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Research Article

Improving the intrinsic electronic conductivity of NiMoO4 anodes by phosphorous doping for high lithium storage

Luchao Yue1,2, Chaoqun Ma3, Shihai Yan3, Zhenguo Wu1, Wenxi Zhao2, Qian Liu2( ), Yonglan Luo2, Benhe Zhong1, Fang Zhang4, Yang Liu5, Abdulmohsen Ali Alshehri6, Khalid Ahmed Alzahrani6, Xiaodong Guo1 ( ), Xuping Sun2( )
School of Chemical Engineering Sichuan UniversityChengdu 610065 China
Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054 China
College of Chemistry and Pharmaceutical Sciences Qingdao Agricultural UniversityQingdao 266109 China
National Engineering Research Center for Nanotechnology No. 28 East Jiang Chuan Road, Shanghai 200241 China
School of Materials Science and Engineering Henan Normal UniversityXinxiang 453007 China
Chemistry Department, Faculty of Science, King Abdulaziz University P.O. Box 80203 Jeddah 21589 Saudi Arabia
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Graphical Abstract

Abstract

Heteroatom doping is one of the most promising strategies toward regulating intrinsically sluggish electronic conductivity and kinetic reaction of transition metal oxides for enhancing their lithium storage. Herein, we designed phosphorus-doped NiMoO4 nanorods (P-NiMoO4) by using a facile hydrothermal method and subsequent low-temperature phosphorization treatment. Phosphorus doping played an indispensable role in significantly improving electronic conductivity and the Li+ diffusion kinetics of NiMoO4 materials. Experimental investigation and density functional theory calculation demonstrated that phosphorus doping can expand the interplanar spacing and alter electronic structures of NiMoO4 nanorods. Meanwhile, the introduced phosphorus dopant can generate some oxygen vacancies on the surface of NiMoO4, which can accelerate Li+ diffusion kinetics and provide more active site for lithium storage. As excepted, P-NiMoO4 electrode delivered a high specific capacity (1, 130 mAh·g−1 at 100 mA·g−1 after 100 cycles), outstanding cycling durability (945 mAh·g−1 at 500 mA·g−1 over 200 cycles), and impressive rate performance (640 mAh·g−1 at 2, 000 mA·g−1) for lithium ion batteries (LIBs). This work could provide a potential strategy for improving intrinsic conductivity of transition metal oxides as high-performance anodes for LIBs.

Keywords

NiMoO4phosphorus dopinganodelithium ion batteries

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References

1

Reddy, M. V.; Rao, G. V. S.; Chowdari, B. V. R. Metal oxides and oxysalts as anode materials for Li ion batteries. Chem. Rev. 2013, 113, 5364–5457.
Crossref Google Scholar
2

Liu, Z. L.; Wang, X. X.; Wu, Z. Y.; Yang, S. J.; Yang, S. L.; Chen, S. P.; Wu, X. T.; Chang, X. H.; Yang, P. P.; Zheng, J. et al. Ultrafine Sn4P3 nanocrystals from chloride reduction on mechanically activated Na surface for sodium/lithium ion batteries. Nano Res. 2020, 13, 3157–3164.
Crossref Google Scholar
3

Fan, Z. Y.; Liang, J.; Yu, W.; Ding, S. J.; Cheng, S. D.; Yang, G.; Wang, Y. L.; Xi, Y. X.; Xi, K.; Kumar, R. V. Ultrathin NiO nanosheets anchored on a highly ordered nanostructured carbon as an enhanced anode material for lithium ion batteries. Nano Energy 2015, 16, 152–162.
Crossref Google Scholar
4

Sheng, Q. Q.; Li, Q.; Xiang, L. X.; Huang, T.; Mai, Y. Y.; Han, L. Double diamond structured bicontinuous mesoporous titania templated by a block copolymer for anode material of lithium-ion battery. Nano Res. 2021, 14, 992–997.
Crossref Google Scholar
5

Yue, H. L.; Wang, G. M.; Jin, R. C.; Wang, Q. Y.; Cui, Y. M.; Gao, S. M. Sulfur-doped amorphous NiMoO4 on crystalline Fe2O3 nanorods for enhanced lithium storage performance. J. Mater. Chem. A 2018, 6, 23819–23827.
Crossref Google Scholar
6

Jiang, G. X.; Li, L.; Xie, Z. J.; Cao, B. Q. Facile fabrication of porous NiMoO4@C nanowire as high performance anode material for lithium ion batteries. Ceram. Int. 2019, 45, 18462–18470.
Crossref Google Scholar
7

Park, J. S.; Cho, J. S.; Kang, Y. C. Scalable synthesis of NiMoO4 microspheres with numerous empty nanovoids as an advanced anode material for Li-ion batteries. J. Power Sources 2018, 379, 278–287.
Crossref Google Scholar
8

Liu, W. L.; Zhi, H. Q.; Yu, X. B. Recent progress in phosphorus based anode materials for lithium/sodium ion batteries. Energy Storage Mater. 2019, 16, 290–322.
Crossref Google Scholar
9

Haetge, J.; Djerdj, I.; Brezesinski, T. Nanocrystalline NiMoO4 with an ordered mesoporous morphology as potential material for rechargeable thin film lithium batteries. Chem. Commun. 2012, 48, 6726–6728.
Crossref Google Scholar
10

Wang, X.; Kim, H. M.; Xiao, Y.; Sun, Y. K. Nanostructured metal phosphide-based materials for electrochemical energy storage. J. Mater. Chem. A 2016, 4, 14915–14931.
Crossref Google Scholar
11

Huang, L.; Xiang, J. W.; Zhang, W.; Chen, C. J.; Xu, H. H.; Huang, Y. H. 3D interconnected porous NiMoO4 nanoplate arrays on Ni foam as high-performance binder-free electrode for supercapacitors. J. Mater. Chem. A 2015, 3, 22081–22087.
Crossref Google Scholar
12

Wang, B.; Li, S. M.; Wu, X. Y.; Tian, W. M.; Liu, J. H.; Yu, M. Integration of network-like porous NiMoO4 nanoarchitectures assembled with ultrathin mesoporous nanosheets on three-dimensional graphene foam for highly reversible lithium storage. J. Mater. Chem. A 2015, 3, 13691–13698.
Crossref Google Scholar
13

Xiao, K.; Xia, L.; Liu, G. X.; Wang, S. Q.; Ding, L. X.; Wang, H. H. Honeycomb-like NiMoO4 ultrathin nanosheet arrays for high- performance electrochemical energy storage. J. Mater. Chem. A 2015, 3, 6128–6135.
Crossref Google Scholar
14

Wang, S. G.; Lin, J.; Fan, C. Y.; Li, Y. F.; Zhang, J. P.; Wu, X. L.; Sun, H. Z.; Deng, M. X.; Su, Z. M. Target encapsulating NiMoO4 nanocrystals into 1D carbon nanofibers as free-standing anode material for lithium- ion batteries with enhanced cycle performance. J. Alloys Compd. 2020, 830, 154648.
Crossref Google Scholar
15

Perkins, J. D.; Paudel, T. R.; Zakutayev, A.; Ndione, P. F.; Parilla, P. A.; Young, D. L.; Lany, S.; Ginley, D. S.; Zunger, A.; Perry, N. H. et al. Inverse design approach to hole doping in ternary oxides: Enhancing p-type conductivity in cobalt oxide spinels. Phys. Rev. B 2011, 84, 205207.
Crossref Google Scholar
16

Zou, X. X.; Su, J. A.; Silva, R.; Goswami, A.; Sathe, B. R.; Asefa, T. Efficient oxygen evolution reaction catalyzed by low-density Ni-doped Co3O4 nanomaterials derived from metal-embedded graphitic C3N4. Chem. Commun. 2013, 49, 7522–7524.
Crossref Google Scholar
17

Song, H.; Yun, S. W.; Chun, H. H.; Kim, M. G.; Chung, K. Y.; Kim, H. S.; Cho, B. W.; Kim, Y. T. Anomalous decrease in structural disorder due to charge redistribution in Cr-doped Li4Ti5O12 negative-electrode materials for high-rate Li-ion batteries. Energy Environ. Sci. 2012, 5, 9903–9913.
Crossref Google Scholar
18

Banerjee, S.; Debata, S.; Madhuri, R.; Sharma, P. K. Electrocatalytic behavior of transition metal (Ni, Fe, Cr) doped metal oxide nanocomposites for oxygen evolution reaction. Appl. Surf. Sci. 2018, 449, 660–668.
Crossref Google Scholar
19

Chen, C. C.; Huang, Y. A.; Zhang, H.; Wang, X. F.; Wang, Y. J.; Jiao, L. F.; Yuan, H. T. Controllable synthesis of Cu-doped CoO hierarchical structure for high performance lithium-ion battery. J. Power Sources 2016, 314, 66–75.
Crossref Google Scholar
20

Yan, C. S.; Zhu, Y.; Li, Y. T.; Fang, Z. W.; Peng, L. L.; Zhou, X.; Chen, G.; Yu, G. H. Local built-in electric field enabled in carbon-doped Co3O4 nanocrystals for superior lithium-ion storage. Adv. Funct. Mater. 2018, 28, 1705951.
Crossref Google Scholar
21

Yan, C. S.; Chen, G.; Zhou, X.; Sun, J. X.; Lv, C. D. Template-based engineering of carbon-doped Co3O4 hollow nanofibers as anode materials for lithium-ion batteries. Adv. Funct. Mater. 2016, 26, 1428–1436.
Crossref Google Scholar
22

Song, H.; Kim, Y. T. A Mo-doped TiNb2O7 anode for lithium-ion batteries with high rate capability due to charge redistribution. Chem. Commun. 2015, 51, 9849–9852.
Crossref Google Scholar
23

Guan, B. Y.; Yu, L.; Lou, X. W. General synthesis of multishell mixed- metal oxyphosphide particles with enhanced electrocatalytic activity in the oxygen evolution reaction. Angew. Chem., Int. Ed. 2017, 56, 2386–2389.
Crossref Google Scholar
24

Xiao, Z. H.; Wang, Y.; Huang, Y. C.; Wei, Z. X.; Dong, C. L.; Ma, J. M.; Shen, S. H.; Li, Y. F.; Wang, S. Y. Filling the oxygen vacancies in Co3O4 with phosphorus: An ultra-efficient electrocatalyst for overall water splitting. Energy Environ. Sci. 2017, 10, 2563–2569.
Crossref Google Scholar
25

Kresse, G.; Furthmuller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 1999, 6, 15–50.
Crossref Google Scholar
26

Segall, M. D.; Lindan, P. J. D.; Probert, M. J.; Pickard, C. J.; Hasnip, P. J.; Clark, S. J.; Payne, M. C. First-principles simulation: Ideas, illustrations and the CASTEP code. J. Phys.: Condens. Matter 2002, 14, 2717–2744.
Crossref Google Scholar
27

Blöchl, P. E. Projector augmented-wave method. Phys. Rev. B, Condens. Matter 1994, 50, 17953–17979.
Crossref Google Scholar
28

Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865–3868.
Crossref Google Scholar
29

Grimme, S. Semiempirical GGA-type density functional constructed with a long-range dispersion correction. J. Comput. Chem. 2006, 27, 1787–1799.
Crossref Google Scholar
30

Asahi, R.; Morikawa, T.; Irie, H.; Ohwaki, T. Nitrogen-doped titanium dioxide as visible-light-sensitive photocatalyst: Designs, developments, and prospects. Chem. Rev. 2014, 114, 9824–9852.
Crossref Google Scholar
31

Yue, L. C.; Zhao, H. T.; Wu, Z. G.; Liang, J.; Lu, S. Y.; Chen, G.; Gao, S. Y.; Zhong, B. H.; Guo, X. D.; Sun, X. P. Recent advances in electrospun one-dimensional carbon nanofiber structures/heterostructures as anode materials for sodium ion batteries. J. Mater. Chem. A 2020, 8, 11493–11510.
Crossref Google Scholar
32

Wang, H. G.; Yuan, S.; Ma, D. L.; Zhang, X. B.; Yan, J. M. Electrospun materials for lithium and sodium rechargeable batteries: From structure evolution to electrochemical performance. Energy Environ. Sci. 2015, 8, 1660–1681.
Crossref Google Scholar
33

Yue, H. L.; Wang, G. M.; Xu, Y. K.; Jin, R. C.; Wang, Q. Y.; Gao, S. M. Oxygen-deficient NiMoO4-xSx nanosheets perpendicularly grown on N-doped carbon nanosheets for high performance lithium-ion batteries. J. Power Sources 2020, 455, 227947.
Crossref Google Scholar
34

Wang, Y.; Pan, Q.; Jia, K.; Wang, H. B.; Gao, J. J.; Xu, C. L.; Zhong, Y. J.; Alshehri, A. A.; Alzahrani, K. A.; Guo, X. D. et al. Ni2P nanosheets on carbon cloth: An efficient flexible electrode for sodium-ion batteries. Inorg. Chem. 2019, 58, 6579–6583.
Crossref Google Scholar
35

An, L.; Feng, J. R.; Zhang, Y.; Wang, R.; Liu, H. W.; Wang, G. C.; Cheng, F. Y.; Xi, P. X. Epitaxial heterogeneous interfaces on N-NiMoO4/NiS2 nanowires/nanosheets to boost hydrogen and oxygen production for overall water splitting. Adv. Funct. Mater. 2019, 29, 1805298.
Crossref Google Scholar
36

Ghosh, D.; Giri, S.; Das, C. K. Synthesis, characterization and electrochemical performance of graphene decorated with 1D NiMoO4·nH2O nanorods. Nanoscale 2013, 5, 10428–10437.
Crossref Google Scholar
37

Xing, Z.; Kong, W. H.; Wu, T. W.; Xie, H. T.; Wang, T.; Luo, Y. L.; Shi, X. F.; Asiri, A. M.; Zhang, Y. N.; Sun, X. P. Hollow Bi2MoO6 sphere effectively catalyzes the ambient electroreduction of N2 to NH3. ACS Sustainable Chem. Eng. 2019, 7, 12692–12696.
Crossref Google Scholar
38

Zhao, D.; Qin, J. W.; Zheng, L. R.; Cao, M. H. Amorphous vanadium oxide/molybdenum oxide hybrid with three-dimensional ordered hierarchically porous structure as a high-performance Li-ion battery anode. Chem. Mater. 2016, 28, 4180–4190.
Crossref Google Scholar
39

Wang, Z. C.; Liu, H. L.; Ge, R. X.; Ren, X.; Ren, J.; Yang, D. J.; Zhang, L. X.; Sun, X. P. Phosphorus-doped Co3O4 nanowire array: A highly efficient bifunctional electrocatalyst for overall water splitting. ACS Catal. 2018, 8, 2236–2241.
Crossref Google Scholar
40

Pan, Q.; Chen, H.; Wu, Z. G.; Wang, Y.; Zhong, B. H.; Xia, L.; Wang, H. Y.; Cui, G. W.; Guo, X. D.; Sun, X. P. Nanowire of WP as a high- performance anode material for sodium‐ion batteries. Chem. –Eur. J. 2019, 25, 971–975.
Google Scholar
41

Wang, Q.; He, H. N.; Luan, J. Y.; Tang, Y. G.; Huang, D.; Peng, Z. G.; Wang, H. Y. Synergistic effect of N-doping and rich oxygen vacancies induced by nitrogen plasma endows TiO2 superior sodium storage performance. Electrochim. Acta 2019, 309, 242–252.
Crossref Google Scholar
42

Zhang, Y. H.; Dai, R. Y.; Hu, S. R. Study of the role of oxygen vacancies as active sites in reduced graphene oxide-modified TiO2. Phys. Chem. Chem. Phys. 2017, 19, 7307–7315.
Crossref Google Scholar
43

Wang, B. B.; Wang, G.; Cheng, X. M.; Wang, H. Synthesis and electrochemical investigation of core-shell ultrathin NiO nanosheets grown on hollow carbon microspheres composite for high performance lithium and sodium ion batteries. Chem. Eng. J. 2016, 306, 1193–1202.
Crossref Google Scholar
44

Sun, Y. X.; Wang, J.; Zhao, B. T.; Cai, R.; Ran, R.; Shao, Z. P. Binder- free α-MoO3 nanobelt electrode for lithium-ion batteries utilizing van der Waals forces for film formation and connection with current collector. J. Mater. Chem. A 2013, 1, 4736–4746.
Crossref Google Scholar
45

Liu, S. D.; Lee, S. C.; Patil, U. M.; Ray, C.; Sankar, K. V.; Zhang, K.; Kundu, A.; Kang, S.; Park, J. H.; Jun, S. C. Controllable sulfuration engineered NiO nanosheets with enhanced capacitance for high rate supercapacitors. J. Mater. Chem. A 2017, 5, 4543–4549.
Crossref Google Scholar
46

Meduri, P.; Clark, E.; Kim, J. H.; Dayalan, E.; Sumanasekera, G. U.; Sunkara, M. K. MoO3-x nanowire arrays as stable and high-capacity anodes for lithium ion batteries. Nano Lett. 2012, 12, 1784–1788.
Crossref Google Scholar
47

Cho, J. S.; Lee, S. Y.; Ju, H. S.; Kang, Y. C. Synthesis of NiO nanofibers composed of hollow nanospheres with controlled sizes by the nanoscale kirkendall diffusion process and their electrochemical properties. ACS Appl. Mater. Interfaces 2015, 7, 25641–25647.
Crossref Google Scholar
48

Wu, J.; Yin, W. J.; Liu, W. W.; Guo, P.; Liu, G. B.; Liu, X. C.; Geng, D. S.; Lau, W. M.; Liu, H.; Liu, L. M. High performance NiO nanosheets anchored on three-dimensional nitrogen-doped carbon nanotubes as a binder-free anode for lithium ion batteries. J. Mater. Chem. A 2016, 4, 10940–10947.
Crossref Google Scholar
49

Ni, J. F.; Fu, S. D.; Wu, C.; Maier, J.; Yu, Y.; Li, L. Self-supported nanotube arrays of sulfur-doped TiO2 enabling ultrastable and robust sodium storage. Adv. Mater. 2016, 28, 2259–2265.
Crossref Google Scholar
50

Yang, F. H.; Gao, H.; Hao, J. N.; Zhang, S. L.; Li, P.; Liu, Y. Q.; Chen, J.; Guo, Z. P. Yolk-shell structured FeP@C nanoboxes as advanced anode materials for rechargeable lithium-/potassium-ion batteries. Adv. Funct. Mater. 2019, 29, 1808291.
Crossref Google Scholar
51

Zhang, J.; Chen, Y. L.; Chu, R. X.; Jiang, H.; Zeng, Y. B.; Zhang, Y.; Huang, N. M.; Guo, H. Pseudocapacitive P-doped NiCo2O4 microspheres as stable anode for lithium ion batteries. J. Alloys Compd. 2019, 787, 1051–1062.
Crossref Google Scholar
52

Wang, Y.; Wu, C. J.; Wu, Z. G.; Cui, G. W.; Xie, F. Y.; Guo, X. D.; Sun, X. P. FeP nanorod arrays on carbon cloth: A high-performance anode for sodium-ion batteries. Chem. Commun. 2018, 54, 9341–9344.
Crossref Google Scholar
53

Cao, D. W.; Kang, W. P.; Wang, W. H.; Sun, K. A.; Wang, Y. Y.; Ma, P.; Sun, D. F. Okra-like Fe7S8/C@ZnS/N-C@C with core-double-shelled structures as robust and high-rate sodium anode. Small 2020, 16, 1907641.
Crossref Google Scholar
54

Liu, P.; Han, J.; Zhu, K. J.; Dong, Z. H.; Jiao, L. F. Heterostructure SnSe2/ZnSe@PDA nanobox for stable and highly efficient sodium- ion storage. Adv. Energy Mater. 2020, 10, 2000741.
Crossref Google Scholar
55

Zheng, Z. M.; Wu, H. H.; Liu, H. D.; Zhang, Q. B.; He, X.; Yu, S. C.; Petrova, V.; Feng, J.; Kostecki, R.; Liu, P. et al. Achieving fast and durable lithium storage through amorphous FeP nanoparticles encapsulated in ultrathin 3D P‑doped porous carbon nanosheets. ACS Nano 2020, 14, 9545–9561.
Crossref Google Scholar
Nano Research
Volume 15 Issue 1,
January 2022
Pages 186-194
DOI: 10.1007/s12274-021-3455-3
Cite this article:
Yue L, Ma C, Yan S, et al. Improving the intrinsic electronic conductivity of NiMoO4 anodes by phosphorous doping for high lithium storage. Nano Research, 2022, 15(1): 186-194. https://doi.org/10.1007/s12274-021-3455-3
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Received: 06 February 2021
Revised: 13 March 2021
Accepted: 15 March 2021
Published: 24 April 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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