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Research Article

The achievement of red upconversion lasing for highly stable perovskite nanocrystal glasses with the assistance of anion modulation

Mengfeifei Jin1,§, Wei Gao3,§, Xiaojuan Liang1, Ying Fang1, Siufung Yu3,4, Ting Wang2,3( ), Weidong Xiang1( )
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
College of Materials and Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China
Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong 999999, China
The Hong Kong Polytechnic University Shenzhen Research Institute, Shenzhen 518052, China

§ Mengfeifei Jin and Wei Gao contributed equally to this work.

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Graphical Abstract

Abstract

Perovskite materials have received extensive attention as optical gain media. However, it is tough to realize lasing using such materials on account of the unstable structure of MAPbI3/CsPbI3 nanocrystals (NCs), and the propensity for mixed-halogen perovskites to undergo phase decomposition into bromine-rich and iodide-rich regions under intense laser irradiation. To solve this issue, we fabricated CsPbX3 (X = Br, I) NCs, which were embedded into a glassy matrix with high stability. In addition, by doping Br- ions into the CsPbI3 NCs to partially replace I- ions, the optical efficiency and the optical gain properties were found to be significantly improved. Here, under 800 nm pulse laser excitation, red random lasing was realized with the assistance of such anion modulation. Moreover, we demonstrate that the perovskite NCs glasses (PNG) show strong water stability after immersion in water for one week, seeding a promise for application in high-definition (HD) displays and photonic devices.

Keywords

nanocrystals glassperovskiterandom lasingred-emitting

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Nano Research
Volume 14 Issue 8,
August 2021
Pages 2861-2866
DOI: 10.1007/s12274-021-3364-5
Cite this article:
Jin M, Gao W, Liang X, et al. The achievement of red upconversion lasing for highly stable perovskite nanocrystal glasses with the assistance of anion modulation. Nano Research, 2021, 14(8): 2861-2866. https://doi.org/10.1007/s12274-021-3364-5
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Received: 02 September 2020
Revised: 24 January 2021
Accepted: 25 January 2021
Published: 28 February 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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