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Research Article

Spider web-like carbonized bacterial cellulose/MoSe2 nanocomposite with enhanced microwave attenuation performance and tunable absorption bands

Zhengjian Xu1,2, Man He1( ), Yuming Zhou1( ), Shuangxi Nie2, Yongjuan Wang1, Yao Huo1, Yifan Kang1, Ruili Wang1, Ran Xu1, Hao Peng1, Xi Chen1
Jiangsu Optoelectronic Functional Materials and Engineering Laboratory, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China
Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, China
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Graphical Abstract

Abstract

It is essential to manufacture microwave absorbers with strong absorption as well as tunable absorption bands at a low filler content. However, it remains challenging for pure biomass material to reach this goal without loading other components. MoSe2, as a transition metal chalcogenide with semiconductor properties, has emerged as a potential microwave absorber filler. Herein, bacterial cellulose (BC)-derived carbon nanofibers/MoSe2 nanocomposite was fabricated and phosphoric acid was used to dope phosphorus in BC, in which MoSe2 microspheres were dropped on the BC network like a dew-covered spider web. This unique network structure enhances conductive loss and multiple reflections of the incident wave. The collocation of BC and MoSe2 is helpful to impedance match and introduces interfacial/dipolar polarization loss; moreover, the P-doping of BC helps to tune the absorption bands. Overall, the optimal reflection loss of undoped one reaches −53.33 dB with only 20 wt.% filler content, whose main absorption peaks focus on X-band. Interestingly, after the P-doping of BC, the main absorption peaks move to Ku-band and the optimal reflection loss gets stronger (−66.84 dB) with the same filler loading. Strong absorption and tunable absorption bands can be realized, and thus wide frequency range is covered. This work is expected to enlighten future exploration of biomass carbon materials on high-performance microwave absorption materials.

Keywords

bacterial celluloseMoSe2network structureP-doped carbontunable absorption band

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Nano Research
Volume 14 Issue 3,
March 2021
Pages 738-746
DOI: 10.1007/s12274-020-3107-z
Cite this article:
Xu Z, He M, Zhou Y, et al. Spider web-like carbonized bacterial cellulose/MoSe2 nanocomposite with enhanced microwave attenuation performance and tunable absorption bands. Nano Research, 2021, 14(3): 738-746. https://doi.org/10.1007/s12274-020-3107-z
Topics:
Carbon nanotubesNanocompositesSelenium compoundsSemiconductor dopingTransition metals

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Received: 23 June 2020
Revised: 07 September 2020
Accepted: 09 September 2020
Published: 01 March 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
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