Engineering electrochemical actuators with large bending strain based on 3D-structure titanium carbide MXene composites

Tong Wang; Tianjiao Wang; Chuanxin Weng; Luqi Liu; Jun Zhao; Zhong Zhang

doi:10.1007/s12274-020-3222-x

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Research Article

Engineering electrochemical actuators with large bending strain based on 3D-structure titanium carbide MXene composites

Tong Wang^{¹^,²}, Tianjiao Wang^{¹^,²}, Chuanxin Weng^¹, Luqi Liu^¹, Jun Zhao^{¹^,²}(

), Zhong Zhang^{¹^,²}(

)

1 CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China

2 University of Chinese Academy of Science, Beijing 100049, China

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Graphical Abstract

Abstract

Electrically responsive electrochemical actuators that contain a polymer electrolyte membrane laminated between two electrodes have attracted great attention due to their potential applications in smart electronics, wearable devices, and soft robotics. However, some challenges such as the achievement of large bending strain under low applied voltage and fast ion diffusion and accumulation still exist to be resolved. The key to the solution lies in the choice of electrode materials and the design of electrode structures. In this study, an engineering electrochemical actuator that presents large bending strain under low applied voltage based on MXene/polystyrene-MXene hybrid electrodes is developed. The developed electrochemical actuator based on the MXene/polystyrene-MXene 3D-structure is found to exhibit large bending strain (ca. 1.18%), broad frequency bandwidth, good durability (90% retention after 10,000 cycles) and considerable Young’s modulus (ca. 246 MPa). The high-performance actuation mainly stems from the excellent properties of MXene and 3D-structure of the electrode. The MXene provides excellent mechanical strength and high electrical conductivity which facilitate strong interaction and rapid electron transfer in electrodes. The 3D architectures formed by polystyrene microspheres generate unimpeded ion pathways for ionic short diffusion and fast injection. This study reveals that the 3D-structure hybrid electrodes play a crucial role in promoting the performance of such electrochemical actuators.

Keywords

electrochemistry actuators MXene composite materials

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Nano Research

Volume 14 Issue 7,
July 2021

Pages 2277-2284

DOI: 10.1007/s12274-020-3222-x

Cite this article:

Wang T, Wang T, Weng C, et al. Engineering electrochemical actuators with large bending strain based on 3D-structure titanium carbide MXene composites. Nano Research, 2021, 14(7): 2277-2284. https://doi.org/10.1007/s12274-020-3222-x

Topics:

Electron devices Polymer membrane electrodes

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Received: 06 August 2020

Revised: 09 October 2020

Accepted: 03 November 2020

Published: 05 July 2021