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Review Article

Two-dimensional MoS2 for hydrogen evolution reaction catalysis: The electronic structure regulation

Shuwen Niu§, Jinyan Cai§, Gongming Wang( )
Hefei National Laboratory for Physical Science at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

§ Shuwen Niu and Jinyan Cai contributed equally to this work.

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Graphical Abstract

Abstract

Molybdenum disulfide (MoS2) has been recognized as one of the most promising candidates to replace precious Pt for hydrogen evolution reaction (HER) catalysis, due to the natural abundance, low cost, tunable electronic properties, and excellent chemical stability. Although notable processes have been achieved in the past decades, their performance is still far less than that of Pt. Searching effective strategies to boosting their HER performance is still the primary goal. In this review, the recent process of the electronic regulation of MoS2 for HER is summarized, including band structure engineering, electronic state modulation, orbital orientation regulation, interface engineering. Last, the key challenges and opportunities in the development of MoS2-based materials for electrochemical HER are also discussed.

Keywords

hydrogen evolution reaction (HER)electronic structure modulationmolybdenum disulfidedensity functional theoryphase and interfacial engineering

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Nano Research
Volume 14 Issue 6,
June 2021
Pages 1985-2002
DOI: 10.1007/s12274-020-3249-z
Cite this article:
Niu S, Cai J, Wang G. Two-dimensional MoS2 for hydrogen evolution reaction catalysis: The electronic structure regulation. Nano Research, 2021, 14(6): 1985-2002. https://doi.org/10.1007/s12274-020-3249-z
Topics:
Catalysis Electronic propertiesElectronic structureHydrogenLayered semiconductorsMolybdenum compoundsSulfur compounds
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NR45 Awards in 2D Materials, 2021

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Received: 04 October 2020
Revised: 10 November 2020
Accepted: 16 November 2020
Published: 04 December 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
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