atom site catalysttransfer hydrogenation

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Nano Research
Volume 13 Issue 11,
November 2020
Pages 3082-3087
DOI: 10.1007/s12274-020-2977-4
Cite this article:
Zhang J, Zheng C, Zhang M, et al. Controlling N-doping type in carbon to boost single-atom site Cu catalyzed transfer hydrogenation of quinoline. Nano Research, 2020, 13(11): 3082-3087. https://doi.org/10.1007/s12274-020-2977-4
Topics:
CarbonCatalyst activityCatalyst selectivity CopperDoping (additives)Hydrogenation
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Received: 03 July 2020
Revised: 06 July 2020
Accepted: 08 July 2020
Published: 20 July 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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