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Research Article

Robust perfluorinated porous organic networks: Succinct synthetic strategy and application in chlorofluorocarbons adsorption

Yali Luo1, Zhenzhen Yang3( ), Xian Suo2, Hao Chen2, Tao Wang2, Ziqian Wang1, Yunfei Liu1, Yinong Lyu1, Ilja Popovs3, Sheng Dai2,3( )
College of Materials Science and Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Nanjing Tech University, Nanjing 211816, China
Department of Chemistry, The University of Tennessee, Knoxville, TN 37996, USA
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA
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Abstract

Fluorinated porous organic networks (F-PONs) have demonstrated unique properties and applications, but approaches capable of affording F-PONs with high fluorine content and robust nanoporous architecture under metal-free and easy handling conditions are still rarely reported. Herein, using polydivinylbenzene (PDVB) as an easily available precursor, a novel and straightforward approach was developed to afford F-PONs via a dehydrative Friedel-Crafts reaction using perfluorinated benzylic alcohols as the cross-linking agent promoted by Brønsted acid (trifluoromethanesulfonic acid). The afforded material (F-PDVB) featured high fluorine content (22 at.%), large surface area (771 m2·g-1), and good chemical/thermal stability, rendering them as promising candidates for the adsorption of CO2, hydrocarbons, fluorocarbons, and chlorofluorocarbons, with weight capacities up to 520 wt.% being achieved. This simple methodology can be extended to fabricate fluorinated hyper-crosslinked polymers (F-HCPs) from rigid aromatic monomers. The progress made in this work will open new opportunities to further expand the involvement of fluorinated materials in large scale applications.

Keywords

fluorinatedporous organic networksFriedel-Crafts reactionhyper-crosslinked polymerschlorofluorocarbons

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Nano Research
Volume 14 Issue 9,
September 2021
Pages 3282-3287
DOI: 10.1007/s12274-021-3339-6
Cite this article:
Luo Y, Yang Z, Suo X, et al. Robust perfluorinated porous organic networks: Succinct synthetic strategy and application in chlorofluorocarbons adsorption. Nano Research, 2021, 14(9): 3282-3287. https://doi.org/10.1007/s12274-021-3339-6
Topics:
Microporosity Organic polymersSynthesis (chemical)
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Seventh Nano Research Award

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Received: 25 November 2020
Revised: 11 January 2021
Accepted: 18 January 2021
Published: 06 February 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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