AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

Multi-interface collaboration of graphene cross-linked NiS-NiS2- Ni3S4 polymorph foam towards robust hydrogen evolution in alkaline electrolyte

Haiqing Wang1,§( ), Wenjing Zhang2,§, Xiaowei Zhang1, Shuxian Hu2, Zhicheng Zhang3, Weijia Zhou1, Hong Liu1,4( )
Collaborative Innovation Center of Technology and Equipment for Biological Diagnosis and Therapy in Universities of Shandong Institute for Advanced Interdisciplinary Research (iAIR), University of Jinan Jinan 250022 China
Beijing Computational Science Research CenterBeijing 100193 China
Tianjin Key Laboratory of Molecular Optoelectronic Sciences Department of Chemistry School of Science Tianjin University, Tianjin 300072 China
State Key Laboratory of Crystal Materials Shandong University Jinan 250100 China

§ Haiqing Wang and Wenjing Zhang contributed equally to this work.

Show Author Information

Graphical Abstract

Abstract

Electrocatalytic hydrogen production in alkaline media is extensively adopted in industry. Unfortunately, further performance improvement is severely impeded by the retarded kinetics, which requires the fine regulation of water dissociation, hydrogen recombination, and hydroxyl desorption. Herein, we develop a multi-interface engineering strategy to make an elaborate balance for the alkaline hydrogen evolution reaction (HER) kinetics. The graphene cross-linked three-phase nickel sulfide (NiS-NiS2-Ni3S4) polymorph foam (G-NNNF) was constructed through hydrothermal sulfidation of graphene wrapped nickel foam as a three-dimensional (3D) scaffold template. The G-NNNF exhibits superior catalytic activity toward HER in alkaline electrolyte, which only requires an overpotential of 68 mV to drive 10 mA·cm−2 and is better than most of the recently reported metal sulfides catalysts. Density functional theory (DFT) calculations verify the interfaces between nickel sulfides (NiS/NiS2/Ni3S4) and cross-linked graphene can endow the electrocatalyst with preferable hydrogen adsorption as well as metallic nature. In addition, the electron transfer from Ni3S4/NiS2 to NiS results in the electron accumulation on NiS and the hole accumulation on Ni3S4/NiS2, respectively. The electron accumulation on NiS favors the optimization of the H* adsorption, whereas the hole accumulation on Ni3S4 is beneficial for the adsorption of H2O. The work about multi-interface collaboration pushes forward the frontier of excellent polymorph catalysts design.

Keywords

hydrogen evolution reactioninterface engineeringpolymorphnickel sulfideheterointerface

Electronic Supplementary Material

Download File(s)
12274_2021_3445_MOESM1_ESM.pdf (2.3 MB)

References

1

Li, H. Y.; Chen, S. M.; Jia, X. F.; Xu, B.; Lin, H. F.; Yang, H. Z.; Song, L.; Wang, X. Amorphous nickel-cobalt complexes hybridized with 1T-phase molybdenum disulfide via hydrazine-induced phase transformation for water splitting. Nat. Commun. 2017, 8, 15377
Crossref Google Scholar
2

Ni, B.; He, P.; Liao, W. X.; Chen, S. M.; Gu, L.; Gong, Y.; Wang, K.; Zhuang, J.; Song, L.; Zhou, G. et al. Surface oxidation of AuNi heterodimers to achieve high activities toward hydrogen/oxygen evolution and oxygen reduction reactions. Small 2018, 14, 1703749
Crossref Google Scholar
3

Li, H. Y.; Chen, S. M.; Zhang, Y.; Zhang, Q. H.; Jia, X. F.; Zhang, Q.; Gu, L.; Sun, X. M.; Song, L.; Wang, X. Systematic design of superaerophobic nanotube-array electrode comprised of transition- metal sulfides for overall water splitting. Nat. Commun. 2018, 9, 2452.
Crossref Google Scholar
4

Liu, D. L.; Zhang, C.; Yu, Y. F.; Shi, Y. M.; Yu, Y.; Niu, Z. Q.; Zhang, B. Hydrogen evolution activity enhancement by tuning the oxygen vacancies in self-supported mesoporous spinel oxide nanowire arrays. Nano Res. 2018, 11, 603-613.
Crossref Google Scholar
5

Hua, W.; Sun, H. H.; Xu, F.; Wang, J. G. A review and perspective on molybdenum-based electrocatalysts for hydrogen evolution reaction. Rare Met. 2020, 39, 335-351.
Crossref Google Scholar
6

Cheng, T.; Wang, L.; Merinov, B. V.; Goddard III, W. A. Explanation of dramatic pH-dependence of hydrogen binding on noble metal electrode: Greatly weakened water adsorption at high pH. J. Am. Chem. Soc. 2018, 140, 7787-7790.
Crossref Google Scholar
7

Lu, H. Y.; Fan, W.; Huang, Y. P.; Liu, T. X. Lotus root-like porous carbon nanofiber anchored with CoP nanoparticles as all-pH hydrogen evolution electrocatalysts. Nano Res. 2018, 11, 1274-1284.
Crossref Google Scholar
8

Wei, J.; Zhou, M.; Long, A. C.; Xue, Y. M.; Liao, H. B.; Wei, C.; Xu, Z. J. Heterostructured electrocatalysts for hydrogen evolution reaction under alkaline conditions. Nano-Micro Lett. 2018, 10, 75.
Crossref Google Scholar
9

Wang, Z. Y.; Li, R. L.; Su, C. L.; Loh, K. P. Intercalated phases of transition metal dichalcogenides. SmartMat 2020, 1, e1013.
Crossref Google Scholar
10

Lv, J.; Cheng, Y.; Liu, W.; Quan, B.; Liang, X. H.; Ji, G. B.; Du, Y. W. Achieving better impedance matching by a sulfurization method through converting Ni into NiS/Ni3S4 composites. J. Mater. Chem. C 2018, 6, 1822-1828.
Crossref Google Scholar
11

Barim, G.; Smock, S. R.; Antunez, P. D.; Glaser, D.; Brutchey, R. L. Phase control in the colloidal synthesis of well-defined nickel sulfide nanocrystals. Nanoscale 2018, 10, 16298-16306.
Crossref Google Scholar
12

Dai, C.; Li, B.; Li, J.; Zhao, B.; Wu, R. X.; Ma, H. F.; Duan, X. D. Controllable synthesis of NiS and NiS2 nanoplates by chemical vapor deposition. Nano Res. 2020, 13, 2506-2511.
Crossref Google Scholar
13

Zhu, J. H.; Chen, Z.; Jia, L.; Lu, Y. Q.; Wei, X. R.; Wang, X. N.; Wu, W. D.; Han, N.; Li, Y. G.; Wu, Z. X. Solvent-free nanocasting toward universal synthesis of ordered mesoporous transition metal sulfide@N-doped carbon composites for electrochemical applications. Nano Res. 2019, 12, 2250-2258.
Crossref Google Scholar
14

Dong, Q. C.; Zhang, Y. Z.; Dai, Z. Y.; Wang, P.; Zhao, M.; Shao, J. J.; Huang, W.; Dong, X. C. Graphene as an intermediary for enhancing the electron transfer rate: A free-standing Ni3S2@graphene@Co9S8 electrocatalytic electrode for oxygen evolution reaction. Nano Res. 2018, 11, 1389-1398.
Crossref Google Scholar
15

Guo, Y. N.; Park, T.; Yi, J. W.; Henzie, J.; Kim, J.; Wang, Z. L.; Jiang, B.; Bando, Y.; Sugahara, Y.; Tang, J. et al. Nanoarchitectonics for transition-metal-sulfide-based electrocatalysts for water splitting. Adv. Mater. 2019, 31, 1807134.
Crossref Google Scholar
16

Jiang, N.; Tang, Q.; Sheng, M.; You, B.; Jiang, D. E.; Sun, Y. J. Nickel sulfides for electrocatalytic hydrogen evolution under alkaline conditions: A case study of crystalline NiS, NiS2, and Ni3S2 nanoparticles. Catal. Sci. Technol. 2016, 6, 1077-1084.
Crossref Google Scholar
17

Staszak-Jirkovský, J.; Malliakas, C. D.; Lopes, P. P.; Danilovic, N.; Kota, S. S.; Chang, K. C.; Genorio, B.; Strmcnik, D.; Stamenkovic, Vojislav R.; Kanatzidis, M. G. et al. Design of active and stable Co-Mo-Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction. Nat. Mater. 2016, 15, 197-203.
Crossref Google Scholar
18

Centi, G. Smart catalytic materials for energy transition. SmartMat 2020, 1, e1005.
Crossref Google Scholar
19

Lin, J. H.; Wang, P. C.; Wang, H. H.; Li, C.; Si, X. Q.; Qi, J. L.; Cao, J.; Zhong, Z. X.; Fei, W. D.; Feng, J. C. Defect-rich heterogeneous MoS2/NiS2 nanosheets electrocatalysts for efficient overall water splitting. Adv. Sci. 2019, 6, 1900246.
Crossref Google Scholar
20

Wang, H. Q.; Xu, X. B.; Ni, B.; Li, H. Y.; Bian, W.; Wang, X. 3D self-assembly of ultrafine molybdenum carbide confined in N-doped carbon nanosheets for efficient hydrogen production. Nanoscale 2017, 9, 15895-15900.
Crossref Google Scholar
21

Hu, J.; Zhang, C. X.; Jiang, L.; Lin, H.; An, Y. M.; Zhou, D.; Leung, M. K. H.; Yang, S. H. Nanohybridization of MoS2 with layered double hydroxides efficiently synergizes the hydrogen evolution in alkaline media. Joule 2017, 1, 383-393.
Crossref Google Scholar
22

Wang, P. T.; Zhang, X.; Zhang, J.; Wan, S.; Guo, S. J.; Lu, G.; Yao, J. L.; Huang, X. Q. Precise tuning in platinum-nickel/nickel sulfide interface nanowires for synergistic hydrogen evolution catalysis. Nat. Commun. 2017, 8, 14580.
Crossref Google Scholar
23

Jin, H. Y.; Liu, X.; Jiao, Y.; Vasileff, A.; Zheng, Y.; Qiao, S. Z. Constructing tunable dual active sites on two-dimensional C3N4@MoN hybrid for electrocatalytic hydrogen evolution. Nano Energy 2018, 53, 690-697.
Crossref Google Scholar
24

Chen, Z. P.; Ren, W. C.; Gao, L. B.; Liu, B. L.; Pei, S. F.; Cheng, H. M. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. Nat. Mater. 2011, 10, 424-428.
Crossref Google Scholar
25

Zhang, B.; Hou, J. G.; Wu, Y. Z.; Cao, S. Y.; Li, Z. W.; Nie, X. W.; Gao, Z. M.; Sun, L. C. Tailoring active sites in mesoporous defect- rich NC/Vo-WON heterostructure array for superior electrocatalytic hydrogen evolution. Adv. Energy Mater. 2019, 9, 1803693.
Crossref Google Scholar
26

Wang, H. Q.; Zhang, X. W.; Wang, J. G.; Liu, H. L.; Hu, S. L.; Zhou, W. J.; Liu, H.; Wang, X. Puffing quaternary FexCoyNi1-x-yP nanoarray via kinetically controlled alkaline etching for robust overall water splitting. Sci. China Mater. 2020, 63, 1054-1064.
Crossref Google Scholar
27

Zhang, Z. F.; Wang, H. Q.; Ma, M. J.; Liu, H. L.; Zhang, Z. C.; Zhou, W. J.; Liu, H. Integrating NiMoO wafer as a heterogeneous 'turbo' for engineering robust Ru-based electrocatalyst for overall water splitting. Chem. Eng. J. 2020, 127686.
Crossref Google Scholar
28

Pothu, R.; Bolagam, R.; Wang, Q. H.; Ni, W.; Cai, J. F.; Peng, X. X.; Feng, Y. Z.; Ma, J. M. Nickel sulfide-based energy storage materials for high-performance electrochemical capacitors. Rare Met. 2021, 40, 353-373.
Crossref Google Scholar
29

Luo, P.; Zhang, H. J.; Liu, L.; Zhang, Y.; Deng, J.; Xu, C. H.; Hu, N.; Wang, Y. Targeted synthesis of unique nickel sulfide (NiS, NiS2) microarchitectures and the applications for the enhanced water splitting system. ACS Appl. Mater. Interfaces 2017, 9, 2500-2508.
Crossref Google Scholar
30

Wang, H. Q.; Xu, Z. F.; Zhang, Z. F.; Hu, S. X.; Ma, M. J.; Zhang, Z. C.; Zhou, W. J.; Liu, H. Addressable surface engineering for N-doped WS2 nanosheet arrays with abundant active sites and the optimal local electronic structure for enhanced hydrogen evolution reaction. Nanoscale 2020, 12, 22541-22550.
Crossref Google Scholar
31

Ni, B.; He, T.; Wang, J. O.; Zhang, S. M.; Ouyang, C.; Long, Y.; Zhuang, J.; Wang, X. The formation of (NiFe)S2 pyrite mesocrystals as efficient pre-catalysts for water oxidation. Chem. Sci. 2018, 9. 2762-2767.
Crossref Google Scholar
32

Wu, T. X.; Zhu, X. G.; Wang, G. Z.; Zhang, Y. X.; Zhang, H. M.; Zhao, H. J. Vapor-phase hydrothermal growth of single crystalline NiS2 nanostructure film on carbon fiber cloth for electrocatalytic oxidation of alcohols to ketones and simultaneous H2 evolution. Nano Res. 2018, 11, 1004-1017.
Crossref Google Scholar
33

Kong, L.; Tang, C.; Peng, H. J.; Huang, J. Q.; Zhang, Q. Advanced energy materials for flexible batteries in energy storage: A review. SmartMat 2020, 1, e1007.
Crossref Google Scholar
34

Li, Q.; Wang, D. W.; Han, C.; Ma, X.; Lu, Q. Q.; Xing, Z. C.; Yang, X. R. Construction of amorphous interface in an interwoven NiS/ NiS2 structure for enhanced overall water splitting. J. Mater. Chem. A 2018, 6, 8233-8237.
Crossref Google Scholar
35

Fang, Z. W.; Peng, L. L.; Qian, Y. M.; Zhang, X.; Xie, Y. J.; Cha, J. J.; Yu, G. H. Dual tuning of Ni-Co-A (A = P, Se, O) nanosheets by anion substitution and holey engineering for efficient hydrogen evolution. J. Am. Chem. Soc. 2018, 140, 5241-5247.
Crossref Google Scholar
36

Yang, Y.; Yao, H. Q.; Yu, Z. H.; Islam, S. M.; He, H. Y.; Yuan, M. W.; Yue, Y. H.; Xu, K.; Hao, W. C.; Sun, G. B. et al. Hierarchical nanoassembly of MoS2/Co9S8/Ni3S2/Ni as a highly efficient electrocatalyst for overall water splitting in a wide pH range. J. Am. Chem. Soc. 2019, 141, 10417-10430.
Crossref Google Scholar
37

Feng, L. L.; Yu, G. T.; Wu, Y. Y.; Li, G. D.; Li, H.; Sun, Y. H.; Asefa, T.; Chen, W.; Zou, X. X. High-index faceted Ni3S2 nanosheet arrays as highly active and ultrastable electrocatalysts for water splitting. J. Am. Chem. Soc. 2015, 137, 14023-14026.
Crossref Google Scholar
38

Miao, R.; Dutta, B.; Sahoo, S.; He, J. K.; Zhong, W.; Cetegen, S. A.; Jiang, T.; Alpay, S. P.; Suib, S. L. Mesoporous iron sulfide for highly efficient electrocatalytic hydrogen evolution. J. Am. Chem. Soc. 2017, 139, 13604-13607.
Crossref Google Scholar
39

Kim, M.; Anjum, M. A. R.; Lee, M.; Lee, B. J.; Lee, J. S. Activating MoS2 basal plane with Ni2P nanoparticles for Pt-like hydrogen evolution reaction in acidic media. Adv. Funct. Mater. 2019, 29, 1809151.
Crossref Google Scholar
40

Li, M. C.; Qian, Y. T.; Du, J. M.; Wu, H. R.; Zhang, L. Y.; Li, G.; Li, K. D.; Wang, W. M.; Kang, D. J. CuS nanosheets decorated with CoS2 nanoparticles as an efficient electrocatalyst for enhanced hydrogen evolution at all pH values. ACS Sustainable Chem. Eng. 2019, 7, 14016-14022.
Crossref Google Scholar
41

Jiang, Y. Q.; Qian, X.; Zhu, C. L.; Liu, H. Y.; Hou, L. X. Nickel cobalt sulfide double-shelled hollow nanospheres as superior bifunctional electrocatalysts for photovoltaics and alkaline hydrogen evolution. ACS Appl. Mater. Interfaces 2018, 10, 9379-9389.
Crossref Google Scholar
42

Zhang, J.; Wang, T.; Pohl, D.; Rellinghaus, B.; Dong, R. H.; Liu, S. H.; Zhuang, X. D.; Feng, X. L. Interface engineering of MoS2/Ni3S2 heterostructures for highly enhanced electrochemical overall-water- splitting activity. Angew. Chem. , Int. Ed. 2016, 55, 6702-6707.
Crossref Google Scholar
43

Li, Y. X.; Yin, J.; An, L.; Lu, M.; Sun, K.; Zhao, Y. Q.; Gao, D. Q.; Cheng, F. Y.; Xi, P. X. FeS2/CoS2 interface nanosheets as efficient bifunctional electrocatalyst for overall water splitting. Small 2018, 14, 1801070.
Crossref Google Scholar
44

Peng, S. J.; Li, L. L.; Zhang, J.; Tan, T. L.; Zhang, T. R.; Ji, D. X.; Han, X. P.; Cheng, F. Y.; Ramakrishna, S. Engineering Co9S8/WS2 array films as bifunctional electrocatalysts for efficient water splitting. J. Mater. Chem. A 2017, 5, 23361-23368.
Crossref Google Scholar
45

Yang, Y. Q.; Zhang, K.; Lin, H. L.; Li, X.; Chan, H. C.; Yang, L. C.; Gao, Q. S. MoS2-Ni3S2 heteronanorods as efficient and stable bifunctional electrocatalysts for overall water splitting. ACS Catal. 2017, 7, 2357-2366.
Crossref Google Scholar
46

Gu, X. D.; Zheng, S. J.; Huang, X. B.; Yuan, H. F.; Li, J. P.; Kundu, M.; Wang, X. G. Hybrid Ni3S2-MoS2 nanowire arrays as a pH-universal catalyst for accelerating the hydrogen evolution reaction. Chem. Commun. 2020, 56, 2471-2474.
Crossref Google Scholar
47

Guo, Y. N.; Tang, J.; Wang, Z. L.; Kang, Y. M.; Bando, Y.; Yamauchi, Y. Elaborately assembled core-shell structured metal sulfides as a bifunctional catalyst for highly efficient electrochemical overall water splitting. Nano Energy 2018, 47, 494-502.
Crossref Google Scholar
48

Hou, Y.; Qiu, M.; Nam, G.; Kim, M. G.; Zhang, T.; Liu, K. J.; Zhuang, X. D.; Cho, J.; Yuan, C.; Feng, X. L. Integrated hierarchical cobalt sulfide/nickel selenide hybrid nanosheets as an efficient three- dimensional electrode for electrochemical and photoelectrochemical water splitting. Nano Lett. 2017, 17, 4202-4209.
Crossref Google Scholar
49

Wu, Y. Y.; Liu, Y. P.; Li, G. D.; Zou, X.; Lian, X. R.; Wang, D. J.; Sun, L.; Asefa, T.; Zou, X. X. Efficient electrocatalysis of overall water splitting by ultrasmall NixCo3−xS4 coupled Ni3S2 nanosheet arrays. Nano Energy 2017, 35, 161-170.
Crossref Google Scholar
50

Zheng, M. Y.; Du, J.; Hou, B. P.; Xu, C. L. Few-layered Mo(1-x)WxS2 hollow nanospheres on Ni3S2 nanorod heterostructure as robust electrocatalysts for overall water splitting. ACS Appl. Mater. Interfaces 2017, 9, 26066-26076.
Crossref Google Scholar
Nano Research
Volume 14 Issue 12,
December 2021
Pages 4857-4864
DOI: 10.1007/s12274-021-3445-5
Cite this article:
Wang H, Zhang W, Zhang X, et al. Multi-interface collaboration of graphene cross-linked NiS-NiS2- Ni3S4 polymorph foam towards robust hydrogen evolution in alkaline electrolyte. Nano Research, 2021, 14(12): 4857-4864. https://doi.org/10.1007/s12274-021-3445-5
Topics:
Hydrogen evolution reaction

772

Views

64

Crossref

65

Web of Science

65

Scopus

11

CSCD

Altmetrics
Received: 24 February 2021
Revised: 08 March 2021
Accepted: 08 March 2021
Published: 17 April 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
Return