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Research Article

Suppressing the surface passivation of Pt-Mo nanowires via constructing Mo-Se coordination for boosting HER performance

Lei Yu1, Tingting Zhou1, Shuhua Cao1, Xishi Tai1, Lili Liu1, Yao Wang2( )
School of Chemistry & Chemical Engineering and Environmental Engineering, Weifang University, Weifang 261061, China
Department of Chemistry, Tsinghua University, Beijing 100084, China
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Abstract

Modulating the surface coordination environment of Pt based nanocrystals at the atomic level is of great importance to obtain good electrocatalytic performance. Given the fundamental understandings of surface structure degeneration of Pt based nanocrystals, introducing a weak electronegative element to the surface of Pt-based catalysts is beneficial for suppressing surface passivation and improving hydrogen evolution reaction performance of Pt. Density functional theory results reveal that the energy barrier of water dissociation process can be greatly reduced by using Se element as the surface modifier to replace the O. This hypothesis is further validated by experiments that ultralong Pt85Mo15-Se nanowires were fabricated to suppress the excessive passivation behavior of transition metals of Pt based alloy. The Pt85Mo15-Se nanowires exhibit higher activity with 4.98 times the specific activity and 4.87 times the mass activity of commercial Pt/C, as well as a better stability towards alkaline hydrogen evolution reaction. The deep exploration of X-ray photoelectron spectroscopy and theoretical calculations disclose that Se element could maintain the electron-rich state around the electronic orbit of Pt. This study provides a new insight to advance the fundamental understanding on electrocatalytic materials, which exhibits a promising approach to protect the surface chemical environment of Pt based nanocrystals.

Keywords

Pt based alloyshydrogen evolution reactionelectron effectinterfacial synergywater dissociation

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Nano Research
Volume 14 Issue 8,
August 2021
Pages 2659-2665
DOI: 10.1007/s12274-020-3269-8
Cite this article:
Yu L, Zhou T, Cao S, et al. Suppressing the surface passivation of Pt-Mo nanowires via constructing Mo-Se coordination for boosting HER performance. Nano Research, 2021, 14(8): 2659-2665. https://doi.org/10.1007/s12274-020-3269-8
Topics:
Binary alloysDensity functional theoryHydrogenHydrogen evolution reaction NanocrystalsNanowiresPlatinum metalsSeleniumSurface structureTransition metalsX-ray photoelectron spectroscopy

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Received: 07 September 2020
Revised: 19 October 2020
Accepted: 29 October 2020
Published: 28 December 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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