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Research Article

Flexible and stable 3D lithium metal anodes based on self-standing MXene/COF frameworks for high-performance lithium-sulfur batteries

Chuanliang Wei1, Yusheng Wang1, Yuchan Zhang1, Liwen Tan1, Yi Qian1, Yuan Tao1, Shenglin Xiong2, Jinkui Feng1( )
Research Center for Carbon Nanomaterials,Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University,Jinan,250061,China;
School of Chemistry and Chemical Engineering,Shandong University,Jinan,250100,China;
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Graphical Abstract

Abstract

Lithium metal (Li) is believed to be the ultimate anode for lithium-ion batteries (LIBs) owing to the advantages of high theoretical capacity, the lowest electrochemical potential, and light weight. Nevertheless, issues such as uncontrollable growth of Li dendrites, large volume changes, high chemical reactivity, and unstable solid electrolyte interphase (SEI) hinder its rapid development and practical application. Herein a stable and dendrite-free Li-metal anode is obtained by designing a flexible and freestanding MXene/COF framework for metallic Li. COF-LZU1 microspheres are distributed among the MXene film framework. Lithiophilic COF-LZU1 microspheres as nucleation seeds can promote uniform Li nucleation by homogenizing the Li+ flux and lowering the nucleation barrier, finally resulting in dense and dendrite-free Li deposition. Under the regulation of the COF-LZU1 seeds, the Coulombic efficiency of the MXene/COF-LZU1 framework and electrochemical stability of corresponding symmetric cells are obviously enhanced. Li-S full cells with the modified Li-metal anode and sulfurized polyacrylonitrile (S@PAN) cathode also exhibited a superior electrochemical performance.

Keywords

MXenecovalent organic framework (COF)dendrite-freelithium metal anodelithium sulfur batterysulfurized polyacrylonitrile

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Nano Research
Volume 14 Issue 10,
October 2021
Pages 3576-3584
DOI: 10.1007/s12274-021-3433-9
Cite this article:
Wei C, Wang Y, Zhang Y, et al. Flexible and stable 3D lithium metal anodes based on self-standing MXene/COF frameworks for high-performance lithium-sulfur batteries. Nano Research, 2021, 14(10): 3576-3584. https://doi.org/10.1007/s12274-021-3433-9
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Received: 21 January 2021
Revised: 01 March 2021
Accepted: 01 March 2021
Published: 07 April 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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