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Research Article

Inorganic/polymer hybrid layer stabilizing anode/electrolyte interfaces in solid-state Li metal batteries

Yiran Hu1,2, Yiren Zhong2, Limin Qi1( ), Hailiang Wang2( )
Beijing National Laboratory for Molecular Sciences (BNLMS), College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
Department of Chemistry and Energy Sciences Institute, Yale University, West Haven, CT 06516, USA
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Abstract

Li1.5Al0.5Ge1.5(PO4)3 (LAGP) is a solid-state electrolyte with high ionic conductivity and air stability but poor chemical stability and high interfacial impedance when directly contacted with Li metal. In this work, we develop an inorganic/polymer hybrid interlayer composed of Li bis(trifluoromethylsulfonyl)imide/poly(vinylene carbonate) polymer electrolyte and SiO2 submicrospheres to stabilize the Li/LAGP interface. The polymeric component renders high ionic conductance and low interfacial resistance, whereas the inorganic component imparts flame retardancy and a physical barrier to the known Li-LAGP side reaction, together enabling stable Li stripping/plating for more than 1,500 h at room temperature. With this interlayer at both electrodes, all-solid-state Li||LiFePO4 full cells with stable cycling performance are also demonstrated.

Keywords

Li1.5Al0.5Ge1.5(PO4)3 (LAGP)hybrid interlayersolid-state electrolyteLi metal batteryinterface

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Nano Research
Volume 13 Issue 12,
December 2020
Pages 3230-3234
DOI: 10.1007/s12274-020-2993-4
Cite this article:
Hu Y, Zhong Y, Qi L, et al. Inorganic/polymer hybrid layer stabilizing anode/electrolyte interfaces in solid-state Li metal batteries. Nano Research, 2020, 13(12): 3230-3234. https://doi.org/10.1007/s12274-020-2993-4
Topics:
Aluminum compoundsElectrodesGermanium compoundsLithiumLithium compoundsSilicaState Batteries

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Received: 02 June 2020
Revised: 17 July 2020
Accepted: 19 July 2020
Published: 25 August 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
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