AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

Silica-coating-assisted nitridation of TiO2 nanoparticles and their photothermal property

Qilin Wei1, Danielle L. Kuhn2, Zachary Zander2, Brendan G. DeLacy2, Hai-Lung Dai1( ), Yugang Sun1( )
Department of Chemistry, Temple University, 1901 North 13th Street, Philadelphia, Pennsylvania 19122, USA
U.S. Army Edgewood Chemical Biological Center, Research & Technology Directorate, Aberdeen Proving Ground, Maryland 21010, USA
Show Author Information

Graphical Abstract

Abstract

Nanoparticles of refractory compounds represent a class of stable materials showing a great promise to support localized surface plasmon resonances (LSPRs) in both visible and near infrared (NIR) spectral regions. It is still challenging to rationally tune the LSPR band because of the difficulty to control the density of charge carriers in individual refractory nanoparticles and maintain the dispersity of nanoparticles in the processes of synthesis and applications. In this work, controlled chemical transformation of titanium dioxide (TiO2) nanoparticles encapsulated with mesoporous silica (SiO2) shells to titanium nitride (TiN) via nitridation reaction at elevated temperatures is developed to tune the density of free electrons in the resulting titanium-oxide-nitride (TiOxNy) nanoparticles. Such tunability enables a flexibility to support LSPR-based optical absorption in the synthesized TiOxNy@SiO2 core-shell nanoparticles across both the visible and NIR regions. The silica shells play a crucial role in preventing the sintering of TiOxNy nanoparticles in the nitridation reaction and maintaining the stability of TiOxNy nanoparticles in applications. The LSPR-based broadband absorption of light in the TiOxNy@SiO2 nanoparticles exhibits strong photothermal effect with photo-to-thermal conversion efficiency as high as ~ 76%.

Keywords

titanium-oxide-nitride nanoparticlesmesoporous silica coatingnitridation reactionstructural transformationplasmonic absorptionphotothermal effect

Electronic Supplementary Material

Download File(s)
12274_2021_3427_MOESM1_ESM.pdf (2.1 MB)

References

[1]
Ding, S. Y.; Yi, J.; Li, J. F.; Ren, B.; Wu, D. Y.; Panneerselvam, R.; Tian, Z. Q. Nanostructure-based plasmon-enhanced Raman spectroscopy for surface analysis of materials. Nat. Rev. Mater. 2016, 1, 16021.
Crossref Google Scholar
[2]
Ray, P. C. Size and shape dependent second order nonlinear optical properties of nanomaterials and their application in biological and chemical sensing. Chem. Rev. 2010, 110, 5332-5365.
Crossref Google Scholar
[3]
Chen, S.; Weitemier, A. Z.; Zeng, X.; He, L. M.; Wang, X. Y.; Tao, Y. Q.; Huang, A. J. Y.; Hashimotodani, Y.; Kano, M.; Iwasaki, H. et al. Near-infrared deep brain stimulation via upconversion nanoparticle-mediated optogenetics. Science 2018, 359, 679-684.
Crossref Google Scholar
[4]
Liu, J. N.; Pan, L. M.; Shang, C. F.; Lu, B.; Wu, R. J.; Feng, Y.; Chen, W. Y.; Zhang, R. W.; Bu, J. W.; Xiong, Z. Q. et al. A highly sensitive and selective nanosensor for near-infrared potassium imaging. Sci. Adv. 2020, 6, eaax9757.
Crossref Google Scholar
[5]
Gupta, N.; Chan, Y. H.; Saha, S.; Liu, M. H. Recent development in near-infrared photothermal therapy based on semiconducting polymer dots. ACS Appl. Polym. Mater. 2020, 2, 4195-4221.
Crossref Google Scholar
[6]
Chen, J. Y.; Glaus, C.; Laforest, R.; Zhang, Q.; Yang, M. X.; Gidding, M.; Welch, M. J.; Xia, Y. N. Gold nanocages as photothermal transducers for cancer treatment. Small 2010, 6, 811-817.
Crossref Google Scholar
[7]
Wang, Y. C.; Black, K. C. L.; Luehmann, H.; Li, W. Y.; Zhang, Y.; Cai, X.; Wan, D. H.; Liu, S. Y.; Li, M.; Kim, P. et al. Comparison study of gold nanohexapods, nanorods, and nanocages for photothermal cancer treatment. ACS Nano 2013, 7, 2068-2077.
Crossref Google Scholar
[8]
Reddy, H.; Guler, U.; Kudyshev, Z.; Kildishev, A. V.; Shalaev, V. M.; Boltasseva, A. Temperature-dependent optical properties of plasmonic titanium nitride thin films. ACS Photonics 2017, 4, 1413-1420.
Crossref Google Scholar
[9]
Xing, Y.; Tang, S. S.; Du, X.; Xu, T. L.; Zhang, X. J. Near-infrared light-driven yolk@shell carbon@silica nanomotors for fuel-free triglyceride degradation. Nano Res. 2021, 14, 654-659.
Crossref Google Scholar
[10]
Chen, Y. C.; Hsu, Y. K.; Popescu, R.; Gerthsen, D.; Lin, Y. G.; Feldmann, C. Au@Nb@HxK1-xNbO3 nanopeapods with near-infrared active plasmonic hot-electron injection for water splitting. Nat. Commun. 2018, 9, 232.
Crossref Google Scholar
[11]
Appleyard, P. G. Infrared extinction performance of high aspect ratio carbon nanoparticles. J. Opt. A: Pure Appl. Opt. 2006, 8, 101-113.
Google Scholar
[12]
Dai, L. W.; Song, L. P.; Huang, Y. J.; Zhang, L.; Lu, X. F.; Zhang, J. W.; Chen, T. Bimetallic Au/Ag core-shell superstructures with tunable surface plasmon resonance in the near-infrared region and high performance surface-enhanced Raman scattering. Langmuir 2017, 33, 5378-5384.
Google Scholar
[13]
Jain, P. K.; Lee, K. S.; El-Sayed, I. H.; El-Sayed, M. A. Calculated absorption and scattering properties of gold nanoparticles of different size, shape, and composition: Applications in biological imaging and biomedicine. J. Phys. Chem. B 2006, 110, 7238-7248.
Google Scholar
[14]
Chang, H. H.; Murphy, C. J. Mini gold nanorods with tunable plasmonic peaks beyond 1000 nm. Chem. Mater. 2018, 30, 1427-1435.
Google Scholar
[15]
Lee, K. S.; El-Sayed, M. A. Gold and silver nanoparticles in sensing and imaging: Sensitivity of plasmon response to size, shape, and metal composition. J. Phys. Chem. B 2006, 110, 19220-19225.
Google Scholar
[16]
Radloff, C.; Halas, N. J. Plasmonic properties of concentric nanoshells. Nano Lett. 2004, 4, 1323-1327.
Google Scholar
[17]
Kumar, M.; Umezawa, N.; Ishii, S.; Nagao, T. Examining the performance of refractory conductive ceramics as plasmonic materials: A theoretical approach. ACS Photonics 2016, 3, 43-50.
Google Scholar
[18]
Mohsen, A. A.; Zahran, M.; Habib, S. E. D.; Allam, N. K. Refractory plasmonics enabling 20% efficient lead-free perovskite solar cells. Sci. Rep. 2020, 10, 6732.
Google Scholar
[19]
Xian, Y. H.; Cai, Y.; Sun, X. Y.; Liu, X. F.; Guo, Q. B.; Zhang, Z. X.; Tong, L. M.; Qiu, J. R. Refractory plasmonic metal nitride nanoparticles for broadband near-infrared optical switches. Laser Photonics Rev. 2019, 13, 1900029.
Google Scholar
[20]
Li, W.; Guler, U.; Kinsey, N.; Naik, G. V.; Boltasseva, A.; Guan, J. G.; Shalaev, V. M.; Kildishev, A. V. Refractory plasmonics with titanium nitride: Broadband metamaterial absorber. Adv. Mater. 2014, 26, 7959-7965.
Google Scholar
[21]
Naldoni, A.; Guler, U.; Wang, Z. X.; Marelli, M.; Malara, F.; Meng, X. G.; Besteiro, L. V.; Govorov, A. O.; Kildishev, A. V.; Boltasseva, A. et al. Broadband hot-electron collection for solar water splitting with plasmonic titanium nitride. Adv. Opt. Mater. 2017, 5, 1601031.
Google Scholar
[22]
Zeng, Q. Y.; Bai, J.; Li, J. H.; Zhou, B. X.; Sun, Y. G. A low-cost photoelectrochemical tandem cell for highly-stable and efficient solar water splitting. Nano Energy 2017, 41, 225-232.
Google Scholar
[23]
Manthiram, K.; Alivisatos, A. P. Tunable localized surface plasmon resonances in tungsten oxide nanocrystals. J. Am. Chem. Soc. 2012, 134, 3995-3998.
Google Scholar
[24]
Lin, L. N.; Feng, X. Y.; Lan, D. P.; Chen, Y.; Zhong, Q. L.; Liu, C.; Cheng, Y.; Qi, R. J.; Ge, J. P.; Yu, C. Z. et al. Coupling effect of Au nanoparticles with the oxygen vacancies of TiO2-x for enhanced charge transfer. J. Phys. Chem. C 2020, 124, 23823-23831.
Google Scholar
[25]
Wang, Q.; Brier, M.; Joshi, S.; Puntambekar, A.; Chakrapani, V. Defect-induced Burstein-Moss shift in reduced V2O5 nanostructures. Phys. Rev. B 2016, 94, 245305.
Google Scholar
[26]
Li, Y. H.; Chen, X.; Zhang, M. J.; Zhu, Y. M.; Ren, W. J.; Mei, Z. W.; Gu, M.; Pan, F. Oxygen vacancy-rich MoO3-x nanobelts for photocatalytic N2 reduction to NH3 in pure water. Catal. Sci. Technol. 2019, 9, 803-810.
Google Scholar
[27]
Li, X. D.; Wang, D. Y.; Zhang, Y.; Liu, L. T.; Wang, W. S. Surface-ligand protected reduction on plasmonic tuning of one-dimensional MoO3-x nanobelts for solar steam generation. Nano Res. 2020, 13, 3025-3032.
Google Scholar
[28]
Ye, X. C.; Reifsnyder Hickey, D.; Fei, J. Y.; Diroll, B. T.; Paik, T.; Chen, J.; Murray, C. B. Seeded growth of metal-doped plasmonic oxide heterodimer nanocrystals and their chemical transformation. J. Am. Chem. Soc. 2014, 136, 5106-5115.
Google Scholar
[29]
Staller, C. M.; Gibbs, S. L.; Saez Cabezas, C. A.; Milliron, D. J. Quantitative analysis of extinction coefficients of tin-doped indium oxide nanocrystal ensembles. Nano Lett. 2019, 19, 8149-8154.
Google Scholar
[30]
Howell, I. R.; Giroire, B.; Garcia, A.; Li, S.; Aymonier, C.; Watkins, J. J. Fabrication of plasmonic TiN nanostructures by nitridation of nanoimprinted TiO2 nanoparticles. J. Mater. Chem. C 2018, 6, 1399-1406.
Google Scholar
[31]
Li, C. C.; Shi, J. J.; Zhu, L.; Zhao, Y. Y.; Lu, J.; Xu, L. Q. Titanium nitride hollow nanospheres with strong lithium polysulfide chemisorption as sulfur hosts for advanced lithium-sulfur batteries. Nano Res. 2018, 11, 4302-4312.
Google Scholar
[32]
Zukalova, M.; Prochazka, J.; Bastl, Z.; Duchoslav, J.; Rubacek, L.; Havlicek, D.; Kavan, L. Facile conversion of electrospun TiO2 into titanium nitride/oxynitride fibers. Chem. Mater. 2010, 22, 4045-4055.
Google Scholar
[33]
Dong, S. M.; Chen, X.; Gu, L.; Zhou, X. H.; Xu, H. X.; Wang, H. B.; Liu, Z. H.; Han, P. X.; Yao, J. H.; Wang, L. et al. Facile preparation of mesoporous titanium nitride microspheres for electrochemical energy storage. ACS Appl. Mater. Interfaces 2011, 3, 93-98.
Google Scholar
[34]
Kan, X. Q.; Deng, C. J.; Yu, C.; Ding, J.; Zhu, H. X. Synthesis, electrochemical and photoluminescence properties of titanium nitride nanoparticles. J. Mater. Sci.: Mater. Electron. 2018, 29, 10624-10630.
Google Scholar
[35]
Sjöberg, J.; Pompe, R. Nitridation of amorphous silica with ammonia. J. Am. Ceram. Soc. 1992, 75, 2189-2193.
Google Scholar
[36]
Kirchhof, J.; Unger, S.; Dellith, J.; Scheffel, A. Diffusion in binary TiO2-SiO2 glasses. Opt. Mater. Express 2014, 4, 672-680.
Google Scholar
[37]
Zhang, Z. Z.; Luo, Z. S.; Yang, Z. P.; Zhang, S. Y.; Zhang, Y.; Zhou, Y. G.; Wang, X. X.; Fu, X. Z. Band-gap tuning of N-doped TiO2 photocatalysts for visible-light-driven selective oxidation of alcohols to aldehydes in water. RSC Adv. 2013, 3, 7215-7218.
Google Scholar
[38]
Fletcher, A. N. Molecular structure of ethanol-d1 solutions. Near-infrared study of hydrogen bonding. J. Phys. Chem. 1972, 76, 2562-2571.
Google Scholar
[39]
Gschwend, P. M.; Conti, S.; Kaech, A.; Maake, C.; Pratsinis, S. E. Silica-coated TiN particles for killing cancer cells. ACS Appl. Mater. Interfaces 2019, 11, 22550-22560.
Google Scholar
[40]
Kaskel, S.; Schlichte, K.; Chaplais, G.; Khanna, M. Synthesis and characterisation of titanium nitride based nanoparticles. J. Mater. Chem. 2003, 13, 1496-1499.
Google Scholar
[41]
Kim, I. S.; Kumta, P. N. Hydrazide sol-gel synthesis of nanostructured titanium nitride: Precursor chemistry and phase evolution. J. Mater. Chem. 2003, 13, 2028-2035.
Google Scholar
[42]
Hu, J. Q.; Lu, Q. Y.; Tang, K. B.; Yu, S. H.; Qian, Y. T.; Zhou, G. E.; Liu, X. M. Low-temperature synthesis of nanocrystalline titanium nitride via a benzene-thermal route. J. Am. Ceram. Soc. 2000, 83, 430-432.
Google Scholar
[43]
Joshi, U. A.; Chung, S. H.; Lee, J. S. Low-temperature, solvent-free solid-state synthesis of single-crystalline titanium nitride nanorods with different aspect ratios. J. Solid State Chem. 2005, 178, 755-760.
Google Scholar
[44]
Yang, X. G.; Li, C.; Yang, L. H.; Yan, Y.; Qian, Y. T. Reduction-nitridation synthesis of titanium nitride nanocrystals. J. Am. Ceram. Soc. 2003, 86, 206-208.
Google Scholar
Nano Research
Volume 14 Issue 9,
September 2021
Pages 3228-3233
DOI: 10.1007/s12274-021-3427-7
Cite this article:
Wei Q, Kuhn DL, Zander Z, et al. Silica-coating-assisted nitridation of TiO2 nanoparticles and their photothermal property. Nano Research, 2021, 14(9): 3228-3233. https://doi.org/10.1007/s12274-021-3427-7
Topics:
Nanocrystals
Part of a topical collection:
Seventh Nano Research Award

866

Views

10

Crossref

11

Web of Science

12

Scopus

2

CSCD

Altmetrics
Received: 05 January 2021
Revised: 23 February 2021
Accepted: 26 February 2021
Published: 25 March 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
Return